Thermal separation to facilitate Direct Analysis in Real Time (DART) of mixtures
We explore a thermal separation technique for use with Direct Analysis in Real Time (DART). By applying gas temperature ramping, we are able to disburse a mixture of compounds in time. The three components were selected to create a challenging mixture that would not likely be discerned solely using...
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| Veröffentlicht in: | Analyst (London) 2010-05, Vol.135 (5), p.883-886 |
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| container_end_page | 886 |
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| container_title | Analyst (London) |
| container_volume | 135 |
| creator | Nilles, J. Michael Connell, Theresa R Durst, H. Dupont |
| description | We explore a thermal separation technique for use with Direct Analysis in Real Time (DART). By applying gas temperature ramping, we are able to disburse a mixture of compounds in time. The three components were selected to create a challenging mixture that would not likely be discerned solely using exact mass capabilities. While the thermal separation technique is of low resolution, it preserves the inherent rapid, non-contact, ambient characteristics of the ion source.
Programmed thermal desorption separates a mixture of compounds in time preserving the inherent rapid, non-contact, ambient characteristics of DART. |
| doi_str_mv | 10.1039/c0an00036a |
| format | Article |
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Programmed thermal desorption separates a mixture of compounds in time preserving the inherent rapid, non-contact, ambient characteristics of DART.</description><subject>Analytical chemistry</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Gas temperature</subject><subject>Ion sources</subject><subject>Preserves</subject><subject>Real time</subject><subject>Separation</subject><issn>0003-2654</issn><issn>1364-5528</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqF0EtLw0AQB_BFFFurF-_KehAfEN1Hkk2OpfUFBaXUc5huZnElj7qbgP32prRavOhpmZ3fzMCfkGPObjiT6a1mUDHGZAw7pM9lHAZRJJJd0l99BiKOwh458P69KzmL2D7pCRbyVMioT15mb-hKKKjHBThobF3RpqYGtC1sAw3SsXWoGzqsoFh666mt6BS7gZktkV6Oh9PZFa0NLe1n0zr0h2TPQOHxaPMOyOv93Wz0GEyeH55Gw0mgZRo3gYF5EiapQYMyRq01Z1wkYR4JzoTKJWiuwCCHNM4TlAhzFc61UEanCRMylwNysd67cPVHi77JSus1FgVUWLc-U5FUsQhj9r-UMuUyUaKT12upXe29Q5MtnC3BLTPOslXU2TbqDp9u1rbzEvMf-p1tB843ALyGwjiotPVbJ1TCuUo7d7J2zuuf7q9DZ3_1s0Vu5BfvFJqN</recordid><startdate>201005</startdate><enddate>201005</enddate><creator>Nilles, J. Michael</creator><creator>Connell, Theresa R</creator><creator>Durst, H. Dupont</creator><general>Royal Society of Chemistry</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>201005</creationdate><title>Thermal separation to facilitate Direct Analysis in Real Time (DART) of mixtures</title><author>Nilles, J. Michael ; Connell, Theresa R ; Durst, H. Dupont</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c396t-fab8489fefe36eccc101284d521027d3ac17afe1a96d8e3eab74bc27fc98023d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Analytical chemistry</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Gas temperature</topic><topic>Ion sources</topic><topic>Preserves</topic><topic>Real time</topic><topic>Separation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nilles, J. Michael</creatorcontrib><creatorcontrib>Connell, Theresa R</creatorcontrib><creatorcontrib>Durst, H. Dupont</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Analyst (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nilles, J. Michael</au><au>Connell, Theresa R</au><au>Durst, H. Dupont</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal separation to facilitate Direct Analysis in Real Time (DART) of mixtures</atitle><jtitle>Analyst (London)</jtitle><addtitle>Analyst</addtitle><date>2010-05</date><risdate>2010</risdate><volume>135</volume><issue>5</issue><spage>883</spage><epage>886</epage><pages>883-886</pages><issn>0003-2654</issn><eissn>1364-5528</eissn><coden>ANALAO</coden><abstract>We explore a thermal separation technique for use with Direct Analysis in Real Time (DART). By applying gas temperature ramping, we are able to disburse a mixture of compounds in time. The three components were selected to create a challenging mixture that would not likely be discerned solely using exact mass capabilities. While the thermal separation technique is of low resolution, it preserves the inherent rapid, non-contact, ambient characteristics of the ion source.
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| fulltext | fulltext |
| identifier | ISSN: 0003-2654 |
| ispartof | Analyst (London), 2010-05, Vol.135 (5), p.883-886 |
| issn | 0003-2654 1364-5528 |
| language | eng |
| recordid | cdi_rsc_primary_c0an00036a |
| source | Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Analytical chemistry Chemistry Exact sciences and technology Gas temperature Ion sources Preserves Real time Separation |
| title | Thermal separation to facilitate Direct Analysis in Real Time (DART) of mixtures |
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