Self-limited oxygen exchange kinetics at SnO2 surfaces
The oxygen exchange at SnO 2 surfaces strongly depends on surface termination, which is affected by the oxygen chemical potential. At low oxygen chemical potential, the surface adopts its reduced termination which allows oxygen exchange, while exchange is suppressed by the stoichiometric surface ter...
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| Veröffentlicht in: | Physical chemistry chemical physics : PCCP 2011-02, Vol.13 (8), p.3223-3226 |
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| container_title | Physical chemistry chemical physics : PCCP |
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| creator | Körber, Christoph Wachau, André Ágoston, Péter Albe, Karsten Klein, Andreas |
| description | The oxygen exchange at SnO
2
surfaces strongly depends on surface termination, which is affected by the oxygen chemical potential. At low oxygen chemical potential, the surface adopts its reduced termination which allows oxygen exchange, while exchange is suppressed by the stoichiometric surface termination.
Oxygen exchange is possible at reduced and suppressed at stoichiometric SnO
2
surfaces. |
| doi_str_mv | 10.1039/c0cp01935f |
| format | Article |
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2
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surfaces strongly depends on surface termination, which is affected by the oxygen chemical potential. At low oxygen chemical potential, the surface adopts its reduced termination which allows oxygen exchange, while exchange is suppressed by the stoichiometric surface termination.
Oxygen exchange is possible at reduced and suppressed at stoichiometric SnO
2
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| fulltext | fulltext |
| identifier | ISSN: 1463-9076 |
| ispartof | Physical chemistry chemical physics : PCCP, 2011-02, Vol.13 (8), p.3223-3226 |
| issn | 1463-9076 1463-9084 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Chemical potential Physical chemistry Tin dioxide Tin oxides |
| title | Self-limited oxygen exchange kinetics at SnO2 surfaces |
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