Facile in situ synthesis of nanofluids based on ionic liquids and copper oxide clusters and nanoparticlesCCDC reference number 839595. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c1dt11578b
Two stable nanofluids comprising of mixed valent copper( i,ii ) oxide clusters (
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| creator | Swadba-Kwany, Magorzata Chancelier, La Ng, Shieling Manyar, Haresh G Hardacre, Christopher Nockemann, Peter |
| description | Two stable nanofluids comprising of mixed valent copper(
i,ii
) oxide clusters ( |
| doi_str_mv | 10.1039/c1dt11578b |
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i,ii
) oxide clusters (<1 nm) suspended in 1-butyl-3-methylimidazolium acetate, [C
4
mim][OAc], and copper(
ii
) oxide nanoparticles (<50 nm) suspended in trioctyl(dodecyl)phosphonium acetate, [P
88812
][OAc], were synthesised in a facile one-pot reaction from solutions of copper(
ii
) acetate hydrate in the corresponding ionic liquids. Formation of the nanostructures was studied using
13
C NMR spectroscopy and differential scanning calorimetry (DSC). From a solution of Cu(OAc)
2
in 1-ethyl-3-methylimidazolium acetate, [C
2
mim][OAc], crystals were obtained that revealed the structure of [C
2
mim][Cu
3
(OAc)
5
(OH)
2
(H
2
O)]H
2
O, indicating the formation of copper hydroxo-clusters in the course of the reaction. Synthesised nanostructures were studied using transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). Physical properties of the prepared IL-nanofluids were examined using IR and UV-VIS spectroscopy, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and densitometry.
Two stable nanofluids comprising of copper oxide clusters or nanoparticles suspended in ionic liquids, were synthesised in a facile one-pot reaction.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c1dt11578b</identifier><language>eng</language><creationdate>2011-12</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Swadba-Kwany, Magorzata</creatorcontrib><creatorcontrib>Chancelier, La</creatorcontrib><creatorcontrib>Ng, Shieling</creatorcontrib><creatorcontrib>Manyar, Haresh G</creatorcontrib><creatorcontrib>Hardacre, Christopher</creatorcontrib><creatorcontrib>Nockemann, Peter</creatorcontrib><title>Facile in situ synthesis of nanofluids based on ionic liquids and copper oxide clusters and nanoparticlesCCDC reference number 839595. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c1dt11578b</title><description>Two stable nanofluids comprising of mixed valent copper(
i,ii
) oxide clusters (<1 nm) suspended in 1-butyl-3-methylimidazolium acetate, [C
4
mim][OAc], and copper(
ii
) oxide nanoparticles (<50 nm) suspended in trioctyl(dodecyl)phosphonium acetate, [P
88812
][OAc], were synthesised in a facile one-pot reaction from solutions of copper(
ii
) acetate hydrate in the corresponding ionic liquids. Formation of the nanostructures was studied using
13
C NMR spectroscopy and differential scanning calorimetry (DSC). From a solution of Cu(OAc)
2
in 1-ethyl-3-methylimidazolium acetate, [C
2
mim][OAc], crystals were obtained that revealed the structure of [C
2
mim][Cu
3
(OAc)
5
(OH)
2
(H
2
O)]H
2
O, indicating the formation of copper hydroxo-clusters in the course of the reaction. Synthesised nanostructures were studied using transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). Physical properties of the prepared IL-nanofluids were examined using IR and UV-VIS spectroscopy, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and densitometry.
Two stable nanofluids comprising of copper oxide clusters or nanoparticles suspended in ionic liquids, were synthesised in a facile one-pot reaction.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkE1PwzAMhiMEEuPjwh3J_ICNfqx05dpRsRMX7lWauCwoTYqdSvTP8lvoNgQHJDjZ8uNXfmQhruJoEUdpcatiHeI4y1fNkZjFyzyfF0m6PP7uk7tTccb8GkVJEmXJTHxUUhmLYBywCQPw6MIW2TD4Fpx0vrWD0QyNZNTgHRjvjAJr3vZj6TQo3_dI4N-NRlB24IB0ILt8LykYZZHLcl0CYYuETiG4oWum1CotsiJbQOUJFI0cpLX-hWS_na5oGeTOrNxUMHE_mRGgRRVob9F66mQARoT10-Yefn_hQpy00jJeftVzcV09PJePc2JV92Q6SWP9s57-z2_-4nWv2_QTK998yQ</recordid><startdate>20111206</startdate><enddate>20111206</enddate><creator>Swadba-Kwany, Magorzata</creator><creator>Chancelier, La</creator><creator>Ng, Shieling</creator><creator>Manyar, Haresh G</creator><creator>Hardacre, Christopher</creator><creator>Nockemann, Peter</creator><scope/></search><sort><creationdate>20111206</creationdate><title>Facile in situ synthesis of nanofluids based on ionic liquids and copper oxide clusters and nanoparticlesCCDC reference number 839595. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c1dt11578b</title><author>Swadba-Kwany, Magorzata ; Chancelier, La ; Ng, Shieling ; Manyar, Haresh G ; Hardacre, Christopher ; Nockemann, Peter</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c1dt11578b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Swadba-Kwany, Magorzata</creatorcontrib><creatorcontrib>Chancelier, La</creatorcontrib><creatorcontrib>Ng, Shieling</creatorcontrib><creatorcontrib>Manyar, Haresh G</creatorcontrib><creatorcontrib>Hardacre, Christopher</creatorcontrib><creatorcontrib>Nockemann, Peter</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Swadba-Kwany, Magorzata</au><au>Chancelier, La</au><au>Ng, Shieling</au><au>Manyar, Haresh G</au><au>Hardacre, Christopher</au><au>Nockemann, Peter</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facile in situ synthesis of nanofluids based on ionic liquids and copper oxide clusters and nanoparticlesCCDC reference number 839595. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c1dt11578b</atitle><date>2011-12-06</date><risdate>2011</risdate><volume>41</volume><issue>1</issue><spage>219</spage><epage>227</epage><pages>219-227</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Two stable nanofluids comprising of mixed valent copper(
i,ii
) oxide clusters (<1 nm) suspended in 1-butyl-3-methylimidazolium acetate, [C
4
mim][OAc], and copper(
ii
) oxide nanoparticles (<50 nm) suspended in trioctyl(dodecyl)phosphonium acetate, [P
88812
][OAc], were synthesised in a facile one-pot reaction from solutions of copper(
ii
) acetate hydrate in the corresponding ionic liquids. Formation of the nanostructures was studied using
13
C NMR spectroscopy and differential scanning calorimetry (DSC). From a solution of Cu(OAc)
2
in 1-ethyl-3-methylimidazolium acetate, [C
2
mim][OAc], crystals were obtained that revealed the structure of [C
2
mim][Cu
3
(OAc)
5
(OH)
2
(H
2
O)]H
2
O, indicating the formation of copper hydroxo-clusters in the course of the reaction. Synthesised nanostructures were studied using transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). Physical properties of the prepared IL-nanofluids were examined using IR and UV-VIS spectroscopy, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and densitometry.
Two stable nanofluids comprising of copper oxide clusters or nanoparticles suspended in ionic liquids, were synthesised in a facile one-pot reaction.</abstract><doi>10.1039/c1dt11578b</doi><tpages>9</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Facile in situ synthesis of nanofluids based on ionic liquids and copper oxide clusters and nanoparticlesCCDC reference number 839595. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c1dt11578b |
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