A free-base dipyrrin capable of forming extended architectures comparable to those of its metal(ii) complex counterpartsElectronic supplementary information (ESI) available: Additional experimental details, selected geometrical parameters and CIF files of LH and its dipyrromethane precursor red-LH, Ni[L]2, Zn[L]2 and Cu[L]2 structures. CCDC reference numbers 792154, 792155 and 835356-835358. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1ce05913k

A free-base dipyrrin capable of forming extended architectures comparable to those of its metal(ii) complex counterpartsElectronic supplementary information (ESI) available: Additional experimental details, selected geometrical parameters and CIF files of LH and its dipyrromethane precursor red-LH, Ni[L]2, Zn[L]2 and Cu[L]2 structures. CCDC reference numbers 792154, 792155 and 835356-835358. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1ce05913k

We demonstrate the involvement of an unprecedented hydrogen-bonded dipyrrin dimer in the generation of a 3-D hydrogen-bonded network which is structurally identical to the 3-D coordination networks formed with bis(dipyrrinato)metal( ii ) complexes. Hydrogen-bonded dipyrrin dimers can generate a 3-D...

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Hauptverfasser: Artigau, Marine, Bonnet, Antoine, Ladeira, Sonia, Hoffmann, Pascal, Vigroux, Alain
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Sprache:eng
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