A triangulo palladium cluster consisting of μ3-capping silyl ligandsThis article is part of the 'Emerging Investigators' themed issue for ChemComm.Electronic supplementary information (ESI) available: Experimental details and NMR spectra. CCDC 764799. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c002435j
We report on the utility of multifunctional, κ 1 Si :κ 3 S -coordinated tris(methimazolyl)silanide ligands [Si(mt Me ) 3 ] − for the stabilisation of a triangulo palladium cluster [Pd 3 {Si(mt Me ) 3 } 2 ] ( 3 ) consisting of very unusual μ 3 -capping SiR 3 donors. Differences to the corresponding p...
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| creator | Armbruster, Felix Meyer, Jens Baldes, Alexander Burgos, Pascual Oña Fernández, Ignacio Breher, Frank |
| description | We report on the utility of multifunctional, κ
1
Si
:κ
3
S
-coordinated tris(methimazolyl)silanide ligands [Si(mt
Me
)
3
]
−
for the stabilisation of a
triangulo
palladium cluster [Pd
3
{Si(mt
Me
)
3
}
2
] (
3
) consisting of very unusual μ
3
-capping SiR
3
donors. Differences to the corresponding platinum chemistry were supported by NMR spectroscopy and DFT calculations.
We report on the utility of multifunctional, κ
1
Si
:κ
3
S
-coordinated tris(methimazolyl)silanide ligands [Si(mt
Me
)
3
]
−
for the stabilisation of a
triangulo
palladium cluster [Pd
3
{Si(mt
Me
)
3
}
2
] (
3
) consisting of very unusual μ
3
-capping SiR
3
donors. |
| doi_str_mv | 10.1039/c002435j |
| format | Article |
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1
Si
:κ
3
S
-coordinated tris(methimazolyl)silanide ligands [Si(mt
Me
)
3
]
−
for the stabilisation of a
triangulo
palladium cluster [Pd
3
{Si(mt
Me
)
3
}
2
] (
3
) consisting of very unusual μ
3
-capping SiR
3
donors. Differences to the corresponding platinum chemistry were supported by NMR spectroscopy and DFT calculations.
We report on the utility of multifunctional, κ
1
Si
:κ
3
S
-coordinated tris(methimazolyl)silanide ligands [Si(mt
Me
)
3
]
−
for the stabilisation of a
triangulo
palladium cluster [Pd
3
{Si(mt
Me
)
3
}
2
] (
3
) consisting of very unusual μ
3
-capping SiR
3
donors.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c002435j</identifier><language>eng</language><creationdate>2010-12</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Armbruster, Felix</creatorcontrib><creatorcontrib>Meyer, Jens</creatorcontrib><creatorcontrib>Baldes, Alexander</creatorcontrib><creatorcontrib>Burgos, Pascual Oña</creatorcontrib><creatorcontrib>Fernández, Ignacio</creatorcontrib><creatorcontrib>Breher, Frank</creatorcontrib><title>A triangulo palladium cluster consisting of μ3-capping silyl ligandsThis article is part of the 'Emerging Investigators' themed issue for ChemComm.Electronic supplementary information (ESI) available: Experimental details and NMR spectra. CCDC 764799. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c002435j</title><description>We report on the utility of multifunctional, κ
1
Si
:κ
3
S
-coordinated tris(methimazolyl)silanide ligands [Si(mt
Me
)
3
]
−
for the stabilisation of a
triangulo
palladium cluster [Pd
3
{Si(mt
Me
)
3
}
2
] (
3
) consisting of very unusual μ
3
-capping SiR
3
donors. Differences to the corresponding platinum chemistry were supported by NMR spectroscopy and DFT calculations.
