Fire-Retardant Property of Hexasubstituted Cyclotriphosphazene Derivatives with Schiff Base Linking Unit Applied as an Additives in Polyurethane Coating for Wood Fabrication
A series of new hexasubstituted cyclotriphosphaze derivatives containing Schiff base linkages were successfully synthesized and characterized. The series contains different terminal substituents of pentyl and tetradecyl. Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spec...
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| Veröffentlicht in: | Polymers 2022-09, Vol.14 (18), p.3768 |
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| creator | Mohd Taip, Nurul Atiqah Jamain, Zuhair Palle, Ismawati |
| description | A series of new hexasubstituted cyclotriphosphaze derivatives containing Schiff base linkages were successfully synthesized and characterized. The series contains different terminal substituents of pentyl and tetradecyl. Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (NMR), and carbon, hydrogen, and nitrogen (CHN) elemental analysis were used to characterize the intermediates and final compounds, while the thermal stability of the final compounds is evaluated with a thermogravimetric analysis (TGA) test. The final compounds are physically added to the polyurethane coating formulation and then applied to the wood panel using a brush and the compound’s fire-retardant properties are evaluated using the limiting oxygen index (LOI) test. In this research, compound 3b showed good thermal stability compared to compound 3a. In terms of LOI results, polyurethane with an LOI value of 21.90% was employed as a matrix for wood coating and the value increased to 24.90% when this polyurethane is incorporated with 1 wt.% of the compound 3b. The increase in the LOI value indicates that the wood coating containing hexasubstituted cyclotriphosphazene compounds exhibits excellent fire-retardant properties as additives. |
| doi_str_mv | 10.3390/polym14183768 |
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The series contains different terminal substituents of pentyl and tetradecyl. Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (NMR), and carbon, hydrogen, and nitrogen (CHN) elemental analysis were used to characterize the intermediates and final compounds, while the thermal stability of the final compounds is evaluated with a thermogravimetric analysis (TGA) test. The final compounds are physically added to the polyurethane coating formulation and then applied to the wood panel using a brush and the compound’s fire-retardant properties are evaluated using the limiting oxygen index (LOI) test. In this research, compound 3b showed good thermal stability compared to compound 3a. In terms of LOI results, polyurethane with an LOI value of 21.90% was employed as a matrix for wood coating and the value increased to 24.90% when this polyurethane is incorporated with 1 wt.% of the compound 3b. The increase in the LOI value indicates that the wood coating containing hexasubstituted cyclotriphosphazene compounds exhibits excellent fire-retardant properties as additives.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym14183768</identifier><identifier>PMID: 36145913</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Additives ; Chemical analysis ; Coating ; Coatings ; Coatings industry ; Fireproofing agents ; Flame retardants ; Fourier transforms ; Hydrogen ; Imines ; Infrared spectroscopy ; Nitrogen ; NMR spectroscopy ; Nuclear magnetic resonance spectroscopy ; Phosphorus ; Polyurethane resins ; Polyurethanes ; Potash ; Potassium ; Schiff bases ; Spectrum analysis ; Stability analysis ; Thermal stability ; Thermogravimetric analysis</subject><ispartof>Polymers, 2022-09, Vol.14 (18), p.3768</ispartof><rights>COPYRIGHT 2022 MDPI AG</rights><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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The series contains different terminal substituents of pentyl and tetradecyl. Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (NMR), and carbon, hydrogen, and nitrogen (CHN) elemental analysis were used to characterize the intermediates and final compounds, while the thermal stability of the final compounds is evaluated with a thermogravimetric analysis (TGA) test. The final compounds are physically added to the polyurethane coating formulation and then applied to the wood panel using a brush and the compound’s fire-retardant properties are evaluated using the limiting oxygen index (LOI) test. In this research, compound 3b showed good thermal stability compared to compound 3a. In terms of LOI results, polyurethane with an LOI value of 21.90% was employed as a matrix for wood coating and the value increased to 24.90% when this polyurethane is incorporated with 1 wt.% of the compound 3b. The increase in the LOI value indicates that the wood coating containing hexasubstituted cyclotriphosphazene compounds exhibits excellent fire-retardant properties as additives.