Adsorption of Magenta Dye on PbO Doped MgZnO: Interpretation of Statistical Physics Parameters Using Double-Layer Models
This article reports the synthesis of PbO doped MgZnO (PbO@MgZnO) by a co-precipitation method, followed by an ultrasonication process. PbO@MgZnO demonstrates a significant adsorption capability toward Magenta Dye (MD). The greatest adsorption capability was optimized by varying parameters such as p...
Gespeichert in:
| Veröffentlicht in: | International journal of environmental research and public health 2022-09, Vol.19 (19), p.12199 |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 19 |
| container_start_page | 12199 |
| container_title | International journal of environmental research and public health |
| container_volume | 19 |
| creator | Altalhi, Tariq Jethave, Ganesh Fegade, Umesh Mersal, Gaber A M Ibrahim, Mohamed M Mahmoud, M H H Kumeria, Tushar Isai, Kalpesh A Sonawane, Milind |
| description | This article reports the synthesis of PbO doped MgZnO (PbO@MgZnO) by a co-precipitation method, followed by an ultrasonication process. PbO@MgZnO demonstrates a significant adsorption capability toward Magenta Dye (MD). The greatest adsorption capability was optimized by varying parameters such as pH, MD concentration, and adsorbent dose. The kinetics study illustrates that the adsorption of MD on PbO@MgZnO follows the pseudo-second-order. The isotherm study revealed that Langmuir is best fitted for the adsorption, but with little difference in the R
value of Langmuir and Freundlich, the adsorption process cloud be single or multi-layer. The maximum adsorption capacity was found to be 333.33 mg/g. The negative ΔG refers to the spontaneity of MD adsorption on PbO@MgZnO. The steric parameters from statistical physics models also favor the multi-layer adsorption mechanism. As a function of solution temperature, the parameter
pattern has values of
= 0.395, 0.290, and 0.280 for 298, 308, and 318 K, respectively (i.e., all values were below 1). Therefore, horizontal molecule positioning and multiple locking mechanisms were implicated during interactions between MD and PbO@MgZnO active sites. |
| doi_str_mv | 10.3390/ijerph191912199 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9564486</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2724248786</sourcerecordid><originalsourceid>FETCH-LOGICAL-c421t-eafd8b0ea048c7c24d1ad2dfd92271d3565ee084e5e4123b16f352ef81bb9963</originalsourceid><addsrcrecordid>eNpdUU1Lw0AQXUSxWj17kwXP0f3KNutBKPWr0NKC9eJl2WQnbUqajbup2H9vqlZU5jDDzJv3ZngInVFyybkiV8USfL2gqg1GldpDR1RKEglJ6P6vuoOOQ1gSwhMh1SHqcMk4jQk9Qu99G5yvm8JV2OV4bOZQNQbfbgC3nWk6wbeuBovH85dqco2HVdMKemjMbuNpW4amyEyJp4tNKLKAp8abFbTIgJ9DUc1bjnVaQjQyG_B47CyU4QQd5KYMcPqdu2h2fzcbPEajycNw0B9FmWC0icDkNkkJGCKSrJcxYamxzOZWMdajlscyBiCJgBgEZTylMucxgzyhaaqU5F1080Vbr9MV2Kz9zptS175YGb_RzhT676QqFnru3rSKpRDJluDim8C71zWERi_d2lftyZr1mGAi6X2irr5QmXcheMh_FCjRW6f0P6fajfPfh_3gd9bwD9UGklo</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2724248786</pqid></control><display><type>article</type><title>Adsorption of Magenta Dye on PbO Doped MgZnO: Interpretation of Statistical Physics Parameters Using Double-Layer Models</title><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>MEDLINE</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><source>PubMed Central Open Access</source><creator>Altalhi, Tariq ; Jethave, Ganesh ; Fegade, Umesh ; Mersal, Gaber A M ; Ibrahim, Mohamed M ; Mahmoud, M H H ; Kumeria, Tushar ; Isai, Kalpesh A ; Sonawane, Milind</creator><creatorcontrib>Altalhi, Tariq ; Jethave, Ganesh ; Fegade, Umesh ; Mersal, Gaber A M ; Ibrahim, Mohamed M ; Mahmoud, M H H ; Kumeria, Tushar ; Isai, Kalpesh A ; Sonawane, Milind</creatorcontrib><description>This article reports the synthesis of PbO doped MgZnO (PbO@MgZnO) by a co-precipitation method, followed by an ultrasonication process. PbO@MgZnO demonstrates a significant adsorption capability toward Magenta Dye (MD). The greatest adsorption capability was optimized by varying parameters such as pH, MD concentration, and adsorbent dose. The kinetics study illustrates that the adsorption of MD on PbO@MgZnO follows the pseudo-second-order. The isotherm study revealed that Langmuir is best fitted for the adsorption, but with little difference in the R
