Recent Advances in the Copolymerization of Ethylene with Polar Comonomers by Nickel Catalysts
The less-expensive and earth-abundant nickel catalyst is highly promising in the copolymerization of ethylene with polar monomers and has thus attracted increasing attention in both industry and academia. Herein, we have summarized the recent advancements made in the state-of-the-art nickel catalyst...
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| Veröffentlicht in: | Polymers 2022-09, Vol.14 (18), p.3809 |
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| creator | Zhang, Randi Gao, Rong Gou, Qingqiang Lai, Jingjing Li, Xinyang |
| description | The less-expensive and earth-abundant nickel catalyst is highly promising in the copolymerization of ethylene with polar monomers and has thus attracted increasing attention in both industry and academia. Herein, we have summarized the recent advancements made in the state-of-the-art nickel catalysts with different types of ligands for ethylene copolymerization and how these modifications influence the catalyst performance, as well as new polymerization modulation strategies. With regard to α-diimine, salicylaldimine/ketoiminato, phosphino-phenolate, phosphine-sulfonate, bisphospnine monoxide,
-heterocyclic carbene and other unclassified chelates, the properties of each catalyst and fine modulation of key copolymerization parameters (activity, molecular weight, comonomer incorporation rate, etc.) are revealed in detail. Despite significant achievements, many opportunities and possibilities are yet to be fully addressed, and a brief outlook on the future development and long-standing challenges is provided. |
| doi_str_mv | 10.3390/polym14183809 |
| format | Article |
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-heterocyclic carbene and other unclassified chelates, the properties of each catalyst and fine modulation of key copolymerization parameters (activity, molecular weight, comonomer incorporation rate, etc.) are revealed in detail. Despite significant achievements, many opportunities and possibilities are yet to be fully addressed, and a brief outlook on the future development and long-standing challenges is provided.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym14183809</identifier><identifier>PMID: 36145954</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Catalysts ; Chelates ; Copolymerization ; Design ; Ethylene ; Ligands ; Modulation ; Molecular weight ; Nickel ; Palladium ; Phosphines ; Poisoning ; Poisons ; Polyethylene ; Polymerization ; Polymers ; Review</subject><ispartof>Polymers, 2022-09, Vol.14 (18), p.3809</ispartof><rights>COPYRIGHT 2022 MDPI AG</rights><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2022 by the authors. 2022</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c454t-e78fadc5066ea23645a25de669a0ea0429821b6329ed83b70961e46b526717ae3</citedby><cites>FETCH-LOGICAL-c454t-e78fadc5066ea23645a25de669a0ea0429821b6329ed83b70961e46b526717ae3</cites><orcidid>0000-0002-7967-167X ; 0000-0001-8178-9207</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9500745/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9500745/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36145954$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Randi</creatorcontrib><creatorcontrib>Gao, Rong</creatorcontrib><creatorcontrib>Gou, Qingqiang</creatorcontrib><creatorcontrib>Lai, Jingjing</creatorcontrib><creatorcontrib>Li, Xinyang</creatorcontrib><title>Recent Advances in the Copolymerization of Ethylene with Polar Comonomers by Nickel Catalysts</title><title>Polymers</title><addtitle>Polymers (Basel)</addtitle><description>The less-expensive and earth-abundant nickel catalyst is highly promising in the copolymerization of ethylene with polar monomers and has thus attracted increasing attention in both industry and academia. Herein, we have summarized the recent advancements made in the state-of-the-art nickel catalysts with different types of ligands for ethylene copolymerization and how these modifications influence the catalyst performance, as well as new polymerization modulation strategies. With regard to α-diimine, salicylaldimine/ketoiminato, phosphino-phenolate, phosphine-sulfonate, bisphospnine monoxide,
