Upconversion-powered photoelectrochemistryElectronic supplementary information (ESI) available: Complete experimental details. See DOI: 10.1039/c1cc16015j

Upconversion photochemistry occurring between palladium( ii ) octaethylporphyrin (PdOEP, 1 ) and 9,10-diphenylanthracene (DPA, 2 ) in toluene successfully sensitizes nanostructured WO 3 photoanodes ( E g = 2.7 eV) to sub-bandgap non-coherent green photons at low power density. Upconversion photochem...

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Hauptverfasser: Khnayzer, Rony S, Blumhoff, Jörg, Harrington, Jordan A, Haefele, Alexandre, Deng, Fan, Castellano, Felix N
Format: Artikel
Sprache:eng
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Zusammenfassung:Upconversion photochemistry occurring between palladium( ii ) octaethylporphyrin (PdOEP, 1 ) and 9,10-diphenylanthracene (DPA, 2 ) in toluene successfully sensitizes nanostructured WO 3 photoanodes ( E g = 2.7 eV) to sub-bandgap non-coherent green photons at low power density. Upconversion photochemistry successfully sensitizes wide bandgap nanostructured WO 3 photoanodes to sub-bandgap non-coherent green photons at low power density.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc16015j