Influence of Multiple Thermomechanical Processing of 3D Filaments Based on Polylactic Acid and Polyhydroxybutyrate on Their Rheological and Utility Properties
This study focused on material recycling of a biodegradable blend based on PLA and PHB for multiple applications of biodegradable polymeric material under real conditions. In this study, we investigated the effect of multiple processing of a biodegradable polymer blend under the trade name NONOILEN...
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creator | Plavec, Roderik Horváth, Vojtech Hlaváčiková, Slávka Omaníková, Leona Repiská, Martina Medlenová, Elena Feranc, Jozef Kruželák, Ján Přikryl, Radek Figalla, Silvestr Kontárová, Soňa Baco, Andrej Danišová, Lucia Vanovčanová, Zuzana Alexy, Pavol |
description | This study focused on material recycling of a biodegradable blend based on PLA and PHB for multiple applications of biodegradable polymeric material under real conditions. In this study, we investigated the effect of multiple processing of a biodegradable polymer blend under the trade name NONOILEN
, which was processed under laboratory as well as industrial conditions. In this article, we report on testing the effect of blending and multiple processing on thermomechanical stability, molecular characteristics, as well as thermophysical and mechanical properties of experimental- and industrial-type tested material suitable for FDM 3D technology. The results showed that the studied material degraded during blending and subsequently during multiple processing. Even after partial degradation, which was demonstrated by a decrease in average molecular weight and a decrease in complex viscosity in the process of multiple reprocessing, there was no significant change in the material's thermophysical properties, either in laboratory or industrial conditions. There was also no negative impact on the strength characteristics of multiple processed samples. The results of this work show that a biodegradable polymer blend based on PLA and PHB is a suitable candidate for material recycling even in industrial processing conditions. In addition, the results suggest that the biodegradable polymeric material NONOILEN
3D 3056-2 is suitable for multiple uses in FDM technology. |
doi_str_mv | 10.3390/polym14101947 |
format | Article |
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, which was processed under laboratory as well as industrial conditions. In this article, we report on testing the effect of blending and multiple processing on thermomechanical stability, molecular characteristics, as well as thermophysical and mechanical properties of experimental- and industrial-type tested material suitable for FDM 3D technology. The results showed that the studied material degraded during blending and subsequently during multiple processing. Even after partial degradation, which was demonstrated by a decrease in average molecular weight and a decrease in complex viscosity in the process of multiple reprocessing, there was no significant change in the material's thermophysical properties, either in laboratory or industrial conditions. There was also no negative impact on the strength characteristics of multiple processed samples. The results of this work show that a biodegradable polymer blend based on PLA and PHB is a suitable candidate for material recycling even in industrial processing conditions. In addition, the results suggest that the biodegradable polymeric material NONOILEN
3D 3056-2 is suitable for multiple uses in FDM technology.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym14101947</identifier><identifier>PMID: 35631830</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>3-D printers ; Additive manufacturing ; Biocompatibility ; Biodegradability ; Biodegradable materials ; Biomedical materials ; Bioplastics ; Biopolymers ; Blending effects ; Filaments ; Flexibility ; Hydrogels ; Impact strength ; Mechanical properties ; Molecular weight ; Plastics ; Polyhydroxybutyrate ; Polylactic acid ; Polymer blends ; Polymers ; Recycling ; Reprocessing ; Rheological properties ; Rheology ; Thermomechanical properties ; Thermomechanical treatment ; Thermophysical properties ; Tissue engineering</subject><ispartof>Polymers, 2022-05, Vol.14 (10), p.1947</ispartof><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2022 by the authors. 2022</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c345t-7ae478ea5d22a3008abbc1d5f93878064e9997eebc0057a24f306ea8248783913</citedby><cites>FETCH-LOGICAL-c345t-7ae478ea5d22a3008abbc1d5f93878064e9997eebc0057a24f306ea8248783913</cites><orcidid>0000-0002-7811-9840 ; 0000-0002-7525-9610 ; 0000-0002-2583-1260</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9143941/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9143941/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35631830$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Plavec, Roderik</creatorcontrib><creatorcontrib>Horváth, Vojtech</creatorcontrib><creatorcontrib>Hlaváčiková, Slávka</creatorcontrib><creatorcontrib>Omaníková, Leona</creatorcontrib><creatorcontrib>Repiská, Martina</creatorcontrib><creatorcontrib>Medlenová, Elena</creatorcontrib><creatorcontrib>Feranc, Jozef</creatorcontrib><creatorcontrib>Kruželák, Ján</creatorcontrib><creatorcontrib>Přikryl, Radek</creatorcontrib><creatorcontrib>Figalla, Silvestr</creatorcontrib><creatorcontrib>Kontárová, Soňa</creatorcontrib><creatorcontrib>Baco, Andrej</creatorcontrib><creatorcontrib>Danišová, Lucia</creatorcontrib><creatorcontrib>Vanovčanová, Zuzana</creatorcontrib><creatorcontrib>Alexy, Pavol</creatorcontrib><title>Influence of Multiple Thermomechanical Processing of 3D Filaments Based on Polylactic Acid and Polyhydroxybutyrate on Their Rheological and Utility Properties</title><title>Polymers</title><addtitle>Polymers (Basel)</addtitle><description>This study focused on material recycling of a biodegradable blend based on PLA and PHB for multiple applications of biodegradable polymeric material under real conditions. In this study, we investigated the effect of multiple processing of a biodegradable polymer blend under the trade name NONOILEN
