Redox‐Switchable Complexes Based on Nanographene‐NHCs

A series of rhodium and iridium complexes with a N‐heterocyclic carbene (NHC) ligand decorated with a perylene‐diimide‐pyrene moiety are described. Electrochemical studies reveal that the complexes can undergo two successive one‐electron reduction events, associated to the reduction of the PDI moiet...

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Veröffentlicht in:	Chemistry : a European journal 2022-08, Vol.28 (44), p.e202201384-n/a
Hauptverfasser:	Ruiz‐Zambrana, César, Dubey, Rajeev K., Poyatos, Macarena, Mateo‐Alonso, Aurelio, Peris, Eduardo
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysts Chemistry Cycloaddition Diimide Electrochemistry Iridium Iridium compounds Ligands mechanism N-heterocyclic carbene nanographene redox-switchable Reduction Rhodium
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