Post-Cyclization Skeletal Rearrangements in Plant Triterpenoid Biosynthesis by a Pair of Branchpoint Isomerases

Triterpenoids possess potent biological activities, but their polycyclic skeletons are challenging to synthesize. The skeletal diversity of triterpenoids in plants is generated by oxidosqualene cyclases based on epoxide-triggered cationic rearrangement cascades. Normally, triterpenoid skeletons then...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of the American Chemical Society 2023-03, Vol.145 (9), p.5083-5091
Hauptverfasser:	Chuang, Ling, Liu, Shenyu, Franke, Jakob
Format:	Artikel
Sprache:	eng
Schlagworte:	Cyclization Cytochrome P-450 Enzyme System - metabolism Plants Triterpenes - metabolism
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!