One-dimensional chain structures of hexanuclear uranium(iv) clusters bridged by formate ligands
Three one-dimensional chain structures of uranium(iv) hexanuclear clusters have been synthesized under hydrothermal/solvothermal conditions. Crystallographic studies disclose that the structures of [U O (OH) (HCOO) (H O)]·3H O (1a), [U O (OH) (HCOO) (HCOOH)(H O)]·3H O (1b) and (H C N) [U O (OH) (HCO...
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| Veröffentlicht in: | RSC advances 2018-10, Vol.8 (61), p.34947-34953 |
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| creator | Ling, Jie Lu, Huangjie Wang, Yaxing Johnson, Kenndra Wang, Shuao |
| description | Three one-dimensional chain structures of uranium(iv) hexanuclear clusters have been synthesized under hydrothermal/solvothermal conditions. Crystallographic studies disclose that the structures of [U
O
(OH)
(HCOO)
(H
O)]·3H
O (1a), [U
O
(OH)
(HCOO)
(HCOOH)(H
O)]·3H
O (1b) and (H
C
N)
[U
O
(OH)
(HCOO)
(H
C
N)] (2) contain a U(iv) hexanulear core [U
(
-OH)
(
-O)
]
which is decorated by terminal HCOO
ligands and water (1a, 1b), HCOOH (1b) or pyridine molecules (2). These hexanuclear U(iv) clusters are further linked into zig-zag 1-D chain structures
bridging HCOO
ligands. UV-vis-NIR spectra, together with bond valence calculations, indicate that all U atoms in three compounds exist as U(iv). Magnetic susceptibility data reveal that compound 2 exhibits paramagnetic characteristics. |
| doi_str_mv | 10.1039/c8ra06330c |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9087207</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2120216059</sourcerecordid><originalsourceid>FETCH-LOGICAL-c433t-b9099bdf3afacdff19817e39b47cf32c342463b2391f36aaa227fa5c67b4903f3</originalsourceid><addsrcrecordid>eNpd0UtrFTEYBuAgii21G3-ABN1UYWpuk0w2Qjl4KRQKouvwTSY5J2UmqbkU--8de2qpzSaBPLy5vAi9puSUEq4_2iEDkZwT-wwdMiJkx4jUzx-tD9BxKVdkHbKnTNKX6ID3vVBE6UNkLqPrprC4WEKKMGO7gxBxqbnZ2rIrOHm8c78hNjs7yLhliKEtJ-HmPbZzK9Xlgsccpq2b8HiLfcoLVIfnsIU4lVfohYe5uOP7-Qj9_PL5x-Zbd3H59XxzdtFZwXntRk20HifPwYOdvKd6oMpxPQplPWeWCyYkHxnX1HMJAIwpD72VahSacM-P0Kd97nUbFzdZF2uG2VznsEC-NQmC-X8nhp3ZphujyaAYUWvA231AKjWYYkN1dmdTjM5WQ4VaUb-ik_tTcvrVXKlmCcW6eYboUiuGSSnUwCUjK333hF6lltcfXhVlhFFJer2qD3tlcyolO_9wY0rM337NZvh-dtfvZsVvHr_xgf5rk_8BWfyhSg</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2120216059</pqid></control><display><type>article</type><title>One-dimensional chain structures of hexanuclear uranium(iv) clusters bridged by formate ligands</title><source>DOAJ Directory of Open Access Journals</source><source>PubMed Central Open Access</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central</source><creator>Ling, Jie ; Lu, Huangjie ; Wang, Yaxing ; Johnson, Kenndra ; Wang, Shuao</creator><creatorcontrib>Ling, Jie ; Lu, Huangjie ; Wang, Yaxing ; Johnson, Kenndra ; Wang, Shuao</creatorcontrib><description>Three one-dimensional chain structures of uranium(iv) hexanuclear clusters have been synthesized under hydrothermal/solvothermal conditions. Crystallographic studies disclose that the structures of [U
O
(OH)
(HCOO)
(H
O)]·3H
O (1a), [U
O
(OH)
(HCOO)
(HCOOH)(H
O)]·3H
O (1b) and (H
C
N)
[U
O
(OH)
(HCOO)
(H
C
N)] (2) contain a U(iv) hexanulear core [U
(
-OH)
(
-O)
]
which is decorated by terminal HCOO
ligands and water (1a, 1b), HCOOH (1b) or pyridine molecules (2). These hexanuclear U(iv) clusters are further linked into zig-zag 1-D chain structures
bridging HCOO
