The Kinetics of Combination of Carbon Dioxide with the Anions of Glycine, Glycyl-Glycine, and Related Amino Acids
The velocity constants k' of the reaction of carbon dioxide with the anions of the amino acids glycine, glycyl-glycine, α-alanine, β-alanine, valine, histidine, β-phenyl alanine, α-amino phenyl acetic acid, and e-amino caproic acid have been determined by the rapid thermal method. At 25 °C the...
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| Veröffentlicht in: | Proceedings of the Royal Society of London. Series B, Biological sciences Biological sciences, 1966-04, Vol.164 (996), p.401-410 |
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| container_issue | 996 |
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| container_title | Proceedings of the Royal Society of London. Series B, Biological sciences |
| container_volume | 164 |
| creator | Chipperfield, J. R. |
| description | The velocity constants k' of the reaction of carbon dioxide with the anions of the amino acids glycine, glycyl-glycine, α-alanine, β-alanine, valine, histidine, β-phenyl alanine, α-amino phenyl acetic acid, and e-amino caproic acid have been determined by the rapid thermal method. At 25 °C the value of k' is given approximately by the equation log10k' = 0.262 pK + 1.197 where pK is the pK value of the amino group which reacts. For glycine and glycyl-glycine the energies of activation have been determined as 8.2 and 8.3 kcal respectively over the range 10 to 40 °C. |
| doi_str_mv | 10.1098/rspb.1966.0040 |
| format | Article |
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For glycine and glycyl-glycine the energies of activation have been determined as 8.2 and 8.3 kcal respectively over the range 10 to 40 °C.</description><identifier>ISSN: 0962-8452</identifier><identifier>ISSN: 0080-4649</identifier><identifier>ISSN: 0950-1193</identifier><identifier>EISSN: 1471-2954</identifier><identifier>EISSN: 2053-9193</identifier><identifier>DOI: 10.1098/rspb.1966.0040</identifier><identifier>PMID: 4379576</identifier><language>eng</language><publisher>London: The Royal Society</publisher><subject>Amino Acids ; Anions ; Bottles ; Carbon Dioxide ; Chemical Phenomena ; Chemistry ; Dipeptides ; Glycine ; In Vitro Techniques ; Kinetics ; Mathematical constants ; Sodium ; Solenoids ; Standard deviation ; Velocity</subject><ispartof>Proceedings of the Royal Society of London. 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R.</creatorcontrib><title>The Kinetics of Combination of Carbon Dioxide with the Anions of Glycine, Glycyl-Glycine, and Related Amino Acids</title><title>Proceedings of the Royal Society of London. Series B, Biological sciences</title><addtitle>Proc. R. Soc. Lond. B</addtitle><addtitle>Proc. R. Soc. Lond. B</addtitle><description>The velocity constants k' of the reaction of carbon dioxide with the anions of the amino acids glycine, glycyl-glycine, α-alanine, β-alanine, valine, histidine, β-phenyl alanine, α-amino phenyl acetic acid, and e-amino caproic acid have been determined by the rapid thermal method. At 25 °C the value of k' is given approximately by the equation log10k' = 0.262 pK + 1.197 where pK is the pK value of the amino group which reacts. For glycine and glycyl-glycine the energies of activation have been determined as 8.2 and 8.3 kcal respectively over the range 10 to 40 °C.</description><subject>Amino Acids</subject><subject>Anions</subject><subject>Bottles</subject><subject>Carbon Dioxide</subject><subject>Chemical Phenomena</subject><subject>Chemistry</subject><subject>Dipeptides</subject><subject>Glycine</subject><subject>In Vitro Techniques</subject><subject>Kinetics</subject><subject>Mathematical constants</subject><subject>Sodium</subject><subject>Solenoids</subject><subject>Standard