Dismutation of Tricyanoboryllead Compounds: The Homoleptic Tetrakis(tricyanoboryl)plumbate Tetraanion

A series of unprecedently air‐stable (tricyanoboryl)plumbate anions was obtained by the reaction of the boron‐centered nucleophile B(CN)32− with triorganyllead halides. Salts of the anions [R3PbB(CN)3]− (R=Ph, Et) were isolated and found to be stable in air at room temperature. In the case of Me3PbH...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie International Edition 2022-06, Vol.61 (24), p.e202202882-n/a
Hauptverfasser:	Häring, Mathias, Kerpen, Christoph, Ribbeck, Tatjana, Hennig, Philipp T., Bertermann, Rüdiger, Ignat'ev, Nikolai V., Finze, Maik
Format:	Artikel
Sprache:	eng
Schlagworte:	Air temperature Anions Aqueous solutions Boron Cyanoborates Dismutations Halides Lead Mixtures Nucleophiles Room temperature Salts
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!