Mixed-Matrix Membranes Based on Polyetherimide, Metal–Organic Framework and Ionic Liquid: Influence of the Composition and Morphology on Gas Transport Properties
In this work, membranes based on polyetherimide (PEI), a ZIF-8 metal–organic framework and 1-ethyl-methylimidazolium tetrafluoroborate ionic liquid (IL) were prepared. IL and ZIF-8 contents amounting to 7 wt% and 25 wt%, respectively, were investigated. CO2, He and H2 transport properties of PEI/IL/...
Gespeichert in:
| Veröffentlicht in: | Polymers 2022-08, Vol.14 (17), p.3489 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 17 |
| container_start_page | 3489 |
| container_title | Polymers |
| container_volume | 14 |
| creator | Zid, Sarra Alcouffe, Pierre Zinet, Matthieu Espuche, Eliane |
| description | In this work, membranes based on polyetherimide (PEI), a ZIF-8 metal–organic framework and 1-ethyl-methylimidazolium tetrafluoroborate ionic liquid (IL) were prepared. IL and ZIF-8 contents amounting to 7 wt% and 25 wt%, respectively, were investigated. CO2, He and H2 transport properties of PEI/IL/ZIF-8 membranes were compared to those obtained for the respective PEI/ZIF-8 and PEI/IL systems. Membranes’ gas permeability and selectivity are discussed as a function of the membrane composition and morphology, and they were assessed in relation to existing experimental and theoretical data from the literature. Promising gas transport properties were obtained using the appropriate combination of ZIF-8 and IL amounts in the PEI matrix. Indeed, an increase in the CO2 permeability coefficient by a factor of around 7.5 and the He and H2 permeability coefficients by a factor of around 4 was achieved by adding 7 wt% IL and 10 wt% ZIF-8 to the PEI matrix. Moreover, diffusion was evidenced as a governing factor in the studied membrane series. |
| doi_str_mv | 10.3390/polym14173489 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9460398</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A746438443</galeid><sourcerecordid>A746438443</sourcerecordid><originalsourceid>FETCH-LOGICAL-c465t-e4905a25c7767f4a7ec5abc2675fd59d2cf86502e1076600ac979121cbc539e3</originalsourceid><addsrcrecordid>eNpdUstu3CAUtapWTZRm2T1SN61Up2AwmC4qTUd5jDSjZDF7xODrGVIbHLDTzK7_kE_on_VLijVR1QQWoMO55xyubpa9J_iMUom_9L7dd4QRQVklX2XHBRY0Z5Tj1__dj7LTGG9xWqzknIi32VFCK1zy4jj7vbIPUOcrPQT7gFbQbYJ2ENF3HaFG3qGbZAHDDoLtbA2fE2XQ7Z9fj9dhq5016CLoDn768ANpV6OFn7ClvRtt_RUtXNOO4Awg36Ckgea-6320g03CE33lQ7_zrd_uJ6tLHdE62cfehwHdBN9DGCzEd9mbRrcRTp_Ok2x9cb6eX-XL68vFfLbMDePlkAOTuNRFaYTgomFagCn1xhRclE1dyrowTcVLXADBgnOMtZFCkoKYjSmpBHqSfTvI9uOmg9qAG4JuVZ9-rsNeeW3V8xdnd2rr75VkHFNZJYFPB4Hdi7Kr2VJNGGaEpgT0niTuxyez4O9GiIPqbDTQtqn7foyqEKSoUiw6yX54Qb31Y3CpExOLMMkIl4l1dmBtdQvKusanjCbtGjprvIPGJnwmGGe0YoymgvxQYIKPMUDzLzLBapou9Wy66F9MYsQZ</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2711494169</pqid></control><display><type>article</type><title>Mixed-Matrix Membranes Based on Polyetherimide, Metal–Organic Framework and Ionic Liquid: Influence of the Composition and Morphology on Gas Transport Properties</title><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>PubMed Central</source><source>PubMed Central Open Access</source><creator>Zid, Sarra ; Alcouffe, Pierre ; Zinet, Matthieu ; Espuche, Eliane</creator><creatorcontrib>Zid, Sarra ; Alcouffe, Pierre ; Zinet, Matthieu ; Espuche, Eliane</creatorcontrib><description>In this work, membranes based on polyetherimide (PEI), a ZIF-8 metal–organic framework and 1-ethyl-methylimidazolium tetrafluoroborate ionic liquid (IL) were prepared. IL and ZIF-8 contents amounting to 7 wt% and 25 wt%, respectively, were investigated. CO2, He and H2 transport properties of PEI/IL/ZIF-8 membranes were compared to those obtained for the respective PEI/ZIF-8 and PEI/IL systems. Membranes’ gas permeability and selectivity are discussed as a function of the membrane composition and morphology, and they were assessed in relation to existing experimental and theoretical data from the literature. Promising gas transport properties were obtained using the appropriate combination of ZIF-8 and IL amounts in the PEI matrix. Indeed, an increase in the CO2 permeability coefficient by a factor of around 7.5 and the He and H2 permeability coefficients by a factor of around 4 was achieved by adding 7 wt% IL and 10 wt% ZIF-8 to the PEI matrix. Moreover, diffusion was evidenced as a governing factor in the studied membrane series.