Quick-Release Antifouling Hydrogels for Solar-Driven Water Purification
Hydrogels are promising soft materials for energy and environmental applications, including sustainable and off-grid water purification and harvesting. A current impediment to technology translation is the low water production rate well below daily human demand. To overcome this challenge, we design...
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| Veröffentlicht in: | ACS central science 2023-02, Vol.9 (2), p.177-185 |
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| creator | Xu, Xiaohui Guillomaitre, Néhémie Christie, Kofi S. S. Bay, R. Ko̅nane Bizmark, Navid Datta, Sujit S. Ren, Zhiyong Jason Priestley, Rodney D. |
| description | Hydrogels are promising soft materials for energy and environmental applications, including sustainable and off-grid water purification and harvesting. A current impediment to technology translation is the low water production rate well below daily human demand. To overcome this challenge, we designed a rapid-response, antifouling, loofah-inspired solar absorber gel (LSAG) capable of producing potable water from various contaminated sources at a rate of ∼26 kg m–2 h–1, which is sufficient to meet daily water demand. The LSAGproduced at room temperature via aqueous processing using an ethylene glycol (EG)–water mixtureuniquely integrates the attributes of poly(N-isopropylacrylamide) (PNIPAm), polydopamine (PDA), and poly(sulfobetaine methacrylate) (PSBMA) to enable off-grid water purification with enhanced photothermal response and the capacity to prevent oil fouling and biofouling. The use of the EG–water mixture was critical to forming the loofah-like structure with enhanced water transport. Remarkably, under sunlight irradiations of 1 and 0.5 sun, the LSAG required only 10 and 20 min to release ∼70% of its stored liquid water, respectively. Equally important, we demonstrate the ability of LSAG to purify water from various harmful sources, including those containing small molecules, oils, metals, and microplastics. |
| doi_str_mv | 10.1021/acscentsci.2c01245 |
| format | Article |
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S. ; Bay, R. Ko̅nane ; Bizmark, Navid ; Datta, Sujit S. ; Ren, Zhiyong Jason ; Priestley, Rodney D.</creator><creatorcontrib>Xu, Xiaohui ; Guillomaitre, Néhémie ; Christie, Kofi S. S. ; Bay, R. Ko̅nane ; Bizmark, Navid ; Datta, Sujit S. ; Ren, Zhiyong Jason ; Priestley, Rodney D.</creatorcontrib><description>Hydrogels are promising soft materials for energy and environmental applications, including sustainable and off-grid water purification and harvesting. A current impediment to technology translation is the low water production rate well below daily human demand. To overcome this challenge, we designed a rapid-response, antifouling, loofah-inspired solar absorber gel (LSAG) capable of producing potable water from various contaminated sources at a rate of ∼26 kg m–2 h–1, which is sufficient to meet daily water demand. The LSAGproduced at room temperature via aqueous processing using an ethylene glycol (EG)–water mixtureuniquely integrates the attributes of poly(N-isopropylacrylamide) (PNIPAm), polydopamine (PDA), and poly(sulfobetaine methacrylate) (PSBMA) to enable off-grid water purification with enhanced photothermal response and the capacity to prevent oil fouling and biofouling. The use of the EG–water mixture was critical to forming the loofah-like structure with enhanced water transport. Remarkably, under sunlight irradiations of 1 and 0.5 sun, the LSAG required only 10 and 20 min to release ∼70% of its stored liquid water, respectively. Equally important, we demonstrate the ability of LSAG to purify water from various harmful sources, including those containing small molecules, oils, metals, and microplastics.</description><identifier>ISSN: 2374-7943</identifier><identifier>EISSN: 2374-7951</identifier><identifier>DOI: 10.1021/acscentsci.2c01245</identifier><identifier>PMID: 36844496</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Antifouling ; Antifouling substances ; Biofouling ; Drinking water ; Energy consumption ; Ethylene glycol ; Freshwater resources ; Heat ; Hydrogels ; Metals ; Microplastics ; Mixtures ; Morphology ; Phase transitions ; Pollutants ; Poly(N-isopropylacrylamide) ; Polyisopropyl acrylamide ; Polymerization ; Polymers ; Population ; Room temperature ; Solar energy ; Solar energy absorbers ; Solvents ; Water demand ; Water pollution ; Water purification ; Water transport</subject><ispartof>ACS central science, 2023-02, Vol.9 (2), p.177-185</ispartof><rights>2023 The Authors. 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The LSAGproduced at room temperature via aqueous processing using an ethylene glycol (EG)–water mixtureuniquely integrates the attributes of poly(N-isopropylacrylamide) (PNIPAm), polydopamine (PDA), and poly(sulfobetaine methacrylate) (PSBMA) to enable off-grid water purification with enhanced photothermal response and the capacity to prevent oil fouling and biofouling. The use of the EG–water mixture was critical to forming the loofah-like structure with enhanced water transport. Remarkably, under sunlight irradiations of 1 and 0.5 sun, the LSAG required only 10 and 20 min to release ∼70% of its stored liquid water, respectively. 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S.</au><au>Bay, R. Ko̅nane</au><au>Bizmark, Navid</au><au>Datta, Sujit S.</au><au>Ren, Zhiyong Jason</au><au>Priestley, Rodney D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Quick-Release Antifouling Hydrogels for Solar-Driven Water Purification</atitle><jtitle>ACS central science</jtitle><addtitle>ACS Cent. Sci</addtitle><date>2023-02-22</date><risdate>2023</risdate><volume>9</volume><issue>2</issue><spage>177</spage><epage>185</epage><pages>177-185</pages><issn>2374-7943</issn><eissn>2374-7951</eissn><abstract>Hydrogels are promising soft materials for energy and environmental applications, including sustainable and off-grid water purification and harvesting. A current impediment to technology translation is the low water production rate well below daily human demand. 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| subjects | Antifouling Antifouling substances Biofouling Drinking water Energy consumption Ethylene glycol Freshwater resources Heat Hydrogels Metals Microplastics Mixtures Morphology Phase transitions Pollutants Poly(N-isopropylacrylamide) Polyisopropyl acrylamide Polymerization Polymers Population Room temperature Solar energy Solar energy absorbers Solvents Water demand Water pollution Water purification Water transport |
| title | Quick-Release Antifouling Hydrogels for Solar-Driven Water Purification |
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