Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments
The elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide hard segments (HS) were studied in compression and tensile mode as well as with stress relaxation (SR) measurements. For these copolymers the compression set values were low and increased wi...
Gespeichert in:
| Veröffentlicht in: | Journal of materials science 2010, Vol.45 (1), p.158-167 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 167 |
|---|---|
| container_issue | 1 |
| container_start_page | 158 |
| container_title | Journal of materials science |
| container_volume | 45 |
| creator | Biemond, G. J. E. Gaymans, Reinoud J. |
| description | The elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide hard segments (HS) were studied in compression and tensile mode as well as with stress relaxation (SR) measurements. For these copolymers the compression set values were low and increased with the modulus and temperature. At low strains ( |
| doi_str_mv | 10.1007/s10853-009-3911-z |
| format | Article |
| fullrecord | <record><control><sourceid>gale_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9403655</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A573285342</galeid><sourcerecordid>A573285342</sourcerecordid><originalsourceid>FETCH-LOGICAL-c691t-272ac7eb91b815bbfcdfe00979013191a0deef6fb0ee8b23054f5bd714f11e9d3</originalsourceid><addsrcrecordid>eNqNkk1r3DAQhk1pabZpf0Bvgh6aHJzqw7KsSyGEtAkECv04C9ke7SrYkivJIZtfX5ld0m6hH-gwMPO8r6SZKYrXBJ8RjMW7SHDDWYmxLJkkpHx4UqwIF6ysGsyeFiuMKS1pVZOj4kWMtxhjLih5XhyxGjNJhVwV4XLQMdkOTcFPEJKFiLxBaQNh9NO-Bkv0I4SIWh2hR96hyQ_bkwQp6BHSZjuAA-TvbQ-nSLsejd753sZsGQHpMedRhPUILsWXxTOjhwiv9vG4-Pbh8uvFVXnz6eP1xflN2dWSpJIKqjsBrSRtQ3jbmq43kL8qJCaMSKJxD2Bq02KApqUM88rwthekMoSA7Nlx8X7nO83tCH2X7w56UFOwow5b5bVVhxVnN2rt75SsMKs5zwZv9wbBf58hJjXa2MEwaAd-jkpwVjeS1wt58leSCtxQLiRb0De_obd-Di43QtGKNlQIyupMne2otR5AWWd8fmGXTw-j7bwDY3P-PM-a5g2o6P8KsjUnNSeL4PRAkJkE92mt5xjV9ZfPh-b_Yn_1JTu2Cz7GAOax4QSrZWvVbmtVHqVatlY9ZA3daWJm3RrCz578WfQDOv7vIQ</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2428277236</pqid></control><display><type>article</type><title>Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments</title><source>SpringerNature Journals</source><creator>Biemond, G. J. E. ; Gaymans, Reinoud J.</creator><creatorcontrib>Biemond, G. J. E. ; Gaymans, Reinoud J.</creatorcontrib><description>The elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide hard segments (HS) were studied in compression and tensile mode as well as with stress relaxation (SR) measurements. For these copolymers the compression set values were low and increased with the modulus and temperature. At low strains (<50%) the tensile set (TS) values were low and the strain recovered almost completely with time. Furthermore, the TS values increased with strain, due to a deformation of the crystallites and a strain hardening of the polyether segments. During the SR measurements, two processes were observed: a fast initial decay in the first 10 s followed by a relaxation process that was dependant on the logarithm of time. The initial decay during the first seconds increased with the modulus of the copolymers and with the applied strain. The SR values for the second process, normalised to the stress at 100 s, were independent of the strain (within the range of 25–300%) and only little dependant on the modulus of the system. In comparison to the literature data the copolymers with the monodisperse HS displayed improved elastic properties and low SR values.