Temperature/time-dependent crystallization of polythiophene:fullerene bulk heterojunction films for polymer solar cells
We report the temperature/time-dependent crystallization of poly(3-hexylthiophene) (P3HT) in blend films of P3HT and [6,6]-phenyl-C 61 -butyric acid methyl ester (PC 61 BM). The crystallization behaviour of P3HT:PC 61 BM blend films was measured as a function of annealing time at two different tempe...
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| Veröffentlicht in: | Nanoscale 2010-11, Vol.2 (11), p.2384-2389 |
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| creator | Nam, Sungho Shin, Minjung Kim, Hwajeong Kim, Youngkyoo |
| description | We report the temperature/time-dependent crystallization of poly(3-hexylthiophene) (P3HT) in blend films of P3HT and [6,6]-phenyl-C
61
-butyric acid methyl ester (PC
61
BM). The crystallization behaviour of P3HT:PC
61
BM blend films was measured as a function of annealing time at two different temperatures (150 °C and 160 °C) by employing a synchrotron-radiation grazing-incidence angle X-ray diffraction (GIXD) technique. The crystallization behaviour was correlated with corresponding solar cells annealed under the same conditions. Results showed that the trend of device performance was almost in accordance with that of the (100) GIXD intensity, indicating that the nanostructure change in blend films does affect the device performance. However, the intermediate zones related to nanomorphology fluctuations, which were observed for lower temperature (140 °C) annealing, were significantly suppressed at higher temperature (150 °C and 160 °C) annealing.
The nanostructure of P3HT:PCBM blend films was obviously affected by annealing temperature, which in turn influenced the device performance. |
| doi_str_mv | 10.1039/c0nr00379d |
| format | Article |
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61
-butyric acid methyl ester (PC
61
BM). The crystallization behaviour of P3HT:PC
61
BM blend films was measured as a function of annealing time at two different temperatures (150 °C and 160 °C) by employing a synchrotron-radiation grazing-incidence angle X-ray diffraction (GIXD) technique. The crystallization behaviour was correlated with corresponding solar cells annealed under the same conditions. Results showed that the trend of device performance was almost in accordance with that of the (100) GIXD intensity, indicating that the nanostructure change in blend films does affect the device performance. However, the intermediate zones related to nanomorphology fluctuations, which were observed for lower temperature (140 °C) annealing, were significantly suppressed at higher temperature (150 °C and 160 °C) annealing.
The nanostructure of P3HT:PCBM blend films was obviously affected by annealing temperature, which in turn influenced the device performance.</description><identifier>ISSN: 2040-3364</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/c0nr00379d</identifier><identifier>PMID: 20877854</identifier><language>eng</language><publisher>England</publisher><subject>Annealing ; Blends ; Crystallization ; Devices ; Nanocomposites ; Nanomaterials ; Nanostructure ; Solar cells</subject><ispartof>Nanoscale, 2010-11, Vol.2 (11), p.2384-2389</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c432t-6b63921b34169eef5e1480c77921dbda53c0d73c605abc57aacd3d1dbd30cf7b3</citedby><cites>FETCH-LOGICAL-c432t-6b63921b34169eef5e1480c77921dbda53c0d73c605abc57aacd3d1dbd30cf7b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20877854$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Nam, Sungho</creatorcontrib><creatorcontrib>Shin, Minjung</creatorcontrib><creatorcontrib>Kim, Hwajeong</creatorcontrib><creatorcontrib>Kim, Youngkyoo</creatorcontrib><title>Temperature/time-dependent crystallization of polythiophene:fullerene bulk heterojunction films for polymer solar cells</title><title>Nanoscale</title><addtitle>Nanoscale</addtitle><description>We report the temperature/time-dependent crystallization of poly(3-hexylthiophene) (P3HT) in blend films of P3HT and [6,6]-phenyl-C
61
-butyric acid methyl ester (PC
61
BM). The crystallization behaviour of P3HT:PC
61
BM blend films was measured as a function of annealing time at two different temperatures (150 °C and 160 °C) by employing a synchrotron-radiation grazing-incidence angle X-ray diffraction (GIXD) technique. The crystallization behaviour was correlated with corresponding solar cells annealed under the same conditions. Results showed that the trend of device performance was almost in accordance with that of the (100) GIXD intensity, indicating that the nanostructure change in blend films does affect the device performance. However, the intermediate zones related to nanomorphology fluctuations, which were observed for lower temperature (140 °C) annealing, were significantly suppressed at higher temperature (150 °C and 160 °C) annealing.
