Effect of Processing Time of Steam-Explosion for the Extraction of Cellulose Fibers from Phoenix canariensis Palm Leaves as Potential Renewable Feedstock for Materials
This paper briefly discusses the utilization of pruning wastes as a lignocellulosic source of cellulose fibers, which could be of potential use in the development of valuable materials such as sustainable textiles and fillers for footwear components including uppers and soles. palm leaves, one of th...
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| Veröffentlicht in: | Polymers 2022-11, Vol.14 (23), p.5206 |
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| creator | Pérez-Limiñana, Maria Angeles Pérez-Aguilar, Henoc Ruzafa-Silvestre, Carlos Orgilés-Calpena, Elena Arán-Ais, Francisca |
| description | This paper briefly discusses the utilization of pruning wastes as a lignocellulosic source of cellulose fibers, which could be of potential use in the development of valuable materials such as sustainable textiles and fillers for footwear components including uppers and soles.
palm leaves, one of the most common plants found in the local environment of the Alicante region (Spain), was used as a biomass raw material. Determining appropriate processing parameters and their desired range of maximum cellulose extraction states is key to improving yields. Therefore, this study aimed at determining the effect of processing conditions on cellulose extraction by optimizing the hydrothermal process, as a part of overall combined processes involving several steps. Specifically, the time of the steam-explosion stage was varied between 15 and 33 min in order to maximize the cellulose extraction yield. The composition of both the extracted fibers and the resulting by-product solutions generated during the different steps were determined by FTIR and TGA in order to analyze the effectiveness of removing hemicellulose, lignin and extractives as well as the removed substances at each stage for their further valorization. Additionally, the morphology of cellulosic fibers was evaluated by SEM and their crystallinity by XRD. Crystalline cellulose fibers were successfully extracted from pruning biomass wastes, achieving more efficient removal of hemicellulose and lignin when the hydrothermal process was assessed over 25-33 min. This resulted in finer and smoother fibers, but the crystallinity of α-cellulose decreased as the time of steam-explosion increased to 33 min. The characterization of waste solutions generated after the different extraction steps confirmed that the most effective treatments to remove lignin and hemicellulose from the cell wall are alkaline pretreatment and a hydrothermal process. |
| doi_str_mv | 10.3390/polym14235206 |
| format | Article |
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palm leaves, one of the most common plants found in the local environment of the Alicante region (Spain), was used as a biomass raw material. Determining appropriate processing parameters and their desired range of maximum cellulose extraction states is key to improving yields. Therefore, this study aimed at determining the effect of processing conditions on cellulose extraction by optimizing the hydrothermal process, as a part of overall combined processes involving several steps. Specifically, the time of the steam-explosion stage was varied between 15 and 33 min in order to maximize the cellulose extraction yield. The composition of both the extracted fibers and the resulting by-product solutions generated during the different steps were determined by FTIR and TGA in order to analyze the effectiveness of removing hemicellulose, lignin and extractives as well as the removed substances at each stage for their further valorization. Additionally, the morphology of cellulosic fibers was evaluated by SEM and their crystallinity by XRD. Crystalline cellulose fibers were successfully extracted from pruning biomass wastes, achieving more efficient removal of hemicellulose and lignin when the hydrothermal process was assessed over 25-33 min. This resulted in finer and smoother fibers, but the crystallinity of α-cellulose decreased as the time of steam-explosion increased to 33 min. The characterization of waste solutions generated after the different extraction steps confirmed that the most effective treatments to remove lignin and hemicellulose from the cell wall are alkaline pretreatment and a hydrothermal process.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym14235206</identifier><identifier>PMID: 36501600</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Alcohol ; Biomass ; Biopolymers ; Cellulose fibers ; Chemicals ; Crystalline cellulose ; Crystallinity ; Ethanol ; Explosions ; Footwear ; Fourier transforms ; Glucose ; High temperature ; Hydrogen ; Lignin ; Lignocellulose ; Oxidation ; Process parameters ; Pruning ; Raw materials ; Textiles ; Wastes</subject><ispartof>Polymers, 2022-11, Vol.14 (23), p.5206</ispartof><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2022 by the authors. 2022</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c415t-bfa6e925a86d42bc7afd44b05e38253d8c0407f7e840b14490a343bc3f9a52253</citedby><cites>FETCH-LOGICAL-c415t-bfa6e925a86d42bc7afd44b05e38253d8c0407f7e840b14490a343bc3f9a52253</cites><orcidid>0000-0002-5689-3683 ; 0000-0001-5471-9318 ; 0000-0001-8062-489X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9736043/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9736043/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36501600$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Pérez-Limiñana, Maria Angeles</creatorcontrib><creatorcontrib>Pérez-Aguilar, Henoc</creatorcontrib><creatorcontrib>Ruzafa-Silvestre, Carlos</creatorcontrib><creatorcontrib>Orgilés-Calpena, Elena</creatorcontrib><creatorcontrib>Arán-Ais, Francisca</creatorcontrib><title>Effect of Processing Time of Steam-Explosion for the Extraction of Cellulose Fibers from Phoenix canariensis Palm Leaves as Potential Renewable Feedstock for Materials</title><title>Polymers</title><addtitle>Polymers (Basel)</addtitle><description>This paper briefly discusses the utilization of pruning wastes as a lignocellulosic source of cellulose fibers, which could be of potential use in the development of valuable materials such as sustainable textiles and fillers for footwear components including uppers and soles.