-heterocyclic carbene and other unclassified chelates, the properties of each catalyst and fine modulation of key copolymerization parameters (activity, molecular weight, comonomer incorporation rate, etc.) are revealed in detail. Despite significant achievements, many opportunities and possibilities are yet to be fully addressed, and a brief outlook on the future development and long-standing challenges is provided.</description><subject>Catalysts</subject><subject>Chelates</subject><subject>Copolymerization</subject><subject>Design</subject><subject>Ethylene</subject><subject>Ligands</subject><subject>Modulation</subject><subject>Molecular weight</subject><subject>Nickel</subject><subject>Palladium</subject><subject>Phosphines</subject><subject>Poisoning</subject><subject>Poisons</subject><subject>Polyethylene</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Review</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkc9rFDEUx4MottQevUrAi5ep-T2Ti7As1QpFRfQoITPzppuaSdYkWxn_-mbdWlqTQx7J532_-fIQeknJGeeavN1Gv8xU0I53RD9Bx4y0vBFckacP6iN0mvM1qUtIpWj7HB1xRYXUUhyjH19hgFDwaryxYYCMXcBlA3gd_2pDcn9scTHgOOHzslk8BMC_XdngL9HbVLk5hli5jPsFf3LDT_B4bYv1Sy75BXo2WZ_h9O48Qd_fn39bXzSXnz98XK8um0FIURpou8mOgyRKgWVcCWmZHEEpbQlYIpjuGO0VZxrGjvct0YqCUL1kqqWtBX6C3h10t7t-hnGfKFlvtsnNNi0mWmcevwS3MVfxxmhJSCtkFXhzJ5Dirx3kYmaXB_DeBoi7bFj1UV01ZhV9_R96HXcp1Hh7SkmtNaOVOjtQV9aDcWGK1Xeoe4TZDTHA5Or9qhVKcE2lrg3NoWFIMecE0_3vKTH7YZtHw678q4eR7-l_o-W30Hel0w</recordid><startdate>20220912</startdate><enddate>20220912</enddate><creator>Zhang, Randi</creator><creator>Gao, Rong</creator><creator>Gou, Qingqiang</creator><creator>Lai, Jingjing</creator><creator>Li, Xinyang</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-7967-167X</orcidid><orcidid>https://orcid.org/0000-0001-8178-9207</orcidid></search><sort><creationdate>20220912</creationdate><title>Recent Advances in the Copolymerization of Ethylene with Polar Comonomers by Nickel Catalysts</title><author>Zhang, Randi ; Gao, Rong ; Gou, Qingqiang ; Lai, Jingjing ; Li, Xinyang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c454t-e78fadc5066ea23645a25de669a0ea0429821b6329ed83b70961e46b526717ae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Catalysts</topic><topic>Chelates</topic><topic>Copolymerization</topic><topic>Design</topic><topic>Ethylene</topic><topic>Ligands</topic><topic>Modulation</topic><topic>Molecular weight</topic><topic>Nickel</topic><topic>Palladium</topic><topic>Phosphines</topic><topic>Poisoning</topic><topic>Poisons</topic><topic>Polyethylene</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Review</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Randi</creatorcontrib><creatorcontrib>Gao, Rong</creatorcontrib><creatorcontrib>Gou, Qingqiang</creatorcontrib><creatorcontrib>Lai, Jingjing</creatorcontrib><creatorcontrib>Li, Xinyang</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials science collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Randi</au><au>Gao, Rong</au><au>Gou, Qingqiang</au><au>Lai, Jingjing</au><au>Li, Xinyang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Recent Advances in the Copolymerization of Ethylene with Polar Comonomers by Nickel Catalysts</atitle><jtitle>Polymers</jtitle><addtitle>Polymers (Basel)</addtitle><date>2022-09-12</date><risdate>2022</risdate><volume>14</volume><issue>18</issue><spage>3809</spage><pages>3809-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>The less-expensive and earth-abundant nickel catalyst is highly promising in the copolymerization of ethylene with polar monomers and has thus attracted increasing attention in both industry and academia. Herein, we have summarized the recent advancements made in the state-of-the-art nickel catalysts with different types of ligands for ethylene copolymerization and how these modifications influence the catalyst performance, as well as new polymerization modulation strategies. With regard to α-diimine, salicylaldimine/ketoiminato, phosphino-phenolate, phosphine-sulfonate, bisphospnine monoxide,
-heterocyclic carbene and other unclassified chelates, the properties of each catalyst and fine modulation of key copolymerization parameters (activity, molecular weight, comonomer incorporation rate, etc.) are revealed in detail. Despite significant achievements, many opportunities and possibilities are yet to be fully addressed, and a brief outlook on the future development and long-standing challenges is provided.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>36145954</pmid><doi>10.3390/polym14183809</doi><orcidid>https://orcid.org/0000-0002-7967-167X</orcidid><orcidid>https://orcid.org/0000-0001-8178-9207</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Catalysts Chelates Copolymerization Design Ethylene Ligands Modulation Molecular weight Nickel Palladium Phosphines Poisoning Poisons Polyethylene Polymerization Polymers Review |
| title | Recent Advances in the Copolymerization of Ethylene with Polar Comonomers by Nickel Catalysts |
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