Pendent Relay Enhances H2O2 Selectivity during Dioxygen Reduction Mediated by Bipyridine-Based Co–N2O2 Complexes

Generally, cobalt–N2O2 complexes show selectivity for hydrogen peroxide during electrochemical dioxygen (O2) reduction. We recently reported a Co­(III)–N2O2 complex with a 2,2′-bipyridine-based ligand backbone which showed alternative selectivity: H2O was observed as the primary reduction product fr...

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Veröffentlicht in:	Journal of the American Chemical Society 2021-08, Vol.143 (33), p.13065-13073
Hauptverfasser:	Nichols, Asa W, Cook, Emma N, Gan, Yunqiao J, Miedaner, Peter R, Dressel, Julia M, Dickie, Diane A, Shafaat, Hannah S, Machan, Charles W
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysis catalysts cobalt dioxygen homogeneous inorganic and physical chemistry INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY mechanism reaction mechanisms redox redox reactions saturation selectivity
Online-Zugang:	Volltext
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