A Three-Dimensional Coordination Framework with a Ferromagnetic Coupled Ni(II)-CrO4 Layer: Synthesis, Structure, and Magnetic Studies

We report herein on the crystal structure and magnetic studies of a three-dimensional (3D) Ni(II)-chromate coordination polymer, [Ni(CrO4)(bpym)(H2O)]n (1; bpym = 5,5′-bipyrimidin), prepared by self-assembly of Ni(II) and chromate ions with a multi-N donor auxiliary ligands, bpym, through hydrotherm...

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