Two-Layer Rubber-Based Composite Material and UHMWPE with High Wear Resistance
The aim of the study is the development of two-layer materials based on ultra-high-molecular-weight polyethylene (UHMWPE) and isoprene rubber (IR) depending on the vulcanization accelerators (2-mercaptobenzothiazole (MBT), diphenylguanidine (DPG), and tetramethylthiuram disulfide (TMTD)). The articl...
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| Veröffentlicht in: | Materials 2022-07, Vol.15 (13), p.4678 |
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| creator | Dyakonov, Afanasy A. Vasilev, Andrey P. Danilova, Sakhayana N. Okhlopkova, Aitalina A. Tarasova, Praskovia N. Lazareva, Nadezhda N. Ushkanov, Alexander A. Tuisov, Aleksei G. Kychkin, Anatoly K. Vinokurov, Pavel V. |
| description | The aim of the study is the development of two-layer materials based on ultra-high-molecular-weight polyethylene (UHMWPE) and isoprene rubber (IR) depending on the vulcanization accelerators (2-mercaptobenzothiazole (MBT), diphenylguanidine (DPG), and tetramethylthiuram disulfide (TMTD)). The article presents the study of the influence of these accelerators on the properties and structure of UHMWPE. It is shown that the use of accelerators to modify UHMWPE leads to an increase in tensile strength of 28–53%, a relative elongation at fracture of 7–23%, and wear resistance of three times compared to the original UHMWPE. It has been determined that the introduction of selected vulcanization accelerators into UHMWPE leads to an increase in adhesion between the polymer and rubber. The study of the interfacial boundary of a two-layer material with scanning electron microscopy (SEM) and infrared spectroscopy (FTIR) showed that the structure is characterized by the presence of UHMWPE fibrils localized in the rubber material due to mechanical adhesion. |
| doi_str_mv | 10.3390/ma15134678 |
| format | Article |
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The article presents the study of the influence of these accelerators on the properties and structure of UHMWPE. It is shown that the use of accelerators to modify UHMWPE leads to an increase in tensile strength of 28–53%, a relative elongation at fracture of 7–23%, and wear resistance of three times compared to the original UHMWPE. It has been determined that the introduction of selected vulcanization accelerators into UHMWPE leads to an increase in adhesion between the polymer and rubber. The study of the interfacial boundary of a two-layer material with scanning electron microscopy (SEM) and infrared spectroscopy (FTIR) showed that the structure is characterized by the presence of UHMWPE fibrils localized in the rubber material due to mechanical adhesion.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma15134678</identifier><identifier>PMID: 35806802</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Accelerators ; Adhesion ; Adhesives ; Bond strength ; Carbon black ; Composite materials ; Elastomers ; Elongation ; Isoprene rubber ; Mercaptobenzothiazole ; Polymerization ; Polymers ; Rubber ; Tensile strength ; Ultra high molecular weight polyethylene ; Vulcanization ; Wear resistance ; Zinc oxides</subject><ispartof>Materials, 2022-07, Vol.15 (13), p.4678</ispartof><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; MDPI - Multidisciplinary Digital Publishing Institute; PubMed Central; Free Full-Text Journals in Chemistry |
| subjects | Accelerators Adhesion Adhesives Bond strength Carbon black Composite materials Elastomers Elongation Isoprene rubber Mercaptobenzothiazole Polymerization Polymers Rubber Tensile strength Ultra high molecular weight polyethylene Vulcanization Wear resistance Zinc oxides |
| title | Two-Layer Rubber-Based Composite Material and UHMWPE with High Wear Resistance |
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