ligands. UV-vis-NIR spectra, together with bond valence calculations, indicate that all U atoms in three compounds exist as U(iv). Magnetic susceptibility data reveal that compound 2 exhibits paramagnetic characteristics.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c8ra06330c</identifier><identifier>PMID: 35547079</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Chains ; Chemistry ; Clusters ; Crystallography ; Ligands ; Magnetic permeability ; Uranium</subject><ispartof>RSC advances, 2018-10, Vol.8 (61), p.34947-34953</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2018</rights><rights>This journal is © The Royal Society of Chemistry 2018 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c433t-b9099bdf3afacdff19817e39b47cf32c342463b2391f36aaa227fa5c67b4903f3</citedby><cites>FETCH-LOGICAL-c433t-b9099bdf3afacdff19817e39b47cf32c342463b2391f36aaa227fa5c67b4903f3</cites><orcidid>0000-0002-1526-1102 ; 0000-0001-9646-8617 ; 0000000196468617 ; 0000000215261102</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9087207/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9087207/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35547079$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/1477205$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Ling, Jie</creatorcontrib><creatorcontrib>Lu, Huangjie</creatorcontrib><creatorcontrib>Wang, Yaxing</creatorcontrib><creatorcontrib>Johnson, Kenndra</creatorcontrib><creatorcontrib>Wang, Shuao</creatorcontrib><title>One-dimensional chain structures of hexanuclear uranium(iv) clusters bridged by formate ligands</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>Three one-dimensional chain structures of uranium(iv) hexanuclear clusters have been synthesized under hydrothermal/solvothermal conditions. Crystallographic studies disclose that the structures of [U
O
(OH)
(HCOO)
(H
O)]·3H
O (1a), [U
O
(OH)
(HCOO)
(HCOOH)(H
O)]·3H
O (1b) and (H
C
N)
[U
O
(OH)
(HCOO)
(H
C
N)] (2) contain a U(iv) hexanulear core [U
(
-OH)
(
-O)
]
which is decorated by terminal HCOO
ligands and water (1a, 1b), HCOOH (1b) or pyridine molecules (2). These hexanuclear U(iv) clusters are further linked into zig-zag 1-D chain structures
bridging HCOO
ligands. UV-vis-NIR spectra, together with bond valence calculations, indicate that all U atoms in three compounds exist as U(iv). Magnetic susceptibility data reveal that compound 2 exhibits paramagnetic characteristics.</description><subject>Chains</subject><subject>Chemistry</subject><subject>Clusters</subject><subject>Crystallography</subject><subject>Ligands</subject><subject>Magnetic permeability</subject><subject>Uranium</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpd0UtrFTEYBuAgii21G3-ABN1UYWpuk0w2Qjl4KRQKouvwTSY5J2UmqbkU--8de2qpzSaBPLy5vAi9puSUEq4_2iEDkZwT-wwdMiJkx4jUzx-tD9BxKVdkHbKnTNKX6ID3vVBE6UNkLqPrprC4WEKKMGO7gxBxqbnZ2rIrOHm8c78hNjs7yLhliKEtJ-HmPbZzK9Xlgsccpq2b8HiLfcoLVIfnsIU4lVfohYe5uOP7-Qj9_PL5x-Zbd3H59XxzdtFZwXntRk20HifPwYOdvKd6oMpxPQplPWeWCyYkHxnX1HMJAIwpD72VahSacM-P0Kd97nUbFzdZF2uG2VznsEC-NQmC-X8nhp3ZphujyaAYUWvA231AKjWYYkN1dmdTjM5WQ4VaUb-ik_tTcvrVXKlmCcW6eYboUiuGSSnUwCUjK333hF6lltcfXhVlhFFJer2qD3tlcyolO_9wY0rM337NZvh-dtfvZsVvHr_xgf5rk_8BWfyhSg</recordid><startdate>20181012</startdate><enddate>20181012</enddate><creator>Ling, Jie</creator><creator>Lu, Huangjie</creator><creator>Wang, Yaxing</creator><creator>Johnson, Kenndra</creator><creator>Wang, Shuao</creator><general>Royal