Covalently Functionalized Cellulose Nanoparticles for Simultaneous Enrichment of Pb(II), Cd(II) and Cu(II) Ions
Cellulose nanoparticles are sustainable natural polymers with excellent application in environmental remediation technology. In this work, we synthesized cellulose nanoparticles and covalently functionalized them with a multi-functional group possessing ligands. The hybrid material shows excellent a...
Gespeichert in:
| Veröffentlicht in: | Polymers 2023-01, Vol.15 (3), p.532 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 3 |
| container_start_page | 532 |
| container_title | Polymers |
| container_volume | 15 |
| creator | Alsaeedi, Huda Ahmad, Hilal Altowairqi, Malak Faisal Alhamed, Afnan Abdullah Alsalme, Ali |
| description | Cellulose nanoparticles are sustainable natural polymers with excellent application in environmental remediation technology. In this work, we synthesized cellulose nanoparticles and covalently functionalized them with a multi-functional group possessing ligands. The hybrid material shows excellent adsorption properties for the simultaneous extraction of multiple metal ions in the sample preparation technique. The sorbent shows excellent sorption capacity in the range of 1.8-2.2 mmol/g of material. The developed method was successfully employed for the simultaneous extraction of Pb(II), Cd(II) and Cu(II) from real-world samples (industrial effluent, river water, tap and groundwater) and subsequently determined by inductively coupled plasma optical emission spectroscopy (ICP-OES). The method shows a preconcentration limit of 0.7 ppb attributes to analyze the trace concentration of studied metal ions. The detection limit obtained for Pb(II), Cd(II) and Cu(II) is found to be 0.4 ppb. |
| doi_str_mv | 10.3390/polym15030532 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9921717</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2775622370</sourcerecordid><originalsourceid>FETCH-LOGICAL-c415t-7934babbf7e99354c21487f989a81b5c6d2dd43210a02ef0a52cf6a8cd65b6fc3</originalsourceid><addsrcrecordid>eNpdkU1rFTEUhoMottQu3UrATYWO5juTjSBDWy8UFdR1yGQSm5JJrslM4frrTXtrac3mHMjDwznnBeA1Ru8pVejDNsfdjDmiiFPyDBwSJGnHqEDPH_UH4LjWa9Qe40Jg-RIcUCEl7ik9BHnINya6tMQdPF-TXUJOJoY_boKDi3GNuTr4xaS8NWUJNroKfS7we5jXuJjk8lrhWSrBXs1NArOH38aTzebdKRym2wpNaqb1rt3kVF-BF97E6o7v6xH4eX72Y_jcXX692AyfLjvLMF86qSgbzTh66ZSinFmCWS-96pXp8citmMg0MUowMog4jwwn1gvT20nwUXhLj8DHvXe7jrObbBuumKi3Jcym7HQ2QT_9SeFK_8o3WimCJZZNcHIvKPn36uqi51BtO8l-aU2k5IIQKlFD3_6HXue1tDPeUUwJ1mJoVLenbMm1FucfhsFI36apn6TZ-DePN3ig_2VH_wLbK5ts</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2774964436</pqid></control><display><type>article</type><title>Covalently Functionalized Cellulose Nanoparticles for Simultaneous Enrichment of Pb(II), Cd(II) and Cu(II) Ions</title><source>PubMed Central Open Access</source><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central</source><creator>Alsaeedi, Huda ; Ahmad, Hilal ; Altowairqi, Malak Faisal ; Alhamed, Afnan Abdullah ; Alsalme, Ali</creator><creatorcontrib>Alsaeedi, Huda ; Ahmad, Hilal ; Altowairqi, Malak Faisal ; Alhamed, Afnan Abdullah ; Alsalme, Ali</creatorcontrib><description>Cellulose nanoparticles are sustainable natural polymers with excellent application in environmental remediation technology. In this work, we synthesized cellulose nanoparticles and covalently functionalized them with a multi-functional group possessing ligands. The hybrid material shows excellent adsorption properties for the simultaneous extraction of multiple metal ions in the sample preparation technique. The sorbent shows excellent sorption capacity in the range of 1.8-2.2 mmol/g of material. The developed method was successfully employed for the simultaneous extraction of Pb(II), Cd(II) and Cu(II) from real-world samples (industrial effluent, river water, tap and groundwater) and subsequently determined by inductively coupled plasma optical emission spectroscopy (ICP-OES). The method shows a preconcentration limit of 0.7 ppb attributes to analyze the trace concentration of studied metal ions. The detection limit obtained for Pb(II), Cd(II) and Cu(II) is found to be 0.4 ppb.