Fabrication of P/N/B-Based Intumescent Flame-Retardant Coating for Polyester/Cotton Blend Fabric
Polyester/cotton (T/C) blend fabrics are highly flammable due to the particular “scaffolding effect”. In this work, an intumescent flame retardant (IFR) agent containing P, N, and B was designed and synthesized using bio-based phytic acid, pentaerythritol, boric acid, and urea. The IFR compounds wer...
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| Veröffentlicht in: | Materials 2022-09, Vol.15 (18), p.6420 |
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| creator | He, Wei-Lin Huang, Yi-Ting Gu, Liang Shen, Ji-Cheng Cheng, Xian-Wei Guan, Jin-Ping |
| description | Polyester/cotton (T/C) blend fabrics are highly flammable due to the particular “scaffolding effect”. In this work, an intumescent flame retardant (IFR) agent containing P, N, and B was designed and synthesized using bio-based phytic acid, pentaerythritol, boric acid, and urea. The IFR compounds were deposited onto a T/C blend fabric by the surface-coating route. The chemical structure of IFR agent and its potential cross-linking reactions with T/C fibers were characterized. The morphology, thermal stability, heat-release ability, flame retardancy, and mechanism of coated T/C blend fabrics were explored. The self-extinguishing action was observed for the coated T/C blend fabric with a weight gain of 13.7%; the limiting oxygen index (LOI) value increased to 27.1% versus 16.9% for a pristine one. Furthermore, the intumescent flame retardant (IFR) coating imparted T/C blend fabrics with high thermal stability and significantly suppressed heat release by nearly 50%. The char residue analyses on morphology and element content confirmed the intumescent FR action for coated T/C blend fabrics. The prepared IFR coating has great potential to serve as an eco-friendly approach for improving the flame retardancy of T/C blend textiles. |
| doi_str_mv | 10.3390/ma15186420 |
| format | Article |
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In this work, an intumescent flame retardant (IFR) agent containing P, N, and B was designed and synthesized using bio-based phytic acid, pentaerythritol, boric acid, and urea. The IFR compounds were deposited onto a T/C blend fabric by the surface-coating route. The chemical structure of IFR agent and its potential cross-linking reactions with T/C fibers were characterized. The morphology, thermal stability, heat-release ability, flame retardancy, and mechanism of coated T/C blend fabrics were explored. The self-extinguishing action was observed for the coated T/C blend fabric with a weight gain of 13.7%; the limiting oxygen index (LOI) value increased to 27.1% versus 16.9% for a pristine one. Furthermore, the intumescent flame retardant (IFR) coating imparted T/C blend fabrics with high thermal stability and significantly suppressed heat release by nearly 50%. The char residue analyses on morphology and element content confirmed the intumescent FR action for coated T/C blend fabrics. The prepared IFR coating has great potential to serve as an eco-friendly approach for improving the flame retardancy of T/C blend textiles.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma15186420</identifier><identifier>PMID: 36143732</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Cellulose fibers ; Chemical properties ; Chemical reactions ; Coating ; Coatings ; Cotton ; Cotton fabrics ; Cotton textiles ; Crosslinking ; Fabrics ; Fire hazards ; Fireproofing agents ; Flame retardants ; Morphology ; NMR ; Nuclear magnetic resonance ; Permeability ; Phosphorus ; Phytic acid ; Polyesters ; Production processes ; Scaffolding ; Specialty products ; Spectrum analysis ; Textile composites ; Textiles ; Thermal properties ; Thermal stability ; Vacuum distillation</subject><ispartof>Materials, 2022-09, Vol.15 (18), p.6420</ispartof><rights>COPYRIGHT 2022 MDPI AG</rights><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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In this work, an intumescent flame retardant (IFR) agent containing P, N, and B was designed and synthesized using bio-based phytic acid, pentaerythritol, boric acid, and urea. The IFR compounds were deposited onto a T/C blend fabric by the surface-coating route. The chemical structure of IFR agent and its potential cross-linking reactions with T/C fibers were characterized. The morphology, thermal stability, heat-release ability, flame retardancy, and mechanism of coated T/C blend fabrics were explored. The self-extinguishing action was observed for the coated T/C blend fabric with a weight gain of 13.7%; the limiting oxygen index (LOI) value increased to 27.1% versus 16.9% for a pristine one. Furthermore, the intumescent flame retardant (IFR) coating imparted T/C blend fabrics with high thermal stability and significantly suppressed heat release by nearly 50%. The char residue analyses on morphology and element content confirmed the intumescent FR action for coated T/C blend fabrics. The prepared IFR coating has great potential to serve as an eco-friendly approach for improving the flame retardancy of T/C blend textiles.