Society of Chemistry</general><general>Royal Society of Chemistry (RSC)</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>OTOTI</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-1526-1102</orcidid><orcidid>https://orcid.org/0000-0001-9646-8617</orcidid><orcidid>https://orcid.org/0000000196468617</orcidid><orcidid>https://orcid.org/0000000215261102</orcidid></search><sort><creationdate>20181012</creationdate><title>One-dimensional chain structures of hexanuclear uranium(iv) clusters bridged by formate ligands</title><author>Ling, Jie ; Lu, Huangjie ; Wang, Yaxing ; Johnson, Kenndra ; Wang, Shuao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c433t-b9099bdf3afacdff19817e39b47cf32c342463b2391f36aaa227fa5c67b4903f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chains</topic><topic>Chemistry</topic><topic>Clusters</topic><topic>Crystallography</topic><topic>Ligands</topic><topic>Magnetic permeability</topic><topic>Uranium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ling, Jie</creatorcontrib><creatorcontrib>Lu, Huangjie</creatorcontrib><creatorcontrib>Wang, Yaxing</creatorcontrib><creatorcontrib>Johnson, Kenndra</creatorcontrib><creatorcontrib>Wang, Shuao</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ling, Jie</au><au>Lu, Huangjie</au><au>Wang, Yaxing</au><au>Johnson, Kenndra</au><au>Wang, Shuao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-dimensional chain structures of hexanuclear uranium(iv) clusters bridged by formate ligands</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2018-10-12</date><risdate>2018</risdate><volume>8</volume><issue>61</issue><spage>34947</spage><epage>34953</epage><pages>34947-34953</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Three one-dimensional chain structures of uranium(iv) hexanuclear clusters have been synthesized under hydrothermal/solvothermal conditions. Crystallographic studies disclose that the structures of [U
O
(OH)
(HCOO)
(H
O)]·3H
O (1a), [U
O
(OH)
(HCOO)
(HCOOH)(H
O)]·3H
O (1b) and (H
C
N)
[U
O
(OH)
(HCOO)
(H
C
N)] (2) contain a U(iv) hexanulear core [U
(
-OH)
(
-O)
]
which is decorated by terminal HCOO
ligands and water (1a, 1b), HCOOH (1b) or pyridine molecules (2). These hexanuclear U(iv) clusters are further linked into zig-zag 1-D chain structures
bridging HCOO
ligands. UV-vis-NIR spectra, together with bond valence calculations, indicate that all U atoms in three compounds exist as U(iv). Magnetic susceptibility data reveal that compound 2 exhibits paramagnetic characteristics.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35547079</pmid><doi>10.1039/c8ra06330c</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-1526-1102</orcidid><orcidid>https://orcid.org/0000-0001-9646-8617</orcidid><orcidid>https://orcid.org/0000000196468617</orcidid><orcidid>https://orcid.org/0000000215261102</orcidid><oa>free_for_read</oa></addata></record> |
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| language | eng |
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| source | DOAJ Directory of Open Access Journals; PubMed Central Open Access; EZB-FREE-00999 freely available EZB journals; PubMed Central |
| subjects | Chains Chemistry Clusters Crystallography Ligands Magnetic permeability Uranium |
| title | One-dimensional chain structures of hexanuclear uranium(iv) clusters bridged by formate ligands |
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