Modulating the Inclusive and Coordinating Ability of Thiacalix[4]arene and Its Antenna Effect on Yb3-Luminescence via Upper-Rim Substitution

The present work introduces the series of thiacalix[4]arenes (H4L) bearing different upper-rim substituents (R = H, Br, NO2) for rational design of ligands providing an antenna-effect on the NIR Yb3+-centered luminescence of their Yb3+ complexes. The unusual inclusive self-assembly of H3L− (Br) thro...

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Veröffentlicht in:	Molecules (Basel, Switzerland) Switzerland), 2022-10, Vol.27 (20), p.6793
Hauptverfasser:	Podyachev, Sergey N., Sudakova, Svetlana N., Zairov, Rustem R., Syakaev, Victor V., Masliy, Alexey N., Dusek, Michal, Gubaidullin, Aidar T., Dovzhenko, Alexey P., Buzyurova, Daina N., Lapaev, Dmitry V., Mambetova, Gulnaz Sh, Babaev, Vasily M., Kuznetsov, Andrey M., Mustafina, Asiya R.
Format:	Artikel
Sprache:	eng
Schlagworte:	Antennas Aqueous solutions Aromatic compounds Crystal structure Cubane Energy Ligands Luminescence Nitrogen dioxide Self-assembly Single crystals X ray analysis
Online-Zugang:	Volltext
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