deviation</subject><subject>Velocity</subject><issn>0962-8452</issn><issn>0080-4649</issn><issn>0950-1193</issn><issn>1471-2954</issn><issn>2053-9193</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1966</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kM1v0zAYxiMEGt3gygEJKaedSPF34gtSV2BDTGJshavlJDZ1SePUdraVvx6nqSomxE72q-f5vR9PkryCYAoBL94535VTyBmbAkDAk2QCSQ4zxCl5mkwAZygrCEXPk2PvVwAATgt6lBwRnHOas0myWSxV-sW0KpjKp1anc7suTSuDse2ulK6Mvw_G3ptapXcmLNMQkVkbDTvgvNlWkX-7-2yb7FDLtk6vVSODqtPZ2rQ2nVWm9i-SZ1o2Xr3cvyfJ908fF_OL7PLr-ef57DKrKMchQ4RDWJBc84pIhXKZM1ZgiglVCNZQa8qwlgrWBAOoVVUyjhCtCFJlWTON8ElyOvbtnN30ygexNr5STSNbZXsvCgIJxoBE43Q0Vs5675QWnTNr6bYCAjFkLIaMxZCxGDKOwJt9575cq_pg34cadTzqzm7jhbYyKmzFyvaujeX_u24eo65vrs4gp_wWMmI4j1CBIWCAIy5-m27XbdBF1IXxvldicD0c8u_M1-PMlQ_WHQ7JKcU4itkoGh_U_UGU7pdgOc6p-FEQ8e3mjDCyuBBX0Q9G_9L8XN4Zp8SDS2LROV_u9hs2IwBG5P2jyLBtZdug2vA3J3TfNKKrNf4Dpm7tUA</recordid><startdate>19660419</startdate><enddate>19660419</enddate><creator>Chipperfield, J. R.</creator><general>The Royal Society</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>19660419</creationdate><title>The Kinetics of Combination of Carbon Dioxide with the Anions of Glycine, Glycyl-Glycine, and Related Amino Acids</title><author>Chipperfield, J. R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c593t-24911847f9c4ae27a766835345e21d1ff563fae1d4301fecb69225c42ebbd6f23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1966</creationdate><topic>Amino Acids</topic><topic>Anions</topic><topic>Bottles</topic><topic>Carbon Dioxide</topic><topic>Chemical Phenomena</topic><topic>Chemistry</topic><topic>Dipeptides</topic><topic>Glycine</topic><topic>In Vitro Techniques</topic><topic>Kinetics</topic><topic>Mathematical constants</topic><topic>Sodium</topic><topic>Solenoids</topic><topic>Standard deviation</topic><topic>Velocity</topic><toplevel>online_resources</toplevel><creatorcontrib>Chipperfield, J. R.</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Proceedings of the Royal Society of London. Series B, Biological sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chipperfield, J. R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Kinetics of Combination of Carbon Dioxide with the Anions of Glycine, Glycyl-Glycine, and Related Amino Acids</atitle><jtitle>Proceedings of the Royal Society of London. Series B, Biological sciences</jtitle><stitle>Proc. R. Soc. Lond. B</stitle><addtitle>Proc. R. Soc. Lond. B</addtitle><date>1966-04-19</date><risdate>1966</risdate><volume>164</volume><issue>996</issue><spage>401</spage><epage>410</epage><pages>401-410</pages><issn>0962-8452</issn><issn>0080-4649</issn><issn>0950-1193</issn><eissn>1471-2954</eissn><eissn>2053-9193</eissn><abstract>The velocity constants k' of the reaction of carbon dioxide with the anions of the amino acids glycine, glycyl-glycine, α-alanine, β-alanine, valine, histidine, β-phenyl alanine, α-amino phenyl acetic acid, and e-amino caproic acid have been determined by the rapid thermal method. At 25 °C the value of k' is given approximately by the equation log10k' = 0.262 pK + 1.197 where pK is the pK value of the amino group which reacts. For glycine and glycyl-glycine the energies of activation have been determined as 8.2 and 8.3 kcal respectively over the range 10 to 40 °C.</abstract><cop>London</cop><pub>The Royal Society</pub><pmid>4379576</pmid><doi>10.1098/rspb.1966.0040</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0962-8452 |
| ispartof | Proceedings of the Royal Society of London. Series B, Biological sciences, 1966-04, Vol.164 (996), p.401-410 |
| issn | 0962-8452 0080-4649 0950-1193 1471-2954 2053-9193 |
| language | eng |
| recordid | cdi_royalsociety_journals_10_1098_rspb_1966_0040 |
| source | MEDLINE; JSTOR Archive Collection A-Z Listing |
| subjects | Amino Acids Anions Bottles Carbon Dioxide Chemical Phenomena Chemistry Dipeptides Glycine In Vitro Techniques Kinetics Mathematical constants Sodium Solenoids Standard deviation Velocity |
| title | The Kinetics of Combination of Carbon Dioxide with the Anions of Glycine, Glycyl-Glycine, and Related Amino Acids |
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