The nanostructure of P3HT:PCBM blend films was obviously affected by annealing temperature, which in turn influenced the device performance.</description><subject>Annealing</subject><subject>Blends</subject><subject>Crystallization</subject><subject>Devices</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Solar cells</subject><issn>2040-3364</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkc1LxDAQxYMofl-8K_UkCHXTTpu03mTxCwQv67mkyYStpk1NUmT96-26uuJFT_OY95vHwCPkKKEXCYVyImnnKAVeqg2ym9KMxgA83Vxrlu2QPe-fKWUlMNgmOyktOC_ybJe8zbDt0YkwOJyEpsVYYY-dwi5E0i18EMY07yI0tousjnprFmHe2H6OHV7qwRh0o4rqwbxEcwzo7PPQyU9cN6b1kbbu86pFF3lrhIskGuMPyJYWxuPh19wnTzfXs-ld_PB4ez-9eohlBmmIWc2gTJMasoSViDrHJCuo5HxcqlqJHCRVHCSjuahlzoWQCtTSAio1r2GfnK1ye2dfB_Shahu__EB0aAdflQyKghbA_yU5S7MCAIqRPF-R0lnvHeqqd00r3KJKaLVspPppZIRPvmKHukW1Rr8rGIHjFeC8XLu_Ak7_8qteafgAmZSgNg</recordid><startdate>201011</startdate><enddate>201011</enddate><creator>Nam, Sungho</creator><creator>Shin, Minjung</creator><creator>Kim, Hwajeong</creator><creator>Kim, Youngkyoo</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>201011</creationdate><title>Temperature/time-dependent crystallization of polythiophene:fullerene bulk heterojunction films for polymer solar cells</title><author>Nam, Sungho ; Shin, Minjung ; Kim, Hwajeong ; Kim, Youngkyoo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c432t-6b63921b34169eef5e1480c77921dbda53c0d73c605abc57aacd3d1dbd30cf7b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Annealing</topic><topic>Blends</topic><topic>Crystallization</topic><topic>Devices</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanostructure</topic><topic>Solar cells</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nam, Sungho</creatorcontrib><creatorcontrib>Shin, Minjung</creatorcontrib><creatorcontrib>Kim, Hwajeong</creatorcontrib><creatorcontrib>Kim, Youngkyoo</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Nanoscale</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nam, Sungho</au><au>Shin, Minjung</au><au>Kim, Hwajeong</au><au>Kim, Youngkyoo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Temperature/time-dependent crystallization of polythiophene:fullerene bulk heterojunction films for polymer solar cells</atitle><jtitle>Nanoscale</jtitle><addtitle>Nanoscale</addtitle><date>2010-11</date><risdate>2010</risdate><volume>2</volume><issue>11</issue><spage>2384</spage><epage>2389</epage><pages>2384-2389</pages><issn>2040-3364</issn><eissn>2040-3372</eissn><abstract>We report the temperature/time-dependent crystallization of poly(3-hexylthiophene) (P3HT) in blend films of P3HT and [6,6]-phenyl-C
61
-butyric acid methyl ester (PC
61
BM). The crystallization behaviour of P3HT:PC
61
BM blend films was measured as a function of annealing time at two different temperatures (150 °C and 160 °C) by employing a synchrotron-radiation grazing-incidence angle X-ray diffraction (GIXD) technique. The crystallization behaviour was correlated with corresponding solar cells annealed under the same conditions. Results showed that the trend of device performance was almost in accordance with that of the (100) GIXD intensity, indicating that the nanostructure change in blend films does affect the device performance. However, the intermediate zones related to nanomorphology fluctuations, which were observed for lower temperature (140 °C) annealing, were significantly suppressed at higher temperature (150 °C and 160 °C) annealing.
The nanostructure of P3HT:PCBM blend films was obviously affected by annealing temperature, which in turn influenced the device performance.</abstract><cop>England</cop><pmid>20877854</pmid><doi>10.1039/c0nr00379d</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2040-3364 |
| ispartof | Nanoscale, 2010-11, Vol.2 (11), p.2384-2389 |
| issn | 2040-3364 2040-3372 |
| language | eng |
| recordid | cdi_rsc_primary_c0nr00379d |
| source | Royal Society Of Chemistry Journals 2008-; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Alma/SFX Local Collection |
| subjects | Annealing Blends Crystallization Devices Nanocomposites Nanomaterials Nanostructure Solar cells |
| title | Temperature/time-dependent crystallization of polythiophene:fullerene bulk heterojunction films for polymer solar cells |
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