value of Langmuir and Freundlich, the adsorption process cloud be single or multi-layer. The maximum adsorption capacity was found to be 333.33 mg/g. The negative ΔG refers to the spontaneity of MD adsorption on PbO@MgZnO. The steric parameters from statistical physics models also favor the multi-layer adsorption mechanism. As a function of solution temperature, the parameter
pattern has values of
= 0.395, 0.290, and 0.280 for 298, 308, and 318 K, respectively (i.e., all values were below 1). Therefore, horizontal molecule positioning and multiple locking mechanisms were implicated during interactions between MD and PbO@MgZnO active sites.</description><identifier>ISSN: 1660-4601</identifier><identifier>ISSN: 1661-7827</identifier><identifier>EISSN: 1660-4601</identifier><identifier>DOI: 10.3390/ijerph191912199</identifier><identifier>PMID: 36231501</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Adsorbents ; Adsorption ; Dyes ; Energy ; Experiments ; Hydrogen-Ion Concentration ; Kinetics ; Lead oxides ; Mathematical models ; Morphology ; Multilayers ; Nanoparticles ; Physics ; Rosaniline Dyes ; Statistical analysis ; Thermodynamics ; Water Pollutants, Chemical - analysis</subject><ispartof>International journal of environmental research and public health, 2022-09, Vol.19 (19), p.12199</ispartof><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2022 by the authors. 2022</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c421t-eafd8b0ea048c7c24d1ad2dfd92271d3565ee084e5e4123b16f352ef81bb9963</citedby><cites>FETCH-LOGICAL-c421t-eafd8b0ea048c7c24d1ad2dfd92271d3565ee084e5e4123b16f352ef81bb9963</cites><orcidid>0000-0002-5470-8579</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9564486/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9564486/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36231501$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Altalhi, Tariq</creatorcontrib><creatorcontrib>Jethave, Ganesh</creatorcontrib><creatorcontrib>Fegade, Umesh</creatorcontrib><creatorcontrib>Mersal, Gaber A M</creatorcontrib><creatorcontrib>Ibrahim, Mohamed M</creatorcontrib><creatorcontrib>Mahmoud, M H H</creatorcontrib><creatorcontrib>Kumeria, Tushar</creatorcontrib><creatorcontrib>Isai, Kalpesh A</creatorcontrib><creatorcontrib>Sonawane, Milind</creatorcontrib><title>Adsorption of Magenta Dye on PbO Doped MgZnO: Interpretation of Statistical Physics Parameters Using Double-Layer Models</title><title>International journal of environmental research and public health</title><addtitle>Int J Environ Res Public Health</addtitle><description>This article reports the synthesis of PbO doped MgZnO (PbO@MgZnO) by a co-precipitation method, followed by an ultrasonication process. PbO@MgZnO demonstrates a significant adsorption capability toward Magenta Dye (MD). The greatest adsorption capability was optimized by varying parameters such as pH, MD concentration, and adsorbent dose. The kinetics study illustrates that the adsorption of MD on PbO@MgZnO follows the pseudo-second-order. The isotherm study revealed that Langmuir is best fitted for the adsorption, but with little difference in the R
