Luminescent liquid crystal materials based on unsymmetrical boron difluoride β-diketonate adductsElectronic supplementary information (ESI) available: Table SI1 containing yields and the analytical data. See DOI: 10.1039/c0nj00503g

A strategic design based on the use of asymmetrically 1,3-alkyloxyphenyl substituted β-diketonate ligands towards the BF 2 group allowed us to find unsymmetrical compounds that, in addition to a high photoluminescent quantum yield, possess a liquid crystal behaviour, which is related to the presence...

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Hauptverfasser: Sánchez, Ignacio, Mayoral, María José, Ovejero, Paloma, Campo, José Antonio, Heras, José Vicente, Cano, Mercedes, Lodeiro, Carlos
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container_issue 12
container_start_page 2937
container_title
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creator Sánchez, Ignacio
Mayoral, María José
Ovejero, Paloma
Campo, José Antonio
Heras, José Vicente
Cano, Mercedes
Lodeiro, Carlos
description A strategic design based on the use of asymmetrically 1,3-alkyloxyphenyl substituted β-diketonate ligands towards the BF 2 group allowed us to find unsymmetrical compounds that, in addition to a high photoluminescent quantum yield, possess a liquid crystal behaviour, which is related to the presence of the banana-shaped liquid crystal mesophases B 1 . Bent-core compounds based on boron difluoride adducts with unsymmetrically 1,3-alkyloxyphenyl substituted β-diketonate ligands are luminescent liquid crystals exhibiting high fluorescence quantum yield. These materials open new opportunities for electro-optical devices.
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title Luminescent liquid crystal materials based on unsymmetrical boron difluoride β-diketonate adductsElectronic supplementary information (ESI) available: Table SI1 containing yields and the analytical data. See DOI: 10.1039/c0nj00503g
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