We report on the utility of multifunctional, κ
1
Si
:κ
3
S
-coordinated tris(methimazolyl)silanide ligands [Si(mt
Me
)
3
]
−
for the stabilisation of a
triangulo
palladium cluster [Pd
3
{Si(mt
Me
)
3
}
2
] (
3
) consisting of very unusual μ
3
-capping SiR
3
donors.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkb9OwzAQxgMCifJHYmfgtsKQkpKkpd1QmooOgAQdEEt1OG7qyrEt26nou_EMPBOXAkJCQnjx2d_vu_ssB8FxN-p0o3hwwaLoMonT5XbQ6sa9JEyTq6edpk4HYT9O0r1g37llRKubXrW2nq_BW4GqrKUGg1JiIeoKmKyd5xaYVk44L1QJeg7vb3HI0Jjm6IRcS5CiRFW46UI4QOsFkxyoNFQ3Br_g0M4rbsvGMlErTr1K9Nq6diNWvCDc1Rzm2kJGF5muqk4uOfNWK8HA1cZI4pRHuwahiKvQC63gLH-cnAOuUEh8kXwI-avhVmxQCQX3JFAoVcDd7QM407TEDmTZKIN-L-kPBh0Y01Rqs6GYXTtySl1aNAsaXaBHmgjZZAzEacprgf9E-4wCjnMY3U-G8PsHDoPdOUrHj772g-BknE-zm9A6NjOUlF40-4bj_9TTv9WZKebxB8ncpXQ</recordid><startdate>20101206</startdate><enddate>20101206</enddate><creator>Armbruster, Felix</creator><creator>Meyer, Jens</creator><creator>Baldes, Alexander</creator><creator>Burgos, Pascual Oña</creator><creator>Fernández, Ignacio</creator><creator>Breher, Frank</creator><scope/></search><sort><creationdate>20101206</creationdate><title>A triangulo palladium cluster consisting of μ3-capping silyl ligandsThis article is part of the 'Emerging Investigators' themed issue for ChemComm.Electronic supplementary information (ESI) available: Experimental details and NMR spectra. CCDC 764799. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c002435j</title><author>Armbruster, Felix ; Meyer, Jens ; Baldes, Alexander ; Burgos, Pascual Oña ; Fernández, Ignacio ; Breher, Frank</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c002435j3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Armbruster, Felix</creatorcontrib><creatorcontrib>Meyer, Jens</creatorcontrib><creatorcontrib>Baldes, Alexander</creatorcontrib><creatorcontrib>Burgos, Pascual Oña</creatorcontrib><creatorcontrib>Fernández, Ignacio</creatorcontrib><creatorcontrib>Breher, Frank</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Armbruster, Felix</au><au>Meyer, Jens</au><au>Baldes, Alexander</au><au>Burgos, Pascual Oña</au><au>Fernández, Ignacio</au><au>Breher, Frank</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A triangulo palladium cluster consisting of μ3-capping silyl ligandsThis article is part of the 'Emerging Investigators' themed issue for ChemComm.Electronic supplementary information (ESI) available: Experimental details and NMR spectra. CCDC 764799. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c002435j</atitle><date>2010-12-06</date><risdate>2010</risdate><volume>47</volume><issue>1</issue><spage>221</spage><epage>223</epage><pages>221-223</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>We report on the utility of multifunctional, κ
1
Si
:κ
3
S
-coordinated tris(methimazolyl)silanide ligands [Si(mt
Me
)
3
]
−
for the stabilisation of a
triangulo
palladium cluster [Pd
3
{Si(mt
Me
)
3
}
2
] (
3
) consisting of very unusual μ
3
-capping SiR
3
donors. Differences to the corresponding platinum chemistry were supported by NMR spectroscopy and DFT calculations.
We report on the utility of multifunctional, κ
1
Si
:κ
3
S
-coordinated tris(methimazolyl)silanide ligands [Si(mt
Me
)
3
]
−
for the stabilisation of a
triangulo
palladium cluster [Pd
3
{Si(mt
Me
)
3
}
2
] (
3
) consisting of very unusual μ
3
-capping SiR
3
donors.</abstract><doi>10.1039/c002435j</doi><tpages>3</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | A triangulo palladium cluster consisting of μ3-capping silyl ligandsThis article is part of the 'Emerging Investigators' themed issue for ChemComm.Electronic supplementary information (ESI) available: Experimental details and NMR spectra. CCDC 764799. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c002435j |
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