palm leaves, one of the most common plants found in the local environment of the Alicante region (Spain), was used as a biomass raw material. Determining appropriate processing parameters and their desired range of maximum cellulose extraction states is key to improving yields. Therefore, this study aimed at determining the effect of processing conditions on cellulose extraction by optimizing the hydrothermal process, as a part of overall combined processes involving several steps. Specifically, the time of the steam-explosion stage was varied between 15 and 33 min in order to maximize the cellulose extraction yield. The composition of both the extracted fibers and the resulting by-product solutions generated during the different steps were determined by FTIR and TGA in order to analyze the effectiveness of removing hemicellulose, lignin and extractives as well as the removed substances at each stage for their further valorization. Additionally, the morphology of cellulosic fibers was evaluated by SEM and their crystallinity by XRD. Crystalline cellulose fibers were successfully extracted from pruning biomass wastes, achieving more efficient removal of hemicellulose and lignin when the hydrothermal process was assessed over 25-33 min. This resulted in finer and smoother fibers, but the crystallinity of α-cellulose decreased as the time of steam-explosion increased to 33 min. The characterization of waste solutions generated after the different extraction steps confirmed that the most effective treatments to remove lignin and hemicellulose from the cell wall are alkaline pretreatment and a hydrothermal process.</description><subject>Alcohol</subject><subject>Biomass</subject><subject>Biopolymers</subject><subject>Cellulose fibers</subject><subject>Chemicals</subject><subject>Crystalline cellulose</subject><subject>Crystallinity</subject><subject>Ethanol</subject><subject>Explosions</subject><subject>Footwear</subject><subject>Fourier transforms</subject><subject>Glucose</subject><subject>High temperature</subject><subject>Hydrogen</subject><subject>Lignin</subject><subject>Lignocellulose</subject><subject>Oxidation</subject><subject>Process parameters</subject><subject>Pruning</subject><subject>Raw materials</subject><subject>Textiles</subject><subject>Wastes</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdkk1v1DAQhiNERavSI1dkiQuXgBPb-bggodUWkBaxass5mjjjrktiL7bTbn8Rf5NZWqq2vow9fvTOZ5a9KfgHIVr-cevH26mQpVAlr15kRyWvRS5FxV8-uh9mJzFecTpSVVVRv8oORaV4UXF-lP1ZGoM6MW_YOniNMVp3yS7shHvXeUKY8uVuO_povWPGB5Y2yJa7FECnvYuoBY7jTASyU9tjiMwEP7H1xqOzO6bBQbDooo1sDePEVgjXGBnQ0yd0ycLIztDhDfQjSSAOMXn961-w75AwEBBfZweGDJ7c2-Ps5-nyYvE1X_348m3xeZVrWaiU9wYqbEsFTTXIstc1mEHKnisUTanE0GgueW1qbCTvCylbDkKKXgvTgiqJOM4-3elu537CQVN-AcZuG-wE4bbzYLunP85uukt_3bU1tVoKEnh_LxD87xlj6iYbNXUIHPo5dmWthKDetxWh756hV34OjsojSjaKptUUROV3lA4-xoDmIZmCd_st6J5sAfFvH1fwQP-fufgLcx-xFw</recordid><startdate>20221129</startdate><enddate>20221129</enddate><creator>Pérez-Limiñana, Maria Angeles</creator><creator>Pérez-Aguilar, Henoc</creator><creator>Ruzafa-Silvestre, Carlos</creator><creator>Orgilés-Calpena, Elena</creator><creator>Arán-Ais, Francisca</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-5689-3683</orcidid><orcidid>https://orcid.org/0000-0001-5471-9318</orcidid><orcidid>https://orcid.org/0000-0001-8062-489X</orcidid></search><sort><creationdate>20221129</creationdate><title>Effect of Processing Time of Steam-Explosion for the Extraction of Cellulose Fibers from Phoenix canariensis Palm Leaves as Potential Renewable Feedstock for Materials</title><author>Pérez-Limiñana, Maria Angeles ; Pérez-Aguilar, Henoc ; Ruzafa-Silvestre, Carlos ; Orgilés-Calpena, Elena ; Arán-Ais, Francisca</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c415t-bfa6e925a86d42bc7afd44b05e38253d8c0407f7e840b14490a343bc3f9a52253</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Alcohol</topic><topic>Biomass</topic><topic>Biopolymers</topic><topic>Cellulose fibers</topic><topic>Chemicals</topic><topic>Crystalline cellulose</topic><topic>Crystallinity</topic><topic>Ethanol</topic><topic>Explosions</topic><topic>Footwear</topic><topic>Fourier