value of Langmuir and Freundlich, the adsorption process cloud be single or multi-layer. The maximum adsorption capacity was found to be 333.33 mg/g. The negative ΔG refers to the spontaneity of MD adsorption on PbO@MgZnO. The steric parameters from statistical physics models also favor the multi-layer adsorption mechanism. As a function of solution temperature, the parameter
pattern has values of
= 0.395, 0.290, and 0.280 for 298, 308, and 318 K, respectively (i.e., all values were below 1). Therefore, horizontal molecule positioning and multiple locking mechanisms were implicated during interactions between MD and PbO@MgZnO active sites.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Dyes</subject><subject>Energy</subject><subject>Experiments</subject><subject>Hydrogen-Ion Concentration</subject><subject>Kinetics</subject><subject>Lead oxides</subject><subject>Mathematical models</subject><subject>Morphology</subject><subject>Multilayers</subject><subject>Nanoparticles</subject><subject>Physics</subject><subject>Rosaniline Dyes</subject><subject>Statistical analysis</subject><subject>Thermodynamics</subject><subject>Water Pollutants, Chemical - analysis</subject><issn>1660-4601</issn><issn>1661-7827</issn><issn>1660-4601</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>BENPR</sourceid><recordid>eNpdUU1Lw0AQXUSxWj17kwXP0f3KNutBKPWr0NKC9eJl2WQnbUqajbup2H9vqlZU5jDDzJv3ZngInVFyybkiV8USfL2gqg1GldpDR1RKEglJ6P6vuoOOQ1gSwhMh1SHqcMk4jQk9Qu99G5yvm8JV2OV4bOZQNQbfbgC3nWk6wbeuBovH85dqco2HVdMKemjMbuNpW4amyEyJp4tNKLKAp8abFbTIgJ9DUc1bjnVaQjQyG_B47CyU4QQd5KYMcPqdu2h2fzcbPEajycNw0B9FmWC0icDkNkkJGCKSrJcxYamxzOZWMdajlscyBiCJgBgEZTylMucxgzyhaaqU5F1080Vbr9MV2Kz9zptS175YGb_RzhT676QqFnru3rSKpRDJluDim8C71zWERi_d2lftyZr1mGAi6X2irr5QmXcheMh_FCjRW6f0P6fajfPfh_3gd9bwD9UGklo</recordid><startdate>20220926</startdate><enddate>20220926</enddate><creator>Altalhi, Tariq</creator><creator>Jethave, Ganesh</creator><creator>Fegade, Umesh</creator><creator>Mersal, Gaber A M</creator><creator>Ibrahim, Mohamed M</creator><creator>Mahmoud, M H H</creator><creator>Kumeria, Tushar</creator><creator>Isai, Kalpesh A</creator><creator>Sonawane, Milind</creator><general>MDPI AG</general><general>MDPI</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8C1</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>K9.</scope><scope>M0S</scope><scope>M1P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-5470-8579</orcidid></search><sort><creationdate>20220926</creationdate><title>Adsorption of Magenta Dye on PbO Doped MgZnO: Interpretation of Statistical Physics Parameters Using Double-Layer Models</title><author>Altalhi, Tariq ; Jethave, Ganesh ; Fegade, Umesh ; Mersal, Gaber A M ; Ibrahim, Mohamed M ; Mahmoud, M H H ; Kumeria, Tushar ; Isai, Kalpesh A ; Sonawane, Milind</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c421t-eafd8b0ea048c7c24d1ad2dfd92271d3565ee084e5e4123b16f352ef81bb9963</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Dyes</topic><topic>Energy</topic><topic>Experiments</topic><topic>Hydrogen-Ion Concentration</topic><topic>Kinetics</topic><topic>Lead oxides</topic><topic>Mathematical models</topic><topic>Morphology</topic><topic>Multilayers</topic><topic>Nanoparticles</topic><topic>Physics</topic><topic>Rosaniline Dyes</topic><topic>Statistical analysis</topic><topic>Thermodynamics</topic><topic>Water Pollutants, Chemical - analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Altalhi, Tariq</creatorcontrib><creatorcontrib>Jethave, Ganesh</creatorcontrib><creatorcontrib>Fegade, Umesh</creatorcontrib><creatorcontrib>Mersal, Gaber A M</creatorcontrib><creatorcontrib>Ibrahim, Mohamed M</creatorcontrib><creatorcontrib>Mahmoud, M H H</creatorcontrib><creatorcontrib>Kumeria, Tushar</creatorcontrib><creatorcontrib>Isai, Kalpesh A</creatorcontrib><creatorcontrib>Sonawane, Milind</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Public