1‐(Azidomethyl)‐5H‐Tetrazole: A Powerful New Ligand for Highly Energetic Coordination Compounds

Highly energetic 1‐(azidomethyl)‐5H‐tetrazole (AzMT, 3) has been synthesized and characterized. This completes the series of 1‐(azidoalkyl)‐5H‐tetrazoles represented by 1‐(azidoethyl)‐5H‐tetrazole (AET) and 1‐(azidopropyl)‐5H‐tetrazole (APT). AzMT was thoroughly analyzed by single‐crystal X‐ray diff...

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Veröffentlicht in:	Chemistry : a European journal 2022-07, Vol.28 (38), p.e202200492-n/a
Hauptverfasser:	Kofen, Moritz, Lommel, Marcus, Wurzenberger, Maximilian H. H., Klapötke, Thomas M., Stierstorfer, Jörg
Format:	Artikel
Sprache:	eng
Schlagworte:	alkylazides Anions Chemical analysis Chemistry Chlorate Coordination compounds Copper Deflagration Detonation Differential thermal analysis energetic coordination compounds Enthalpy External stimuli Heavy metals Infrared spectroscopy initiation Iron Ligands Manganese Nitrogen isotopes NMR Nuclear magnetic resonance PETN primary explosives Silver Spectroscopic analysis Spectrum analysis Synthesis tetrazole Tetrazoles Thermal analysis X-ray diffraction Zinc
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