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym15030532</identifier><identifier>PMID: 36771833</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Adsorbents ; Adsorption ; Aqueous solutions ; Cadmium ; Cellulose ; Copper ; Equilibrium ; Fourier transforms ; Functional groups ; Graphene ; Groundwater ; Inductively coupled plasma ; Industrial effluents ; Ions ; Lead ; Ligands ; Metal ions ; Metals ; Nanoparticles ; Natural polymers ; Optical emission spectroscopy ; Reproducibility ; Sorbents ; Spectrum analysis</subject><ispartof>Polymers, 2023-01, Vol.15 (3), p.532</ispartof><rights>2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2023 by the authors. 2023</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c415t-7934babbf7e99354c21487f989a81b5c6d2dd43210a02ef0a52cf6a8cd65b6fc3</citedby><cites>FETCH-LOGICAL-c415t-7934babbf7e99354c21487f989a81b5c6d2dd43210a02ef0a52cf6a8cd65b6fc3</cites><orcidid>0000-0003-0897-2296 ; 0000-0003-1602-8430</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9921717/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9921717/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,315,728,781,785,886,27929,27930,53796,53798</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36771833$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Alsaeedi, Huda</creatorcontrib><creatorcontrib>Ahmad, Hilal</creatorcontrib><creatorcontrib>Altowairqi, Malak Faisal</creatorcontrib><creatorcontrib>Alhamed, Afnan Abdullah</creatorcontrib><creatorcontrib>Alsalme, Ali</creatorcontrib><title>Covalently Functionalized Cellulose Nanoparticles for Simultaneous Enrichment of Pb(II), Cd(II) and Cu(II) Ions</title><title>Polymers</title><addtitle>Polymers (Basel)</addtitle><description>Cellulose nanoparticles are sustainable natural polymers with excellent application in environmental remediation technology. In this work, we synthesized cellulose nanoparticles and covalently functionalized them with a multi-functional group possessing ligands. The hybrid material shows excellent adsorption properties for the simultaneous extraction of multiple metal ions in the sample preparation technique. The sorbent shows excellent sorption capacity in the range of 1.8-2.2 mmol/g of material. The developed method was successfully employed for the simultaneous extraction of Pb(II), Cd(II) and Cu(II) from real-world samples (industrial effluent, river water, tap and groundwater) and subsequently determined by inductively coupled plasma optical emission spectroscopy (ICP-OES). The method shows a preconcentration limit of 0.7 ppb attributes to analyze the trace concentration of studied metal ions. The detection limit obtained for Pb(II), Cd(II) and Cu(II) is found to be 0.4 ppb.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Aqueous solutions</subject><subject>Cadmium</subject><subject>Cellulose</subject><subject>Copper</subject><subject>Equilibrium</subject><subject>Fourier transforms</subject><subject>Functional groups</subject><subject>Graphene</subject><subject>Groundwater</subject><subject>Inductively coupled plasma</subject><subject>Industrial effluents</subject><subject>Ions</subject><subject>Lead</subject><subject>Ligands</subject><subject>Metal ions</subject><subject>Metals</subject><subject>Nanoparticles</subject><subject>Natural polymers</subject><subject>Optical emission spectroscopy</subject><subject>Reproducibility</subject><subject>Sorbents</subject><subject>Spectrum analysis</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkU1rFTEUhoMottQu3UrATYWO5juTjSBDWy8UFdR1yGQSm5JJrslM4frrTXtrac3mHMjDwznnBeA1Ru8pVejDNsfdjDmiiFPyDBwSJGnHqEDPH_UH4LjWa9Qe40Jg-RIcUCEl7ik9BHnINya6tMQdPF-TXUJOJoY_boKDi3GNuTr4xaS8NWUJNroKfS7we5jXuJjk8lrhWSrBXs1NArOH38aTzebdKRym2wpNaqb1rt3kVF-BF97E6o7v6xH4eX72Y_jcXX692AyfLjvLMF86qSgbzTh66ZSinFmCWS-96pXp8citmMg0MUowMog4jwwn1gvT20nwUXhLj8DHvXe7jrObbBuumKi3Jcym7HQ2QT_9SeFK_8o3WimCJZZNcHIvKPn36uqi51BtO8l-aU2k5IIQKlFD3_6HXue1tDPeUUwJ1mJoVLenbMm1FucfhsFI36apn6TZ-DePN3ig_2VH_wLbK5ts</recordid><startdate>20230119</startdate><enddate>20230119</enddate><creator>Alsaeedi, Huda</creator><creator>Ahmad, Hilal</creator><creator>Altowairqi, Malak Faisal</creator><creator>Alhamed, Afnan Abdullah</creator><creator>Alsalme, Ali</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0003-0897-2296</orcidid><orcidid>https://orcid.org/0000-0003-1602-8430</orcidid></search><sort><creationdate>20230119</creationdate><title>Covalently Functionalized Cellulose Nanoparticles for Simultaneous Enrichment of Pb(II), Cd(II) and Cu(II) Ions</title><author>Alsaeedi, Huda ; Ahmad, Hilal ; Altowairqi, Malak Faisal ; Alhamed, Afnan Abdullah ; Alsalme, Ali</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c415t-7934babbf7e99354c21487f989a81b5c6d2dd43210a02ef0a52cf6a8cd65b6fc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Aqueous solutions</topic><topic>Cadmium</topic><topic>Cellulose</topic><topic>Copper</topic><topic>Equilibrium</topic><topic>Fourier transforms</topic><topic>Functional groups</topic><topic>Graphene</topic><topic>Groundwater</topic><topic>Inductively coupled plasma</topic><topic>Industrial effluents</topic><topic>Ions</topic><topic>Lead</topic><topic>Ligands</topic><topic>Metal ions</topic><topic>Metals</topic><topic>Nanoparticles</topic><topic>Natural polymers</topic><topic>Optical emission spectroscopy</topic><topic>Reproducibility</topic><topic>Sorbents</topic><topic>Spectrum analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Alsaeedi, Huda</creatorcontrib><creatorcontrib>Ahmad, Hilal</creatorcontrib><creatorcontrib>Altowairqi, Malak Faisal</creatorcontrib><creatorcontrib>Alhamed, Afnan Abdullah</creatorcontrib><creatorcontrib>Alsalme, Ali</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Access via ProQuest (Open Access)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Alsaeedi, Huda</au><au>Ahmad, Hilal</au><au>Altowairqi, Malak Faisal</au><au>Alhamed, Afnan Abdullah</au><au>Alsalme, Ali</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Covalently Functionalized Cellulose Nanoparticles for Simultaneous Enrichment of Pb(II), Cd(II) and Cu(II) Ions</atitle><jtitle>Polymers</jtitle><addtitle>Polymers (Basel)</addtitle><date>2023-01-19</date><risdate>2023</risdate><volume>15</volume><issue>3</issue><spage>532</spage><pages>532-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>Cellulose nanoparticles are sustainable natural polymers with excellent application in environmental remediation technology. In this work, we synthesized cellulose nanoparticles and covalently functionalized them with a multi-functional group possessing ligands. The hybrid material shows excellent adsorption properties for the simultaneous extraction of multiple metal ions in the sample preparation technique. The sorbent shows excellent sorption capacity in the range of 1.8-2.2 mmol/g of material. The developed method was successfully employed for the simultaneous extraction of Pb(II), Cd(II) and Cu(II) from real-world samples (industrial effluent, river water, tap and groundwater) and subsequently determined by inductively coupled plasma optical emission spectroscopy (ICP-OES). The method shows a preconcentration limit of 0.7 ppb attributes to analyze the trace concentration of studied metal ions. The detection limit obtained for Pb(II), Cd(II) and Cu(II) is found to be 0.4 ppb.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>36771833</pmid><doi>10.3390/polym15030532</doi><orcidid>https://orcid.org/0000-0003-0897-2296</orcidid><orcidid>https://orcid.org/0000-0003-1602-8430</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2073-4360 |
| ispartof | Polymers, 2023-01, Vol.15 (3), p.532 |
| issn | 2073-4360 2073-4360 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9921717 |
| source | PubMed Central Open Access; MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central |
| subjects | Adsorbents Adsorption Aqueous solutions Cadmium Cellulose Copper Equilibrium Fourier transforms Functional groups Graphene Groundwater Inductively coupled plasma Industrial effluents Ions Lead Ligands Metal ions Metals Nanoparticles Natural polymers Optical emission spectroscopy Reproducibility Sorbents Spectrum analysis |
| title | Covalently Functionalized Cellulose Nanoparticles for Simultaneous Enrichment of Pb(II), Cd(II) and Cu(II) Ions |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-14T01%3A07%3A13IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Covalently%20Functionalized%20Cellulose%20Nanoparticles%20for%20Simultaneous%20Enrichment%20of%20Pb(II),%20Cd(II)%20and%20Cu(II)%20Ions&rft.jtitle=Polymers&rft.au=Alsaeedi,%20Huda&rft.date=2023-01-19&rft.volume=15&rft.issue=3&rft.spage=532&rft.pages=532-&rft.issn=2073-4360&rft.eissn=2073-4360&rft_id=info:doi/10.3390/polym15030532&rft_dat=%3Cproquest_pubme%3E2775622370%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2774964436&rft_id=info:pmid/36771833&rfr_iscdi=true |