The Kinetics of the Interaction of Atomic Hydrogen with Olefines. IV. Results Obtained by the Foregoing Techniques
The experimental techniques and theoretical considerations developed in the previous parts have been utilized in obtaining data on the reactions of the type H + CnH2n = CnH2n+1. The olefines used were ethylene, propylene, iso-butene, n-pentene-2 (cis), and 2, 3, 3, tri-methyl-butene-1. Certain tenta...
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| Veröffentlicht in: | Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences Mathematical and physical sciences, 1949-04, Vol.196 (1047), p.494-509 |
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| container_issue | 1047 |
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| container_title | Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences |
| container_volume | 196 |
| creator | Melville, Harry Work Robb, J. C. |
| description | The experimental techniques and theoretical considerations developed in the previous parts have been utilized in obtaining data on the reactions of the type H + CnH2n = CnH2n+1. The olefines used were ethylene, propylene, iso-butene, n-pentene-2 (cis), and 2, 3, 3, tri-methyl-butene-1. Certain tentative suggestions as to the effect of structure on the reactivity of the double bond are put forward, but in general, the collision efficiency of a hydrogen atom with an olefine lies between 10–3 and 10–4. It is noted that in the computation of the collision efficiency, it seems to be rather unsatisfactory that the diameter of the whole molecule should be used and it is suggested that perhaps the effective diameter of a more intimate part of the molecule in the region of the double bond should be employed. |
| doi_str_mv | 10.1098/rspa.1949.0041 |
| format | Article |
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It is noted that in the computation of the collision efficiency, it seems to be rather unsatisfactory that the diameter of the whole molecule should be used and it is suggested that perhaps the effective diameter of a more intimate part of the molecule in the region of the double bond should be employed.</description><identifier>ISSN: 1364-5021</identifier><identifier>ISSN: 0080-4630</identifier><identifier>EISSN: 1471-2946</identifier><identifier>EISSN: 2053-9169</identifier><identifier>DOI: 10.1098/rspa.1949.0041</identifier><language>eng</language><publisher>London: The Royal Society</publisher><subject>Atomic interactions ; Atoms ; Hydrogen ; Kinetics ; Molecules ; Oxides ; Propylene ; Ratios ; Tungsten oxides ; Water pressure</subject><ispartof>Proceedings of the Royal Society of London. 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It is noted that in the computation of the collision efficiency, it seems to be rather unsatisfactory that the diameter of the whole molecule should be used and it is suggested that perhaps the effective diameter of a more intimate part of the molecule in the region of the double bond should be employed.</description><subject>Atomic interactions</subject><subject>Atoms</subject><subject>Hydrogen</subject><subject>Kinetics</subject><subject>Molecules</subject><subject>Oxides</subject><subject>Propylene</subject><subject>Ratios</subject><subject>Tungsten oxides</subject><subject>Water pressure</subject><issn>1364-5021</issn><issn>0080-4630</issn><issn>1471-2946</issn><issn>2053-9169</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1949</creationdate><recordtype>article</recordtype><recordid>eNp9Ustu1DAUjRBIlMKWBSv_QMJ17Dy8QqNC6aiFocPQrZU4zsRDGqe2Q0m_HidBlUaIrnxf55x7jxwEbzFEGFj-3ti-iDCjLAKg-FlwgmmGw5jR9LmPSUrDBGL8Mnhl7QEAWJJnJ4HZNRJdqk46JSzSNXI-X3dOmkI4pbuptHL6Vgl0MVZG72WH7pVr0KaVtYfZCK1vIrSVdmidRZvSFb5aoXKcmc61kXutuj3aSdF06m6Q9nXwoi5aK9_8fU-DH-efdmcX4dXm8_psdRUKSjAOJcgaGKQZLjKJoSQs92Es8jgRqSiIFFCVkNQx0LoUECcE00oUJSGizLI6JadBtPAKo601sua9UbeFGTkGPjnGJ8f45BifHPMAsgCMHv1iWijpRn7Qg-l8-n-UfQq1_f5thRnJf2GWKgw045AT_yaAE_6g-pluGvCUKVfWDpLPY8cy_6q-W1QP1mnzeBnLSRz7Zrg0lXXy92OzMD95mpEs4Tc55SS5_ghfr7_wrZ__sMw3at_cKyP50S2ztND-U3Ru3nLejzLK66FteV_VngE_yaDH3tjiCEz-AHo_1qk</recordid><startdate>19490422</startdate><enddate>19490422</enddate><creator>Melville, Harry Work</creator><creator>Robb, J. 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C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4311-e0ef090671a7e10b39871a2c825c6ca3ec0db05f204fbc025314dcab33cb77f63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1949</creationdate><topic>Atomic interactions</topic><topic>Atoms</topic><topic>Hydrogen</topic><topic>Kinetics</topic><topic>Molecules</topic><topic>Oxides</topic><topic>Propylene</topic><topic>Ratios</topic><topic>Tungsten oxides</topic><topic>Water pressure</topic><toplevel>online_resources</toplevel><creatorcontrib>Melville, Harry Work</creatorcontrib><creatorcontrib>Robb, J. C.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Melville, Harry Work</au><au>Robb, J. 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Certain tentative suggestions as to the effect of structure on the reactivity of the double bond are put forward, but in general, the collision efficiency of a hydrogen atom with an olefine lies between 10–3 and 10–4. It is noted that in the computation of the collision efficiency, it seems to be rather unsatisfactory that the diameter of the whole molecule should be used and it is suggested that perhaps the effective diameter of a more intimate part of the molecule in the region of the double bond should be employed.</abstract><cop>London</cop><pub>The Royal Society</pub><doi>10.1098/rspa.1949.0041</doi><tpages>16</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Proceedings of the Royal Society of London. Series A, Mathematical and physical sciences, 1949-04, Vol.196 (1047), p.494-509 |
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| source | JSTOR Mathematics & Statistics; JSTOR Archive Collection A-Z Listing; Alma/SFX Local Collection |
| subjects | Atomic interactions Atoms Hydrogen Kinetics Molecules Oxides Propylene Ratios Tungsten oxides Water pressure |
| title | The Kinetics of the Interaction of Atomic Hydrogen with Olefines. IV. Results Obtained by the Foregoing Techniques |
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