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym14173489</identifier><identifier>PMID: 36080562</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Carbon dioxide ; Chemical engineering ; Chemical Sciences ; Composition ; Gas transport ; Gases ; Ionic liquids ; Membrane separation ; Membranes ; Metal-organic frameworks ; Morphology ; Permeability ; Polyetherimide ; Polyetherimides ; Polymers ; Selectivity ; Transport properties</subject><ispartof>Polymers, 2022-08, Vol.14 (17), p.3489</ispartof><rights>COPYRIGHT 2022 MDPI AG</rights><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><rights>2022 by the authors. 2022</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c465t-e4905a25c7767f4a7ec5abc2675fd59d2cf86502e1076600ac979121cbc539e3</citedby><cites>FETCH-LOGICAL-c465t-e4905a25c7767f4a7ec5abc2675fd59d2cf86502e1076600ac979121cbc539e3</cites><orcidid>0000-0002-0178-2062 ; 0000-0003-1742-4478</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9460398/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9460398/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://hal.science/hal-04136503$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Zid, Sarra</creatorcontrib><creatorcontrib>Alcouffe, Pierre</creatorcontrib><creatorcontrib>Zinet, Matthieu</creatorcontrib><creatorcontrib>Espuche, Eliane</creatorcontrib><title>Mixed-Matrix Membranes Based on Polyetherimide, Metal–Organic Framework and Ionic Liquid: Influence of the Composition and Morphology on Gas Transport Properties</title><title>Polymers</title><description>In this work, membranes based on polyetherimide (PEI), a ZIF-8 metal–organic framework and 1-ethyl-methylimidazolium tetrafluoroborate ionic liquid (IL) were prepared. IL and ZIF-8 contents amounting to 7 wt% and 25 wt%, respectively, were investigated. CO2, He and H2 transport properties of PEI/IL/ZIF-8 membranes were compared to those obtained for the respective PEI/ZIF-8 and PEI/IL systems. Membranes’ gas permeability and selectivity are discussed as a function of the membrane composition and morphology, and they were assessed in relation to existing experimental and theoretical data from the literature. Promising gas transport properties were obtained using the appropriate combination of ZIF-8 and IL amounts in the PEI matrix. Indeed, an increase in the CO2 permeability coefficient by a factor of around 7.5 and the He and H2 permeability coefficients by a factor of around 4 was achieved by adding 7 wt% IL and 10 wt% ZIF-8 to the PEI matrix. Moreover, diffusion was evidenced as a governing factor in the studied membrane series.</description><subject>Carbon dioxide</subject><subject>Chemical engineering</subject><subject>Chemical Sciences</subject><subject>Composition</subject><subject>Gas transport</subject><subject>Gases</subject><subject>Ionic liquids</subject><subject>Membrane separation</subject><subject>Membranes</subject><subject>Metal-organic frameworks</subject><subject>Morphology</subject><subject>Permeability</subject><subject>Polyetherimide</subject><subject>Polyetherimides</subject><subject>Polymers</subject><subject>Selectivity</subject><subject>Transport properties</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdUstu3CAUtapWTZRm2T1SN61Up2AwmC4qTUd5jDSjZDF7xODrGVIbHLDTzK7_kE_on_VLijVR1QQWoMO55xyubpa9J_iMUom_9L7dd4QRQVklX2XHBRY0Z5Tj1__dj7LTGG9xWqzknIi32VFCK1zy4jj7vbIPUOcrPQT7gFbQbYJ2ENF3HaFG3qGbZAHDDoLtbA2fE2XQ7Z9fj9dhq5016CLoDn768ANpV6OFn7ClvRtt_RUtXNOO4Awg36Ckgea-6320g03CE33lQ7_zrd_uJ6tLHdE62cfehwHdBN9DGCzEd9mbRrcRTp_Ok2x9cb6eX-XL68vFfLbMDePlkAOTuNRFaYTgomFagCn1xhRclE1dyrowTcVLXADBgnOMtZFCkoKYjSmpBHqSfTvI9uOmg9qAG4JuVZ9-rsNeeW3V8xdnd2rr75VkHFNZJYFPB4Hdi7Kr2VJNGGaEpgT0niTuxyez4O9GiIPqbDTQtqn7foyqEKSoUiw6yX54Qb31Y3CpExOLMMkIl4l1dmBtdQvKusanjCbtGjprvIPGJnwmGGe0YoymgvxQYIKPMUDzLzLBapou9Wy66F9MYsQZ</recordid><startdate>20220825</startdate><enddate>20220825</enddate><creator>Zid, Sarra</creator><creator>Alcouffe, Pierre</creator><creator>Zinet, Matthieu</creator><creator>Espuche, Eliane</creator><general>MDPI AG</general><general>MDPI</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>1XC</scope><scope>VOOES</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-0178-2062</orcidid><orcidid>https://orcid.org/0000-0003-1742-4478</orcidid></search><sort><creationdate>20220825</creationdate><title>Mixed-Matrix Membranes