</description><subject>Cellulose fibers</subject><subject>Chemical properties</subject><subject>Chemical reactions</subject><subject>Coating</subject><subject>Coatings</subject><subject>Cotton</subject><subject>Cotton fabrics</subject><subject>Cotton textiles</subject><subject>Crosslinking</subject><subject>Fabrics</subject><subject>Fire hazards</subject><subject>Fireproofing agents</subject><subject>Flame retardants</subject><subject>Morphology</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Permeability</subject><subject>Phosphorus</subject><subject>Phytic acid</subject><subject>Polyesters</subject><subject>Production processes</subject><subject>Scaffolding</subject><subject>Specialty products</subject><subject>Spectrum analysis</subject><subject>Textile composites</subject><subject>Textiles</subject><subject>Thermal properties</subject><subject>Thermal stability</subject><subject>Vacuum distillation</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdUU1P3DAQtVArQFsu_IJIXFClsB47seMLErvqFiTUogrOxutMFqPEBjupxL-vV4v4qOdgj_3e87wZQo6BnnGu6HwwUEMjKkb3yCEoJUpQVfXlw_mAHKX0SPPiHBqm9skBF1BxydkhuV-ZdXTWjC74InTFzfzXfFEuTMK2uPLjNGCy6Mdi1ZsByz84mtianC9DpvhN0YVY3IT-BdOIcb4M45h1Fj36ttgpfyNfO9MnPHrdZ-Ru9eN2eVle__55tby4Li2v2Vi2INBSlFUNrWBt1QhLYd1ALZhpDBMcOl4pS2tJ0UiGtpJKILXArAAQHZ-R853u07QesN0WHU2vn6IbTHzRwTj9-cW7B70Jf7WqKWx7MyOnrwIxPE_Zjx5c9t73xmOYkmYSpGiUAJahJ_9BH8MUfba3RYm6gdzojDrboTamR-18F_K_NkeLg7PBY-fy_UW2LLmSTGXC9x3BxpBSxO6teqB6O2z9Pmz-D03imME</recordid><startdate>20220915</startdate><enddate>20220915</enddate><creator>He, Wei-Lin</creator><creator>Huang, Yi-Ting</creator><creator>Gu, Liang</creator><creator>Shen, Ji-Cheng</creator><creator>Cheng, Xian-Wei</creator><creator>Guan, Jin-Ping</creator><general>MDPI AG</general><general>MDPI</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20220915</creationdate><title>Fabrication of P/N/B-Based Intumescent Flame-Retardant Coating for Polyester/Cotton Blend Fabric</title><author>He, Wei-Lin ; Huang, Yi-Ting ; Gu, Liang ; Shen, Ji-Cheng ; Cheng, Xian-Wei ; Guan, Jin-Ping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c352t-d16ec0e7451d62d486c01b81562a8a2631f349c0570ea72ec4796e0c12c6116f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Cellulose fibers</topic><topic>Chemical properties</topic><topic>Chemical reactions</topic><topic>Coating</topic><topic>Coatings</topic><topic>Cotton</topic><topic>Cotton fabrics</topic><topic>Cotton textiles</topic><topic>Crosslinking</topic><topic>Fabrics</topic><topic>Fire hazards</topic><topic>Fireproofing agents</topic><topic>Flame retardants</topic><topic>Morphology</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Permeability</topic><topic>Phosphorus</topic><topic>Phytic acid</topic><topic>Polyesters</topic><topic>Production processes</topic><topic>Scaffolding</topic><topic>Specialty products</topic><topic>Spectrum analysis</topic><topic>Textile composites</topic><topic>Textiles</topic><topic>Thermal properties</topic><topic>Thermal stability</topic><topic>Vacuum distillation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>He, Wei-Lin</creatorcontrib><creatorcontrib>Huang, Yi-Ting</creatorcontrib><creatorcontrib>Gu, Liang</creatorcontrib><creatorcontrib>Shen, Ji-Cheng</creatorcontrib><creatorcontrib>Cheng, Xian-Wei</creatorcontrib><creatorcontrib>Guan, Jin-Ping</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>He, Wei-Lin</au><au>Huang, Yi-Ting</au><au>Gu, Liang</au><au>Shen, Ji-Cheng</au><au>Cheng, Xian-Wei</au><au>Guan, Jin-Ping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication of P/N/B-Based Intumescent Flame-Retardant Coating for Polyester/Cotton Blend Fabric</atitle><jtitle>Materials</jtitle><date>2022-09-15</date><risdate>2022</risdate><volume>15</volume><issue>18</issue><spage>6420</spage><pages>6420-</pages><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>Polyester/cotton (T/C) blend fabrics are highly flammable due to the particular “scaffolding effect”. In this work, an intumescent flame retardant (IFR) agent containing P, N, and B was designed and synthesized using bio-based phytic acid, pentaerythritol, boric acid, and urea. The IFR compounds were deposited onto a T/C blend fabric by the surface-coating route. The chemical structure of IFR agent and its potential cross-linking reactions with T/C fibers were characterized. The morphology, thermal stability, heat-release ability, flame retardancy, and mechanism of coated T/C blend fabrics were explored. The self-extinguishing action was observed for the coated T/C blend fabric with a weight gain of 13.7%; the limiting oxygen index (LOI) value increased to 27.1% versus 16.9% for a pristine one. Furthermore, the intumescent flame retardant (IFR) coating imparted T/C blend fabrics with high thermal stability and significantly suppressed heat release by nearly 50%. The char residue analyses on morphology and element content confirmed the intumescent FR action for coated T/C blend fabrics. The prepared IFR coating has great potential to serve as an eco-friendly approach for improving the flame retardancy of T/C blend textiles.</abstract><cop>Basel</cop><pub>MDPI AG</pub><pmid>36143732</pmid><doi>10.3390/ma15186420</doi><oa>free_for_read</oa></addata></record> |
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| ispartof | Materials, 2022-09, Vol.15 (18), p.6420 |
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| source | MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access |
| subjects | Cellulose fibers Chemical properties Chemical reactions Coating Coatings Cotton Cotton fabrics Cotton textiles Crosslinking Fabrics Fire hazards Fireproofing agents Flame retardants Morphology NMR Nuclear magnetic resonance Permeability Phosphorus Phytic acid Polyesters Production processes Scaffolding Specialty products Spectrum analysis Textile composites Textiles Thermal properties Thermal stability Vacuum distillation |
| title | Fabrication of P/N/B-Based Intumescent Flame-Retardant Coating for Polyester/Cotton Blend Fabric |
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