Reactivity of bi- and monometallic trifluoroacetates towards amorphous SiO2

The reactivity of alkali–manganese(ii) and alkali trifluoroacetates towards amorphous SiO2 (a-SiO2) was studied in the solid-state. K4Mn2(tfa)8, Cs3Mn2(tfa)7(tfaH), KH(tfa)2, and CsH(tfa)2 (tfa = CF3COO–) were thermally decomposed under vacuum in fused quartz tubes. Three new bimetallic fluorotriflu...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2022-12, Vol.51 (47), p.18224-18233
Hauptverfasser:	Munasinghe, Hashini N, Imer, Marcos R, Szlag, Regina G, Suescun, Leopoldo, Rabuffetti, Federico A
Format:	Artikel
Sprache:	eng
Schlagworte:	Bimetals Crystallization Decomposition Fluorination Fluorosilicates Fused quartz Manganese Metal clusters Silicon dioxide Trifluoroacetates Tubes
Online-Zugang:	Volltext
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