Structure and Reactivity of [Ru–Al] and [Ru–Sn] Heterobimetallic PPh3‑Based Complexes

Treatment of [Ru­(PPh3)­(C6H4PPh2)2H]­[Li­(THF)2] with AlMe2Cl and SnMe3Cl leads to elimination of LiCl and CH4 and formation of the heterobimetallic complexes [Ru­(C6H4PPh2)2{PPh2C6H4AlMe­(THF)}­H] 5 and [Ru­(PPh3)­(C6H4PPh2)­(PPh2C6H4SnMe2)] 6, respectively. The pathways to 5 and 6 have been probe...

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Veröffentlicht in:	Organometallics 2022-10, Vol.41 (19), p.2716-2730
Hauptverfasser:	Isaac, Connie J., Miloserdov, Fedor M., Pécharman, Anne-Frédérique, Lowe, John P., McMullin, Claire L., Whittlesey, Michael K.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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