Carbon-sulfur bond cleavage reactions of dibenzothiophene derivatives mediated by iron and ruthenium carbonylsElectronic supplementary information (ESI) available: Full experimental procedures and data for bpyDBT, 2, 3 and 4. CCDC reference numbers 779898-779899. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c0dt00768d
A thermal reaction of 6-(4′′-dibenzothienyl)-2,2′-bipyridine (bpyDBT) with [Ru 3 (CO) 12 ] produced a sulfur-bridged triruthenium complex via double carbon-sulfur bond cleavage and CO insertion, while a diiron( i , i ) complex containing a thiametallacycle was obtained by a photochemical reaction of...
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| creator | Hirotsu, Masakazu Tsuboi, Chiaki Nishioka, Takanori Kinoshita, Isamu |
| description | A thermal reaction of 6-(4′′-dibenzothienyl)-2,2′-bipyridine (bpyDBT) with [Ru
3
(CO)
12
] produced a sulfur-bridged triruthenium complex
via
double carbon-sulfur bond cleavage and CO insertion, while a diiron(
i
,
i
) complex containing a thiametallacycle was obtained by a photochemical reaction of bpyDBT with [Fe(CO)
5
].
A thermal reaction of 6-(4′′-dibenzothienyl)-2,2′-bipyridine with [Ru
3
(CO)
12
] produced a sulfur-bridged triruthenium complex
via
double C-S bond cleavage and CO insertion, while a diiron(
i
,
i
) complex containing a thiametallacycle was obtained by a photochemical reaction using [Fe(CO)
5
]. |
| doi_str_mv | 10.1039/c0dt00768d |
| format | Article |
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3
(CO)
12
] produced a sulfur-bridged triruthenium complex
via
double carbon-sulfur bond cleavage and CO insertion, while a diiron(
i
,
i
) complex containing a thiametallacycle was obtained by a photochemical reaction of bpyDBT with [Fe(CO)
5
].
A thermal reaction of 6-(4′′-dibenzothienyl)-2,2′-bipyridine with [Ru
3
(CO)
12
] produced a sulfur-bridged triruthenium complex
via
double C-S bond cleavage and CO insertion, while a diiron(
i
,
i
) complex containing a thiametallacycle was obtained by a photochemical reaction using [Fe(CO)
5
].</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c0dt00768d</identifier><language>eng</language><creationdate>2011-01</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Hirotsu, Masakazu</creatorcontrib><creatorcontrib>Tsuboi, Chiaki</creatorcontrib><creatorcontrib>Nishioka, Takanori</creatorcontrib><creatorcontrib>Kinoshita, Isamu</creatorcontrib><title>Carbon-sulfur bond cleavage reactions of dibenzothiophene derivatives mediated by iron and ruthenium carbonylsElectronic supplementary information (ESI) available: Full experimental procedures and data for bpyDBT, 2, 3 and 4. CCDC reference numbers 779898-779899. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c0dt00768d</title><description>A thermal reaction of 6-(4′′-dibenzothienyl)-2,2′-bipyridine (bpyDBT) with [Ru
3
(CO)
12
] produced a sulfur-bridged triruthenium complex
via
double carbon-sulfur bond cleavage and CO insertion, while a diiron(
i
,
i
) complex containing a thiametallacycle was obtained by a photochemical reaction of bpyDBT with [Fe(CO)
5
].
A thermal reaction of 6-(4′′-dibenzothienyl)-2,2′-bipyridine with [Ru
3
(CO)
12
] produced a sulfur-bridged triruthenium complex
via
double C-S bond cleavage and CO insertion, while a diiron(
i
,
i
) complex containing a thiametallacycle was obtained by a photochemical reaction using [Fe(CO)
5
].</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkU1PwkAQhqvRREUv3k3GmyaApUVKOVogcvIgd7LdncKa7e5md0vEX-9QjRxM9DSTzDvvMx9RdD2I-4M4zR94LEIcZ6OxOI7OB8Ms6-VJOjz5yZPRWXTh_VscJ0n8mJwfrQvmSqN7vlFV44BSAVwh27I1gkPGgzTag6lAyBL1hwkbaewGNYJAJ7csyC16qFFIFlBAuQPpjAZGPq4JJJRNDbyF7JSfKeSB6pKDb6xVWKMOzFGTroyr2Z4Gd7PXxT3QCFKxUuEE5o1SgO-WgK1egXWGo2gcofckwQIDMoDS7qZPyy4kXUjbyrAPRTEtaJUKHWqOoJu6ROchy_JxPu61Ie_DnLqJ2zZxt_NEUWbtmN3QrK2_1FAs5kA6OgI6wMMuX7ODR4Tpy2ICv99xGZ1WTHm8-o6d6GY-WxbPPef5ytJedITVQZ52otu_6isrqvQ_j09uBqvz</recordid><startdate>20110110</startdate><enddate>20110110</enddate><creator>Hirotsu, Masakazu</creator><creator>Tsuboi, Chiaki</creator><creator>Nishioka, Takanori</creator><creator>Kinoshita, Isamu</creator><scope/></search><sort><creationdate>20110110</creationdate><title>Carbon-sulfur bond cleavage reactions of dibenzothiophene derivatives mediated by iron and ruthenium carbonylsElectronic supplementary information (ESI) available: Full experimental procedures and data for bpyDBT, 2, 3 and 4. CCDC reference numbers 779898-779899. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c0dt00768d</title><author>Hirotsu, Masakazu ; Tsuboi, Chiaki ; Nishioka, Takanori ; Kinoshita, Isamu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c0dt00768d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hirotsu, Masakazu</creatorcontrib><creatorcontrib>Tsuboi, Chiaki</creatorcontrib><creatorcontrib>Nishioka, Takanori</creatorcontrib><creatorcontrib>Kinoshita, Isamu</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hirotsu, Masakazu</au><au>Tsuboi, Chiaki</au><au>Nishioka, Takanori</au><au>Kinoshita, Isamu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Carbon-sulfur bond cleavage reactions of dibenzothiophene derivatives mediated by iron and ruthenium carbonylsElectronic supplementary information (ESI) available: Full experimental procedures and data for bpyDBT, 2, 3 and 4. CCDC reference numbers 779898-779899. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c0dt00768d</atitle><date>2011-01-10</date><risdate>2011</risdate><volume>4</volume><issue>4</issue><spage>785</spage><epage>787</epage><pages>785-787</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A thermal reaction of 6-(4′′-dibenzothienyl)-2,2′-bipyridine (bpyDBT) with [Ru
3
(CO)
12
] produced a sulfur-bridged triruthenium complex
via
double carbon-sulfur bond cleavage and CO insertion, while a diiron(
i
,
i
) complex containing a thiametallacycle was obtained by a photochemical reaction of bpyDBT with [Fe(CO)
5
].
A thermal reaction of 6-(4′′-dibenzothienyl)-2,2′-bipyridine with [Ru
3
(CO)
12
] produced a sulfur-bridged triruthenium complex
via
double C-S bond cleavage and CO insertion, while a diiron(
i
,
i
) complex containing a thiametallacycle was obtained by a photochemical reaction using [Fe(CO)
5
].</abstract><doi>10.1039/c0dt00768d</doi><tpages>3</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Carbon-sulfur bond cleavage reactions of dibenzothiophene derivatives mediated by iron and ruthenium carbonylsElectronic supplementary information (ESI) available: Full experimental procedures and data for bpyDBT, 2, 3 and 4. CCDC reference numbers 779898-779899. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c0dt00768d |
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