Palladium-catalysed cross coupling of perfluoroalkenyl zinc reagents with 5-halo-6-azauracils

Palladium-catalysed cross coupling of perfluoroalkenyl zinc reagents with 5-halo-6-azauracils

The title reactions of 1,3-dimethyl-5-halo-6-azauracils with perfluoroalkenylzinc reagents [CF 2=CFZnI and CF 3C(ZnBr)=CF 2] give not only corresponding alkenes but also, unexpectedly, a hexafluoroalkane derivative.

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Veröffentlicht in:Mendeleev communications 2004, Vol.14 (2), p.63-64
Hauptverfasser: Wójtowicz-Rajchel, Hanna, Bednarczyk, Irena, Katrusiak, Andrzej, Koroniak, Henryk
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container_title Mendeleev communications
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creator Wójtowicz-Rajchel, Hanna
Bednarczyk, Irena
Katrusiak, Andrzej
Koroniak, Henryk
description The title reactions of 1,3-dimethyl-5-halo-6-azauracils with perfluoroalkenylzinc reagents [CF 2=CFZnI and CF 3C(ZnBr)=CF 2] give not only corresponding alkenes but also, unexpectedly, a hexafluoroalkane derivative.
doi_str_mv 10.1070/MC2004v014n02ABEH001888
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title Palladium-catalysed cross coupling of perfluoroalkenyl zinc reagents with 5-halo-6-azauracils
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