Synthesis of [(-cyano-P-nacnac)Cp] and [(-cyano-nacnac)Cp]-zirconium complexes, and their remote activation for ethylene polymerizationElectronic supplementary information (ESI) available: further experimental and spectroscopic details. CCDC reference numbers 847631847635. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1dt11261a

In this contribution the synthesis and characterization of two distinct, yet similar, zirconium complexes, [(- P -nacnac-CN)Cp] and [(-nacnac-CN)Cp] zirconium dichloride were discussed. In addition to the complexes, Lewis acid adducts [B(C 6 F 5 ) 3 ] of the complexes were isolated and characterized...

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Hauptverfasser: Rojas, Rene S, Cabrera, Alan R, Peoples, Brian C, Spannhoff, Kirsten, Valderrama, Mauricio, Frhlich, Roland, Kehr, Gerald, Erker, Gerhard
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Sprache:eng
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