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-009-3911-z</identifier><identifier>PMID: 36039279</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Amides ; Characterization and Evaluation of Materials ; Classical Mechanics ; Compressing ; Copolymers ; Crystallites ; Crystallography and Scattering Methods ; Decay rate ; Elastic constants ; Elastic properties ; Materials Science ; Oxides ; Polymer Sciences ; Polymers ; Segments ; Solid Mechanics ; Strain ; Strain hardening ; Stress relaxation ; Thermoplastic elastomers</subject><ispartof>Journal of materials science, 2010, Vol.45 (1), p.158-167</ispartof><rights>The Author(s) 2009</rights><rights>COPYRIGHT 2010 Springer</rights><rights>The Author(s) 2009. This work is published under https://creativecommons.org/licenses/by-nc/2.0 (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c691t-272ac7eb91b815bbfcdfe00979013191a0deef6fb0ee8b23054f5bd714f11e9d3</citedby><cites>FETCH-LOGICAL-c691t-272ac7eb91b815bbfcdfe00979013191a0deef6fb0ee8b23054f5bd714f11e9d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-009-3911-z$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-009-3911-z$$EHTML$$P50$$Gspringer$$Hfree_for_read</linktohtml><link.rule.ids>230,314,780,784,885,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Biemond, G. J. E.</creatorcontrib><creatorcontrib>Gaymans, Reinoud J.</creatorcontrib><title>Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>The elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide hard segments (HS) were studied in compression and tensile mode as well as with stress relaxation (SR) measurements. For these copolymers the compression set values were low and increased with the modulus and temperature. At low strains (<50%) the tensile set (TS) values were low and the strain recovered almost completely with time. Furthermore, the TS values increased with strain, due to a deformation of the crystallites and a strain hardening of the polyether segments. During the SR measurements, two processes were observed: a fast initial decay in the first 10 s followed by a relaxation process that was dependant on the logarithm of time. The initial decay during the first seconds increased with the modulus of the copolymers and with the applied strain. The SR values for the second process, normalised to the stress at 100 s, were independent of the strain (within the range of 25–300%) and only little dependant on the modulus of the system. In comparison to the literature data the copolymers with the monodisperse HS displayed improved elastic properties and low SR values.</description><subject>Amides</subject><subject>Characterization and Evaluation of Materials</subject><subject>Classical Mechanics</subject><subject>Compressing</subject><subject>Copolymers</subject><subject>Crystallites</subject><subject>Crystallography and Scattering Methods</subject><subject>Decay rate</subject><subject>Elastic constants</subject><subject>Elastic properties</subject><subject>Materials Science</subject><subject>Oxides</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Segments</subject><subject>Solid Mechanics</subject><subject>Strain</subject><subject>Strain hardening</subject><subject>Stress relaxation</subject><subject>Thermoplastic elastomers</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqNkk1r3DAQhk1pabZpf0Bvgh6aHJzqw7KsSyGEtAkECv04C9ke7SrYkivJIZtfX5ld0m6hH-gwMPO8r6SZKYrXBJ8RjMW7SHDDWYmxLJkkpHx4UqwIF6ysGsyeFiuMKS1pVZOj4kWMtxhjLih5XhyxGjNJhVwV4XLQMdkOTcFPEJKFiLxBaQNh9NO-Bkv0I4SIWh2hR96hyQ_bkwQp6BHSZjuAA-TvbQ-nSLsejd753sZsGQHpMedRhPUILsWXxTOjhwiv9vG4-Pbh8uvFVXnz6eP1xflN2dWSpJIKqjsBrSRtQ3jbmq43kL8qJCaMSKJxD2Bq02KApqUM88rwthekMoSA7Nlx8X7nO83tCH2X7w56UFOwow5b5bVVhxVnN2rt75SsMKs5zwZv9wbBf58hJjXa2MEwaAd-jkpwVjeS1wt58leSCtxQLiRb0De_obd-Di43QtGKNlQIyupMne2otR5AWWd8fmGXTw-j7bwDY3P-PM-a5g2o6P8KsjUnNSeL4PRAkJkE92mt5xjV9ZfPh-b_Yn_1JTu2Cz7GAOax4QSrZWvVbmtVHqVatlY9ZA3daWJm3RrCz578WfQDOv7vIQ</recordid><startdate>2010</startdate><enddate>2010</enddate><creator>Biemond, G. J. E.</creator><creator>Gaymans, Reinoud J.