A sustainable route from the renewable myrcene to methyl ethers via direct hydroalkoxylationElectronic supplementary information (ESI) available: Experimental details, general procedure, synthesis of pure compounds, 1H and 13C NMR. See DOI: 10.1039/c1cy00359c
A direct route to odoriferous methyl ethers from the monoterpene myrcene is presented. Investigating the activity of different catalytically active Lewis acids, the non-toxic and low-cost AlCl 3 appeared to be very suitable. Thus, the common route to ethers via the corresponding alcohols was reduced...
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