transforms</topic><topic>Glucose</topic><topic>High temperature</topic><topic>Hydrogen</topic><topic>Lignin</topic><topic>Lignocellulose</topic><topic>Oxidation</topic><topic>Process parameters</topic><topic>Pruning</topic><topic>Raw materials</topic><topic>Textiles</topic><topic>Wastes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pérez-Limiñana, Maria Angeles</creatorcontrib><creatorcontrib>Pérez-Aguilar, Henoc</creatorcontrib><creatorcontrib>Ruzafa-Silvestre, Carlos</creatorcontrib><creatorcontrib>Orgilés-Calpena, Elena</creatorcontrib><creatorcontrib>Arán-Ais, Francisca</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pérez-Limiñana, Maria Angeles</au><au>Pérez-Aguilar, Henoc</au><au>Ruzafa-Silvestre, Carlos</au><au>Orgilés-Calpena, Elena</au><au>Arán-Ais, Francisca</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Processing Time of Steam-Explosion for the Extraction of Cellulose Fibers from Phoenix canariensis Palm Leaves as Potential Renewable Feedstock for Materials</atitle><jtitle>Polymers</jtitle><addtitle>Polymers (Basel)</addtitle><date>2022-11-29</date><risdate>2022</risdate><volume>14</volume><issue>23</issue><spage>5206</spage><pages>5206-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>This paper briefly discusses the utilization of pruning wastes as a lignocellulosic source of cellulose fibers, which could be of potential use in the development of valuable materials such as sustainable textiles and fillers for footwear components including uppers and soles.
palm leaves, one of the most common plants found in the local environment of the Alicante region (Spain), was used as a biomass raw material. Determining appropriate processing parameters and their desired range of maximum cellulose extraction states is key to improving yields. Therefore, this study aimed at determining the effect of processing conditions on cellulose extraction by optimizing the hydrothermal process, as a part of overall combined processes involving several steps. Specifically, the time of the steam-explosion stage was varied between 15 and 33 min in order to maximize the cellulose extraction yield. The composition of both the extracted fibers and the resulting by-product solutions generated during the different steps were determined by FTIR and TGA in order to analyze the effectiveness of removing hemicellulose, lignin and extractives as well as the removed substances at each stage for their further valorization. Additionally, the morphology of cellulosic fibers was evaluated by SEM and their crystallinity by XRD. Crystalline cellulose fibers were successfully extracted from pruning biomass wastes, achieving more efficient removal of hemicellulose and lignin when the hydrothermal process was assessed over 25-33 min. This resulted in finer and smoother fibers, but the crystallinity of α-cellulose decreased as the time of steam-explosion increased to 33 min. The characterization of waste solutions generated after the different extraction steps confirmed that the most effective treatments to remove lignin and hemicellulose from the cell wall are alkaline pretreatment and a hydrothermal process.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>36501600</pmid><doi>10.3390/polym14235206</doi><orcidid>https://orcid.org/0000-0002-5689-3683</orcidid><orcidid>https://orcid.org/0000-0001-5471-9318</orcidid><orcidid>https://orcid.org/0000-0001-8062-489X</orcidid><oa>free_for_read</oa></addata></record> |
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| source | MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central; PubMed Central Open Access |
| subjects | Alcohol Biomass Biopolymers Cellulose fibers Chemicals Crystalline cellulose Crystallinity Ethanol Explosions Footwear Fourier transforms Glucose High temperature Hydrogen Lignin Lignocellulose Oxidation Process parameters Pruning Raw materials Textiles Wastes |
| title | Effect of Processing Time of Steam-Explosion for the Extraction of Cellulose Fibers from Phoenix canariensis Palm Leaves as Potential Renewable Feedstock for Materials |
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