Facile synthesis of high-surface-area nanoporous carbon from biomass resources and its application in supercapacitors

It is critical for nanoporous carbons to have a large surface area, and low cost and be readily available for challenging energy and environmental issues. The pursuit of all three characteristics, particularly large surface area, is a formidable challenge because traditional methods to produce porou...

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Veröffentlicht in:RSC advances 2018-01, Vol.8 (4), p.1857-1865
Hauptverfasser: Yao, Yuechao, Zhang, Qi, Liu, Peng, Yu, Liang, Huang, Lin, Zeng, Shao-Zhong, Liu, Lijia, Zeng, Xierong, Zou, Jizhao
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Sprache:eng
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Zusammenfassung:It is critical for nanoporous carbons to have a large surface area, and low cost and be readily available for challenging energy and environmental issues. The pursuit of all three characteristics, particularly large surface area, is a formidable challenge because traditional methods to produce porous carbon materials with a high surface area are complicated and expensive, frequently resulting in pollution (commonly from the activation process). Here we report a facile method to synthesize nanoporous carbon materials with a high surface area of up to 1234 m g and an average pore diameter of 0.88 nm through a simple carbonization procedure with carefully selected carbon precursors (biomass material) and carbonization conditions. It is the high surface area that leads to a high capacitance (up to 213 F g at 0.1 A g ) and a stable cycle performance (6.6% loss over 12 000 cycles) as shown in a three-electrode cell. Furthermore, the high capacitance (107 F g at 0.1 A g ) can be obtained in a supercapacitor device. This facile approach may open a door for the preparation of high surface area porous carbons for energy storage.
ISSN:2046-2069
2046-2069
DOI:10.1039/c7ra12525a