A diastereomerically enriched, dimeric organolithium compound and the stereochemical course of its transformationsElectronic supplementary information (ESI) available: Experimental, computational and crystallographical data. CCDC [836557 and 836558]. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1cc15872d

A dimeric -silylated ethyllithium compound is presented featuring stereogenic metalated carbon centres with defined configurations. It can be generated by diastereoselective deprotonation of the corresponding ethylsilane. Reaction with Me 3 SnCl proceeds under inversion and the transfer of the stere...

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Hauptverfasser:	Unkelbach, Christian, Abele, Bors C, Lehmen, Klaus, Schildbach, Daniel, Waerder, Benedikt, Wild, Kerstin, Strohmann, Carsten
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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