</description><subject>Additives</subject><subject>Chemical analysis</subject><subject>Coating</subject><subject>Coatings</subject><subject>Coatings industry</subject><subject>Fireproofing agents</subject><subject>Flame retardants</subject><subject>Fourier transforms</subject><subject>Hydrogen</subject><subject>Imines</subject><subject>Infrared spectroscopy</subject><subject>Nitrogen</subject><subject>NMR spectroscopy</subject><subject>Nuclear magnetic resonance spectroscopy</subject><subject>Phosphorus</subject><subject>Polyurethane resins</subject><subject>Polyurethanes</subject><subject>Potash</subject><subject>Potassium</subject><subject>Schiff bases</subject><subject>Spectrum analysis</subject><subject>Stability analysis</subject><subject>Thermal stability</subject><subject>Thermogravimetric analysis</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdUsFu1DAUjBCIVkuP3C1x4ZLWsRM7viAtC9sirUQFVBwjx37euGTtYDsLyz_xj3i1FaLYBz-9NzPy6E1RvKzwJaUCX01-POyqumopZ-2T4pxgTsuaMvz0n_qsuIjxHudTN4xV_HlxRllVN6Ki58XvtQ1QfoIkg5YuodvgJwjpgLxBN_BTxrmPyaY5gUargxp9CnYafJwG-QscoHcQ7F4mu4eIftg0oM9qsMagtzIC2lj3zbotunM2oeU0jTaryIikQ0ut7YllHbrNNuYAaZBZceWzXCYZH9BX7zVayz5YlZvevSieGTlGuHh4F8Xd-v2X1U25-Xj9YbXclCo7S6XEvRRt23PFGg2CC6H7mnFiCHAgrCZt0x_995j3kpk2T5TSRHCOq9pITRfFm5PuNPc70ApcCnLspmB3Mhw6L233eOLs0G39vhMNpqIRWeD1g0Dw32eIqdvZqGAcs0M_x47wKm-Mk4Zm6Kv_oPd-Di7bO6IYw4SRI-ryhNrKETrrTF6EVPlq2FnlHRib-0tes5qKKgdiUZQnggo-xgDm7-8r3B3D0z0KD_0DVim62g</recordid><startdate>20220908</startdate><enddate>20220908</enddate><creator>Mohd Taip, Nurul Atiqah</creator><creator>Jamain, Zuhair</creator><creator>Palle, Ismawati</creator><general>MDPI AG</general><general>MDPI</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-0272-557X</orcidid></search><sort><creationdate>20220908</creationdate><title>Fire-Retardant Property of Hexasubstituted Cyclotriphosphazene Derivatives with Schiff Base Linking Unit Applied as an Additives in Polyurethane Coating for Wood Fabrication</title><author>Mohd Taip, Nurul Atiqah ; Jamain, Zuhair ; Palle, Ismawati</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c361t-a0ba988b7c65de9799db4672f2e7e264285b4591b07ba6f872fccd2977014fad3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Additives</topic><topic>Chemical analysis</topic><topic>Coating</topic><topic>Coatings</topic><topic>Coatings industry</topic><topic>Fireproofing agents</topic><topic>Flame retardants</topic><topic>Fourier transforms</topic><topic>Hydrogen</topic><topic>Imines</topic><topic>Infrared spectroscopy</topic><topic>Nitrogen</topic><topic>NMR spectroscopy</topic><topic>Nuclear magnetic resonance spectroscopy</topic><topic>Phosphorus</topic><topic>Polyurethane resins</topic><topic>Polyurethanes</topic><topic>Potash</topic><topic>Potassium</topic><topic>Schiff bases</topic><topic>Spectrum analysis</topic><topic>Stability analysis</topic><topic>Thermal stability</topic><topic>Thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mohd Taip, Nurul Atiqah</creatorcontrib><creatorcontrib>Jamain, Zuhair</creatorcontrib><creatorcontrib>Palle, Ismawati</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mohd Taip, Nurul Atiqah</au><au>Jamain, Zuhair</au><au>Palle, Ismawati</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fire-Retardant Property of Hexasubstituted Cyclotriphosphazene Derivatives with Schiff Base Linking Unit Applied as an Additives in Polyurethane Coating for Wood Fabrication</atitle><jtitle>Polymers</jtitle><date>2022-09-08</date><risdate>2022</risdate><volume>14</volume><issue>18</issue><spage>3768</spage><pages>3768-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>A series of new hexasubstituted cyclotriphosphaze derivatives containing Schiff base linkages were successfully synthesized and characterized. The series contains different terminal substituents of pentyl and tetradecyl. Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (NMR), and carbon, hydrogen, and nitrogen (CHN) elemental analysis were used to characterize the intermediates and final compounds, while the thermal stability of the final compounds is evaluated with a thermogravimetric analysis (TGA) test. The final compounds are physically added to the polyurethane coating formulation and then applied to the wood panel using a brush and the compound’s fire-retardant properties are evaluated using the limiting oxygen index (LOI) test. In this research, compound 3b showed good thermal stability compared to compound 3a. In terms of LOI results, polyurethane with an LOI value of 21.90% was employed as a matrix for wood coating and the value increased to 24.90% when this polyurethane is incorporated with 1 wt.% of the compound 3b. 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| subjects | Additives Chemical analysis Coating Coatings Coatings industry Fireproofing agents Flame retardants Fourier transforms Hydrogen Imines Infrared spectroscopy Nitrogen NMR spectroscopy Nuclear magnetic resonance spectroscopy Phosphorus Polyurethane resins Polyurethanes Potash Potassium Schiff bases Spectrum analysis Stability analysis Thermal stability Thermogravimetric analysis |
| title | Fire-Retardant Property of Hexasubstituted Cyclotriphosphazene Derivatives with Schiff Base Linking Unit Applied as an Additives in Polyurethane Coating for Wood Fabrication |
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