Effect of the Synthesis Conditions of MIL-100(Fe) on Its Catalytic Properties and Stability under Reaction Conditions
MIL-100(Fe) is a metal–organic framework (MOF) characterized by the presence of Lewis acid and Fe(II/III) redox sites. In this work, different synthesis methods for the preparation of MIL-100(Fe) are studied. Depending on the source of fluorine, different phases can be obtained: MIL-100(Fe) and an F...
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| Veröffentlicht in: | Materials 2022-09, Vol.15 (18), p.6499 |
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| creator | Delgado-Marín, José J. Narciso, Javier Ramos-Fernández, Enrique V. |
| description | MIL-100(Fe) is a metal–organic framework (MOF) characterized by the presence of Lewis acid and Fe(II/III) redox sites. In this work, different synthesis methods for the preparation of MIL-100(Fe) are studied. Depending on the source of fluorine, different phases can be obtained: MIL-100(Fe) and an Fe trimesate with unknown structure which we call Fe(BTC). These materials were characterized using numerous techniques and applied in the reaction of CO2 cycloaddition with epichlorohydrin, a reaction catalyzed by Lewis acid sites. It was observed that samples with more Fe(BTC) phase were more active in the reaction. However, all samples, under reaction conditions, transformed into a less active phase. |
| doi_str_mv | 10.3390/ma15186499 |
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In this work, different synthesis methods for the preparation of MIL-100(Fe) are studied. Depending on the source of fluorine, different phases can be obtained: MIL-100(Fe) and an Fe trimesate with unknown structure which we call Fe(BTC). These materials were characterized using numerous techniques and applied in the reaction of CO2 cycloaddition with epichlorohydrin, a reaction catalyzed by Lewis acid sites. It was observed that samples with more Fe(BTC) phase were more active in the reaction. 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In this work, different synthesis methods for the preparation of MIL-100(Fe) are studied. Depending on the source of fluorine, different phases can be obtained: MIL-100(Fe) and an Fe trimesate with unknown structure which we call Fe(BTC). These materials were characterized using numerous techniques and applied in the reaction of CO2 cycloaddition with epichlorohydrin, a reaction catalyzed by Lewis acid sites. It was observed that samples with more Fe(BTC) phase were more active in the reaction. 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In this work, different synthesis methods for the preparation of MIL-100(Fe) are studied. Depending on the source of fluorine, different phases can be obtained: MIL-100(Fe) and an Fe trimesate with unknown structure which we call Fe(BTC). These materials were characterized using numerous techniques and applied in the reaction of CO2 cycloaddition with epichlorohydrin, a reaction catalyzed by Lewis acid sites. It was observed that samples with more Fe(BTC) phase were more active in the reaction. However, all samples, under reaction conditions, transformed into a less active phase.</abstract><cop>Basel</cop><pub>MDPI AG</pub><pmid>36143813</pmid><doi>10.3390/ma15186499</doi><orcidid>https://orcid.org/0000-0001-6357-0383</orcidid><orcidid>https://orcid.org/0000-0002-3625-4550</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Acids Adsorption Analysis Aqueous solutions Carbon dioxide Catalysis Chemical properties Cycloaddition Epichlorohydrin Ethanol Fluorides Fluorine Iron Lewis acid Ligands Metal ions Metal-organic frameworks Metals Phase transformations (Statistical physics) Potassium Testing |
| title | Effect of the Synthesis Conditions of MIL-100(Fe) on Its Catalytic Properties and Stability under Reaction Conditions |
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