Reactions of dizincocene with sterically demanding bis(iminodi(phenyl)phosphorano)methanes
Reactions of Cp* 2 Zn 2 with sterically demanding bis(iminodi(phenyl)phosphorano)methanes LH (LH = CH 2 (Ph 2 P&z.dbd;NR) 2 (R = Ph L 1 H , SiMe 3 L 2 H , 2,6- i -Pr 2 C 6 H 3 (Dipp) L 3 H ) at ambient temperature occurred with elimination of Cp*H and subsequent formation of the homoleptic compl...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2010-11, Vol.46 (41), p.7757-7759 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Schulz, Stephan Gondzik, Sebastian Schuchmann, Daniella Westphal, Ulrich Dobrzycki, Lukasz Boese, Roland Harder, Sjoerd |
| description | Reactions of Cp*
2
Zn
2
with sterically demanding bis(iminodi(phenyl)phosphorano)methanes LH (LH = CH
2
(Ph
2
P&z.dbd;NR)
2
(R = Ph
L
1
H
, SiMe
3
L
2
H
, 2,6-
i
-Pr
2
C
6
H
3
(Dipp)
L
3
H
) at ambient temperature occurred with elimination of Cp*H and subsequent formation of the homoleptic complex L
1
2
Zn
2
1
and the heteroleptic complexes LZnZnCp* (L = L
2
2
, L
3
3
, L
1
4
).
3
is the first structurally characterized heteroleptic organozinc complex with the zinc atoms in the formal oxidation state +1.
Synthesis and X-ray crystal structures of homo- and heteroleptic Zn(
i
) complexes. |
| doi_str_mv | 10.1039/c0cc02859b |
| format | Article |
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2
Zn
2
with sterically demanding bis(iminodi(phenyl)phosphorano)methanes LH (LH = CH
2
(Ph
2
P&z.dbd;NR)
2
(R = Ph
L
1
H
, SiMe
3
L
2
H
, 2,6-
i
-Pr
2
C
6
H
3
(Dipp)
L
3
H
) at ambient temperature occurred with elimination of Cp*H and subsequent formation of the homoleptic complex L
1
2
Zn
2
1
and the heteroleptic complexes LZnZnCp* (L = L
2
2
, L
3
3
, L
1
4
).
3
is the first structurally characterized heteroleptic organozinc complex with the zinc atoms in the formal oxidation state +1.
Synthesis and X-ray crystal structures of homo- and heteroleptic Zn(
i
) complexes.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c0cc02859b</identifier><identifier>PMID: 20830375</identifier><language>eng</language><publisher>England</publisher><ispartof>Chemical communications (Cambridge, England), 2010-11, Vol.46 (41), p.7757-7759</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c370t-df2497dea41bfbbabffea3c6e41b1df94ed65bf2a8ba96e87209b0b22cc1f33c3</citedby><cites>FETCH-LOGICAL-c370t-df2497dea41bfbbabffea3c6e41b1df94ed65bf2a8ba96e87209b0b22cc1f33c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20830375$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Schulz, Stephan</creatorcontrib><creatorcontrib>Gondzik, Sebastian</creatorcontrib><creatorcontrib>Schuchmann, Daniella</creatorcontrib><creatorcontrib>Westphal, Ulrich</creatorcontrib><creatorcontrib>Dobrzycki, Lukasz</creatorcontrib><creatorcontrib>Boese, Roland</creatorcontrib><creatorcontrib>Harder, Sjoerd</creatorcontrib><title>Reactions of dizincocene with sterically demanding bis(iminodi(phenyl)phosphorano)methanes</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>Reactions of Cp*
2
Zn
2
with sterically demanding bis(iminodi(phenyl)phosphorano)methanes LH (LH = CH
2
(Ph
2
P&z.dbd;NR)
2
(R = Ph
L
1
H
, SiMe
3
L
2
H
, 2,6-
i
-Pr
2
C
6
H
3
(Dipp)
L
3
H
) at ambient temperature occurred with elimination of Cp*H and subsequent formation of the homoleptic complex L
1
2
Zn
2
1
and the heteroleptic complexes LZnZnCp* (L = L
2
2
, L
3
3
, L
1
4
).
