meso-Tetraarylporpholactones as high pH sensorsElectronic supplementary information (ESI) available: Details of the alternative preparations of TFPL and TFPLPt, 13C, 1H, and 19F NMR spectra, IR spectra, etc. of these and comparison compounds in the absence and presence of base, UV-vis spectra of TFPL in different solvents and the presence of different bases, UV-vis TFPL acid titrations, etc. See DOI: 10.1039/c0an00018cPart 3 of the series Oxazolochlorins. Part 2: J. Akhigbe, C. Ryppa, M. Zeller
The ability of meso -tetra(pentafluorophenyl)porpholactone ( T F PL ) and its Pt( ii ) complex [ meso -tetra(pentafluorophenyl)porpholactonato]Pt( ii ) ( T F PLPt ) to function as optical high pH sensors is described. Under strongly alkaline or high methoxide conditions, their UV-vis spectra undergo...
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