Health Database</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>International journal of environmental research and public health</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Altalhi, Tariq</au><au>Jethave, Ganesh</au><au>Fegade, Umesh</au><au>Mersal, Gaber A M</au><au>Ibrahim, Mohamed M</au><au>Mahmoud, M H H</au><au>Kumeria, Tushar</au><au>Isai, Kalpesh A</au><au>Sonawane, Milind</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption of Magenta Dye on PbO Doped MgZnO: Interpretation of Statistical Physics Parameters Using Double-Layer Models</atitle><jtitle>International journal of environmental research and public health</jtitle><addtitle>Int J Environ Res Public Health</addtitle><date>2022-09-26</date><risdate>2022</risdate><volume>19</volume><issue>19</issue><spage>12199</spage><pages>12199-</pages><issn>1660-4601</issn><issn>1661-7827</issn><eissn>1660-4601</eissn><abstract>This article reports the synthesis of PbO doped MgZnO (PbO@MgZnO) by a co-precipitation method, followed by an ultrasonication process. PbO@MgZnO demonstrates a significant adsorption capability toward Magenta Dye (MD). The greatest adsorption capability was optimized by varying parameters such as pH, MD concentration, and adsorbent dose. The kinetics study illustrates that the adsorption of MD on PbO@MgZnO follows the pseudo-second-order. The isotherm study revealed that Langmuir is best fitted for the adsorption, but with little difference in the R
value of Langmuir and Freundlich, the adsorption process cloud be single or multi-layer. The maximum adsorption capacity was found to be 333.33 mg/g. The negative ΔG refers to the spontaneity of MD adsorption on PbO@MgZnO. The steric parameters from statistical physics models also favor the multi-layer adsorption mechanism. As a function of solution temperature, the parameter
pattern has values of
= 0.395, 0.290, and 0.280 for 298, 308, and 318 K, respectively (i.e., all values were below 1). Therefore, horizontal molecule positioning and multiple locking mechanisms were implicated during interactions between MD and PbO@MgZnO active sites.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>36231501</pmid><doi>10.3390/ijerph191912199</doi><orcidid>https://orcid.org/0000-0002-5470-8579</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1660-4601 |
| ispartof | International journal of environmental research and public health, 2022-09, Vol.19 (19), p.12199 |
| issn | 1660-4601 1661-7827 1660-4601 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9564486 |
| source | MDPI - Multidisciplinary Digital Publishing Institute; MEDLINE; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access |
| subjects | Adsorbents Adsorption Dyes Energy Experiments Hydrogen-Ion Concentration Kinetics Lead oxides Mathematical models Morphology Multilayers Nanoparticles Physics Rosaniline Dyes Statistical analysis Thermodynamics Water Pollutants, Chemical - analysis |
| title | Adsorption of Magenta Dye on PbO Doped MgZnO: Interpretation of Statistical Physics Parameters Using Double-Layer Models |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-05T10%3A22%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Adsorption%20of%20Magenta%20Dye%20on%20PbO%20Doped%20MgZnO:%20Interpretation%20of%20Statistical%20Physics%20Parameters%20Using%20Double-Layer%20Models&rft.jtitle=International%20journal%20of%20environmental%20research%20and%20public%20health&rft.au=Altalhi,%20Tariq&rft.date=2022-09-26&rft.volume=19&rft.issue=19&rft.spage=12199&rft.pages=12199-&rft.issn=1660-4601&rft.eissn=1660-4601&rft_id=info:doi/10.3390/ijerph191912199&rft_dat=%3Cproquest_pubme%3E2724248786%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2724248786&rft_id=info:pmid/36231501&rfr_iscdi=true |