Based on Polyetherimide, Metal–Organic Framework and Ionic Liquid: Influence of the Composition and Morphology on Gas Transport Properties</title><author>Zid, Sarra ; Alcouffe, Pierre ; Zinet, Matthieu ; Espuche, Eliane</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c465t-e4905a25c7767f4a7ec5abc2675fd59d2cf86502e1076600ac979121cbc539e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Carbon dioxide</topic><topic>Chemical engineering</topic><topic>Chemical Sciences</topic><topic>Composition</topic><topic>Gas transport</topic><topic>Gases</topic><topic>Ionic liquids</topic><topic>Membrane separation</topic><topic>Membranes</topic><topic>Metal-organic frameworks</topic><topic>Morphology</topic><topic>Permeability</topic><topic>Polyetherimide</topic><topic>Polyetherimides</topic><topic>Polymers</topic><topic>Selectivity</topic><topic>Transport properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zid, Sarra</creatorcontrib><creatorcontrib>Alcouffe, Pierre</creatorcontrib><creatorcontrib>Zinet, Matthieu</creatorcontrib><creatorcontrib>Espuche, Eliane</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zid, Sarra</au><au>Alcouffe, Pierre</au><au>Zinet, Matthieu</au><au>Espuche, Eliane</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mixed-Matrix Membranes Based on Polyetherimide, Metal–Organic Framework and Ionic Liquid: Influence of the Composition and Morphology on Gas Transport Properties</atitle><jtitle>Polymers</jtitle><date>2022-08-25</date><risdate>2022</risdate><volume>14</volume><issue>17</issue><spage>3489</spage><pages>3489-</pages><issn>2073-4360</issn><eissn>2073-4360</eissn><abstract>In this work, membranes based on polyetherimide (PEI), a ZIF-8 metal–organic framework and 1-ethyl-methylimidazolium tetrafluoroborate ionic liquid (IL) were prepared. IL and ZIF-8 contents amounting to 7 wt% and 25 wt%, respectively, were investigated. CO2, He and H2 transport properties of PEI/IL/ZIF-8 membranes were compared to those obtained for the respective PEI/ZIF-8 and PEI/IL systems. Membranes’ gas permeability and selectivity are discussed as a function of the membrane composition and morphology, and they were assessed in relation to existing experimental and theoretical data from the literature. Promising gas transport properties were obtained using the appropriate combination of ZIF-8 and IL amounts in the PEI matrix. Indeed, an increase in the CO2 permeability coefficient by a factor of around 7.5 and the He and H2 permeability coefficients by a factor of around 4 was achieved by adding 7 wt% IL and 10 wt% ZIF-8 to the PEI matrix. Moreover, diffusion was evidenced as a governing factor in the studied membrane series.</abstract><cop>Basel</cop><pub>MDPI AG</pub><pmid>36080562</pmid><doi>10.3390/polym14173489</doi><orcidid>https://orcid.org/0000-0002-0178-2062</orcidid><orcidid>https://orcid.org/0000-0003-1742-4478</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2073-4360 |
| ispartof | Polymers, 2022-08, Vol.14 (17), p.3489 |
| issn | 2073-4360 2073-4360 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9460398 |
| source | MDPI - Multidisciplinary Digital Publishing Institute; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; PubMed Central Open Access |
| subjects | Carbon dioxide Chemical engineering Chemical Sciences Composition Gas transport Gases Ionic liquids Membrane separation Membranes Metal-organic frameworks Morphology Permeability Polyetherimide Polyetherimides Polymers Selectivity Transport properties |
| title | Mixed-Matrix Membranes Based on Polyetherimide, Metal–Organic Framework and Ionic Liquid: Influence of the Composition and Morphology on Gas Transport Properties |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-13T01%3A53%3A45IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Mixed-Matrix%20Membranes%20Based%20on%20Polyetherimide,%20Metal%E2%80%93Organic%20Framework%20and%20Ionic%20Liquid:%20Influence%20of%20the%20Composition%20and%20Morphology%20on%20Gas%20Transport%20Properties&rft.jtitle=Polymers&rft.au=Zid,%20Sarra&rft.date=2022-08-25&rft.volume=14&rft.issue=17&rft.spage=3489&rft.pages=3489-&rft.issn=2073-4360&rft.eissn=2073-4360&rft_id=info:doi/10.3390/polym14173489&rft_dat=%3Cgale_pubme%3EA746438443%3C/gale_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2711494169&rft_id=info:pmid/36080562&rft_galeid=A746438443&rfr_iscdi=true |