Spontaneous Synthesis of [FeII(Atrz)3]SO4 and its Analogues Through Accelerated Ageing: New Insights from Small‐Scale Reactions

Accelerated ageing reactions that take place between two solid materials on contact in the absence of added solvent have been used to synthesize two spin‐crossover‐active 1D coordination polymers and one of their Cu(II) analogues. The hygroscopy of the ligands and the relative humidity of the reacti...

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Veröffentlicht in:	Chemistry : a European journal 2022-11, Vol.28 (64), p.e202201823-n/a
Hauptverfasser:	Lonergan, Rhona F., Conway, Georgina A., Doheny, Patrick W., Shepherd, Helena J.
Format:	Artikel
Sprache:	eng
Schlagworte:	accelerated ageing Aging Aminotriazole Chemistry Coordination polymers Copper Crystals Fibrous structure Hygroscopicity Ligands Polymers Relative humidity Salts solid-state reactions spin crossover
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