Modified Fabrication of Perovskite-Based Composites and Its Exploration in Printable Humidity Sensors

Organic perovskites are promising optoelectronic semiconductor materials with photoelectric applications. It is known that the luminescence of perovskites is highly sensitive to hydron molecules due to its low moisture resistance of crystal structure, indicating its potential application on humidity...

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Veröffentlicht in:Polymers 2022-10, Vol.14 (20), p.4354
Hauptverfasser: Peng, Meiting, Zhang, Fan, Tian, Liyong, You, Longbin, Wu, Jiayi, Wen, Nanhua, Zhang, Yangfan, Wu, Yancheng, Gan, Feng, Yu, Hui, Zhao, Jing, Feng, Qi, Deng, Fuqin, Zheng, Longhui, Wu, Yingzhu, Yi, Ningbo
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container_issue 20
container_start_page 4354
container_title Polymers
container_volume 14
creator Peng, Meiting
Zhang, Fan
Tian, Liyong
You, Longbin
Wu, Jiayi
Wen, Nanhua
Zhang, Yangfan
Wu, Yancheng
Gan, Feng
Yu, Hui
Zhao, Jing
Feng, Qi
Deng, Fuqin
Zheng, Longhui
Wu, Yingzhu
Yi, Ningbo
description Organic perovskites are promising optoelectronic semiconductor materials with photoelectric applications. It is known that the luminescence of perovskites is highly sensitive to hydron molecules due to its low moisture resistance of crystal structure, indicating its potential application on humidity-sensing. Herein, a novel perovskite-based compound (PBC) with minimal defects was developed to promote the photoluminescence performance via optimization of the drying method and precursor constitutions. Perovskite materials with good structural integrity and enhanced fluorescence performance up to four times were obtained from supercritical drying. Moreover, the hydrophilic polymer matrix, polyethylene oxide (PEO), was added to obtain a composite of perovskite/PEO (PPC), introducing enhanced humidity sensitivity and solution processibility. These perovskite/PEO composites also exhibited long-term stability and manifold cycles of sensitivity to humidity owing to perovskite encapsulation by PEO. In addition, this precursor solution of perovskite-based composites could be fancily processed by multiple methods, including printing and handwriting, which demonstrates the potential and broaden the applications in architecture decoration, logos, trademarks, and double encryption of anti-fake combined with humidity.
doi_str_mv 10.3390/polym14204354
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It is known that the luminescence of perovskites is highly sensitive to hydron molecules due to its low moisture resistance of crystal structure, indicating its potential application on humidity-sensing. Herein, a novel perovskite-based compound (PBC) with minimal defects was developed to promote the photoluminescence performance via optimization of the drying method and precursor constitutions. Perovskite materials with good structural integrity and enhanced fluorescence performance up to four times were obtained from supercritical drying. Moreover, the hydrophilic polymer matrix, polyethylene oxide (PEO), was added to obtain a composite of perovskite/PEO (PPC), introducing enhanced humidity sensitivity and solution processibility. These perovskite/PEO composites also exhibited long-term stability and manifold cycles of sensitivity to humidity owing to perovskite encapsulation by PEO. In addition, this precursor solution of perovskite-based composites could be fancily processed by multiple methods, including printing and handwriting, which demonstrates the potential and broaden the applications in architecture decoration, logos, trademarks, and double encryption of anti-fake combined with humidity.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>36297932</pmid><doi>10.3390/polym14204354</doi><orcidid>https://orcid.org/0000-0002-4544-2983</orcidid><oa>free_for_read</oa></addata></record>
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subjects Communication
Composite materials
Crystal defects
Crystal structure
Crystals
Drying
Efficiency
Flexibility
Fluorescence
Food quality
Fourier transforms
Handwriting
Humidity
Logos
Moisture effects
Moisture resistance
Morphology
Optimization
Optoelectronics
Perovskite
Perovskites
Photoelectricity
Photoluminescence
Polyethylene oxide
Polymers
Precursors
Semiconductor materials
Semiconductors
Sensitivity enhancement
Sensors
Solvents
Spectrum analysis
Structural integrity
Structure
title Modified Fabrication of Perovskite-Based Composites and Its Exploration in Printable Humidity Sensors
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