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>7X8</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>5PM</scope></search><sort><creationdate>2010</creationdate><title>Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments</title><author>Biemond, G. J. E. ; Gaymans, Reinoud J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c691t-272ac7eb91b815bbfcdfe00979013191a0deef6fb0ee8b23054f5bd714f11e9d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Amides</topic><topic>Characterization and Evaluation of Materials</topic><topic>Classical Mechanics</topic><topic>Compressing</topic><topic>Copolymers</topic><topic>Crystallites</topic><topic>Crystallography and Scattering Methods</topic><topic>Decay rate</topic><topic>Elastic constants</topic><topic>Elastic properties</topic><topic>Materials Science</topic><topic>Oxides</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Segments</topic><topic>Solid Mechanics</topic><topic>Strain</topic><topic>Strain hardening</topic><topic>Stress relaxation</topic><topic>Thermoplastic elastomers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Biemond, G. J. E.</creatorcontrib><creatorcontrib>Gaymans, Reinoud J.</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Biemond, G. J. E.</au><au>Gaymans, Reinoud J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2010</date><risdate>2010</risdate><volume>45</volume><issue>1</issue><spage>158</spage><epage>167</epage><pages>158-167</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>The elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide hard segments (HS) were studied in compression and tensile mode as well as with stress relaxation (SR) measurements. For these copolymers the compression set values were low and increased with the modulus and temperature. At low strains (<50%) the tensile set (TS) values were low and the strain recovered almost completely with time. Furthermore, the TS values increased with strain, due to a deformation of the crystallites and a strain hardening of the polyether segments. During the SR measurements, two processes were observed: a fast initial decay in the first 10 s followed by a relaxation process that was dependant on the logarithm of time. The initial decay during the first seconds increased with the modulus of the copolymers and with the applied strain. The SR values for the second process, normalised to the stress at 100 s, were independent of the strain (within the range of 25–300%) and only little dependant on the modulus of the system. In comparison to the literature data the copolymers with the monodisperse HS displayed improved elastic properties and low SR values.</abstract><cop>New York</cop><pub>Springer US</pub><pmid>36039279</pmid><doi>10.1007/s10853-009-3911-z</doi><tpages>10</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-2461 |
| ispartof | Journal of materials science, 2010, Vol.45 (1), p.158-167 |
| issn | 0022-2461 1573-4803 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9403655 |
| source | SpringerNature Journals |
| subjects | Amides Characterization and Evaluation of Materials Classical Mechanics Compressing Copolymers Crystallites Crystallography and Scattering Methods Decay rate Elastic constants Elastic properties Materials Science Oxides Polymer Sciences Polymers Segments Solid Mechanics Strain Strain hardening Stress relaxation Thermoplastic elastomers |
| title | Elastic properties of thermoplastic elastomers based on poly(tetramethylene oxide) and monodisperse amide segments |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-26T07%3A29%3A26IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Elastic%20properties%20of%20thermoplastic%20elastomers%20based%20on%20poly(tetramethylene%20oxide)%20and%20monodisperse%20amide%20segments&rft.jtitle=Journal%20of%20materials%20science&rft.au=Biemond,%20G.%20J.%20E.&rft.date=2010&rft.volume=45&rft.issue=1&rft.spage=158&rft.epage=167&rft.pages=158-167&rft.issn=0022-2461&rft.eissn=1573-4803&rft_id=info:doi/10.1007/s10853-009-3911-z&rft_dat=%3Cgale_pubme%3EA573285342%3C/gale_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2428277236&rft_id=info:pmid/36039279&rft_galeid=A573285342&rfr_iscdi=true |