3
is the first structurally characterized heteroleptic organozinc complex with the zinc atoms in the formal oxidation state +1.
Synthesis and X-ray crystal structures of homo- and heteroleptic Zn(
i
) complexes.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kMtLw0AQxhdRbK1evCvxZCtE95HXHqX4goIgCuIl7GPWriS7MZsi9a83pVXx4sAwM3w_PoYPoUOCzwlm_EJhpTAtUi630JCwLInTpHjeXu0pj3OWpAO0F8Ib7oukxS4aUFwwzPJ0iF4eQKjOehcibyJtP61TXoGD6MN28yh00FolqmoZaaiF09a9RtKGsa2t89qOmzm4ZTVp5j703QrnJzV0c-Eg7KMdI6oAB5s5Qk_XV4_T23h2f3M3vZzFiuW4i7WhCc81iIRII6WQxoBgKoP-JtrwBHSWSkNFIQXPoMgp5hJLSpUihjHFRuh07du0_n0BoStrGxRUVf-EX4QyT_OcJ0lGe_JsTarWh9CCKZvW1qJdlgSXqyjL3yh7-Hhju5A16B_0O7seOFoDbVA_6h-Dk__0stGGfQFOjYem</recordid><startdate>20101107</startdate><enddate>20101107</enddate><creator>Schulz, Stephan</creator><creator>Gondzik, Sebastian</creator><creator>Schuchmann, Daniella</creator><creator>Westphal, Ulrich</creator><creator>Dobrzycki, Lukasz</creator><creator>Boese, Roland</creator><creator>Harder, Sjoerd</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20101107</creationdate><title>Reactions of dizincocene with sterically demanding bis(iminodi(phenyl)phosphorano)methanes</title><author>Schulz, Stephan ; Gondzik, Sebastian ; Schuchmann, Daniella ; Westphal, Ulrich ; Dobrzycki, Lukasz ; Boese, Roland ; Harder, Sjoerd</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c370t-df2497dea41bfbbabffea3c6e41b1df94ed65bf2a8ba96e87209b0b22cc1f33c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schulz, Stephan</creatorcontrib><creatorcontrib>Gondzik, Sebastian</creatorcontrib><creatorcontrib>Schuchmann, Daniella</creatorcontrib><creatorcontrib>Westphal, Ulrich</creatorcontrib><creatorcontrib>Dobrzycki, Lukasz</creatorcontrib><creatorcontrib>Boese, Roland</creatorcontrib><creatorcontrib>Harder, Sjoerd</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schulz, Stephan</au><au>Gondzik, Sebastian</au><au>Schuchmann, Daniella</au><au>Westphal, Ulrich</au><au>Dobrzycki, Lukasz</au><au>Boese, Roland</au><au>Harder, Sjoerd</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reactions of dizincocene with sterically demanding bis(iminodi(phenyl)phosphorano)methanes</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2010-11-07</date><risdate>2010</risdate><volume>46</volume><issue>41</issue><spage>7757</spage><epage>7759</epage><pages>7757-7759</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Reactions of Cp*
2
Zn
2
with sterically demanding bis(iminodi(phenyl)phosphorano)methanes LH (LH = CH
2
(Ph
2
P&z.dbd;NR)
2
(R = Ph
L
1
H
, SiMe
3
L
2
H
, 2,6-
i
-Pr
2
C
6
H
3
(Dipp)
L
3
H
) at ambient temperature occurred with elimination of Cp*H and subsequent formation of the homoleptic complex L
1
2
Zn
2
1
and the heteroleptic complexes LZnZnCp* (L = L
2
2
, L
3
3
, L
1
4
).
3
is the first structurally characterized heteroleptic organozinc complex with the zinc atoms in the formal oxidation state +1.
Synthesis and X-ray crystal structures of homo- and heteroleptic Zn(
i
) complexes.</abstract><cop>England</cop><pmid>20830375</pmid><doi>10.1039/c0cc02859b</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2010-11, Vol.46 (41), p.7757-7759 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_rsc_primary_c0cc02859b |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Reactions of dizincocene with sterically demanding bis(iminodi(phenyl)phosphorano)methanes |
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