, which was processed under laboratory as well as industrial conditions. In this article, we report on testing the effect of blending and multiple processing on thermomechanical stability, molecular characteristics, as well as thermophysical and mechanical properties of experimental- and industrial-type tested material suitable for FDM 3D technology. The results showed that the studied material degraded during blending and subsequently during multiple processing. Even after partial degradation, which was demonstrated by a decrease in average molecular weight and a decrease in complex viscosity in the process of multiple reprocessing, there was no significant change in the material's thermophysical properties, either in laboratory or industrial conditions. There was also no negative impact on the strength characteristics of multiple processed samples. The results of this work show that a biodegradable polymer blend based on PLA and PHB is a suitable candidate for material recycling even in industrial processing conditions. In addition, the results suggest that the biodegradable polymeric material NONOILEN
3D 3056-2 is suitable for multiple uses in FDM technology.</description><subject>3-D printers</subject><subject>Additive manufacturing</subject><subject>Biocompatibility</subject><subject>Biodegradability</subject><subject>Biodegradable materials</subject><subject>Biomedical materials</subject><subject>Bioplastics</subject><subject>Biopolymers</subject><subject>Blending effects</subject><subject>Filaments</subject><subject>Flexibility</subject><subject>Hydrogels</subject><subject>Impact strength</subject><subject>Mechanical properties</subject><subject>Molecular weight</subject><subject>Plastics</subject><subject>Polyhydroxybutyrate</subject><subject>Polylactic acid</subject><subject>Polymer blends</subject><subject>Polymers</subject><subject>Recycling</subject><subject>Reprocessing</subject><subject>Rheological properties</subject><subject>Rheology</subject><subject>Thermomechanical properties</subject><subject>Thermomechanical treatment</subject><subject>Thermophysical properties</subject><subject>Tissue engineering</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkctu1jAQhS0EolXpki2yxIZNqB07cbxBKoVCpSIq1K4jx5n8ceXYwXYq8jI8K05vavFmrJlPZ-boIPSWko-MSXI0e7tOlFNCJRcv0H5JBCs4q8nLJ_89dBjjNcmPV3VNxWu0x6qa0YaRffT3zA12AacB-wH_WGwyswV8OUKY_AR6VM5oZfFF8BpiNG63cewLPjVWTeBSxJ9VhB57hy_yNVbpZDQ-1qbHyvW3vXHtg_-zdktag0qwoVnfBPxrBG_97nbBBl8lY01at2UzhGQgvkGvBmUjHN7XA3R1-vXy5Htx_vPb2cnxeaEZr1IhFHDRgKr6slSMkEZ1naZ9NUjWiIbUHKSUAqDThFRClXxgpAbVlDyPmaTsAH26052XboJeZ2NB2XYOZlJhbb0y7fOJM2O78zetpJxJvgl8uBcI_vcCMbWTiRqsVQ78EtuyFrQUtOEko-__Q6_9Ely2t1GEccFFlanijtLBxxhgeDyGknYLv30WfubfPXXwSD9Ezf4BXY6uNg</recordid><startdate>20220511</startdate><enddate>20220511</enddate><creator>Plavec, Roderik</creator><creator>Horváth, Vojtech</creator><creator>Hlaváčiková, Slávka</creator><creator>Omaníková, Leona</creator><creator>Repiská, Martina</creator><creator>Medlenová, Elena</creator><creator>Feranc, Jozef</creator><creator>Kruželák, Ján</creator><creator>Přikryl, Radek</creator><creator>Figalla, Silvestr</creator><creator>Kontárová, Soňa</creator><creator>Baco, Andrej</creator><creator>Danišová, Lucia</creator><creator>Vanovčanová, Zuzana</creator><creator>Alexy, Pavol</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-7811-9840</orcidid><orcidid>https://orcid.org/0000-0002-7525-9610</orcidid><orcidid>https://orcid.org/0000-0002-2583-1260</orcidid></search><sort><creationdate>20220511</creationdate><title>Influence of Multiple Thermomechanical Processing of 3D Filaments Based on Polylactic Acid and Polyhydroxybutyrate on Their Rheological and Utility Properties</title><author>Plavec, Roderik ; 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In this study, we investigated the effect of multiple processing of a biodegradable polymer blend under the trade name NONOILEN
, which was processed under laboratory as well as industrial conditions. In this article, we report on testing the effect of blending and multiple processing on thermomechanical stability, molecular characteristics, as well as thermophysical and mechanical properties of experimental- and industrial-type tested material suitable for FDM 3D technology. The results showed that the studied material degraded during blending and subsequently during multiple processing. Even after partial degradation, which was demonstrated by a decrease in average molecular weight and a decrease in complex viscosity in the process of multiple reprocessing, there was no significant change in the material's thermophysical properties, either in laboratory or industrial conditions. There was also no negative impact on the strength characteristics of multiple processed samples. The results of this work show that a biodegradable polymer blend based on PLA and PHB is a suitable candidate for material recycling even in industrial processing conditions. In addition, the results suggest that the biodegradable polymeric material NONOILEN
3D 3056-2 is suitable for multiple uses in FDM technology.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>35631830</pmid><doi>10.3390/polym14101947</doi><orcidid>https://orcid.org/0000-0002-7811-9840</orcidid><orcidid>https://orcid.org/0000-0002-7525-9610</orcidid><orcidid>https://orcid.org/0000-0002-2583-1260</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | 3-D printers Additive manufacturing Biocompatibility Biodegradability Biodegradable materials Biomedical materials Bioplastics Biopolymers Blending effects Filaments Flexibility Hydrogels Impact strength Mechanical properties Molecular weight Plastics Polyhydroxybutyrate Polylactic acid Polymer blends Polymers Recycling Reprocessing Rheological properties Rheology Thermomechanical properties Thermomechanical treatment Thermophysical properties Tissue engineering |
title | Influence of Multiple Thermomechanical Processing of 3D Filaments Based on Polylactic Acid and Polyhydroxybutyrate on Their Rheological and Utility Properties |
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