Temperature-triggered reversible breakdown of polymer-stabilized olive-silicone oil Janus emulsions
A one-step moderate energy vibrational emulsification method was successfully employed to produce thermo-responsive olive/silicone-based Janus emulsions stabilized by poly( N , N -diethylacrylamide) carrying 0.7 mol% oleoyl side chains. Completely engulfed emulsion droplets remained stable at room t...
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| Veröffentlicht in: | RSC advances 2019-06, Vol.9 (34), p.19271-19277 |
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| container_issue | 34 |
| container_start_page | 19271 |
| container_title | RSC advances |
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| creator | Raju, Rajarshi Roy Liebig, Ferenc Hess, Andreas Schlaad, Helmut Koetz, Joachim |
| description | A one-step moderate energy vibrational emulsification method was successfully employed to produce thermo-responsive olive/silicone-based Janus emulsions stabilized by poly(
N
,
N
-diethylacrylamide) carrying 0.7 mol% oleoyl side chains. Completely engulfed emulsion droplets remained stable at room temperature and could be destabilized on demand upon heating to the transition temperature of the polymeric stabilizer. Time-dependent light micrographs demonstrate the temperature-induced breakdown of the Janus droplets, which opens new aspects of application, for instance in biocatalysis.
A one-step moderate energy vibrational emulsification method was successfully employed to produce thermo-responsive olive/silicone-based Janus emulsions stabilized by poly(
N
,
N
-diethylacrylamide) carrying 0.7 mol% oleoyl side chains. |
| doi_str_mv | 10.1039/c9ra03463c |
| format | Article |
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N
,
N
-diethylacrylamide) carrying 0.7 mol% oleoyl side chains. Completely engulfed emulsion droplets remained stable at room temperature and could be destabilized on demand upon heating to the transition temperature of the polymeric stabilizer. Time-dependent light micrographs demonstrate the temperature-induced breakdown of the Janus droplets, which opens new aspects of application, for instance in biocatalysis.
A one-step moderate energy vibrational emulsification method was successfully employed to produce thermo-responsive olive/silicone-based Janus emulsions stabilized by poly(
N
,
N
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N
,
N
-diethylacrylamide) carrying 0.7 mol% oleoyl side chains. Completely engulfed emulsion droplets remained stable at room temperature and could be destabilized on demand upon heating to the transition temperature of the polymeric stabilizer. Time-dependent light micrographs demonstrate the temperature-induced breakdown of the Janus droplets, which opens new aspects of application, for instance in biocatalysis.
A one-step moderate energy vibrational emulsification method was successfully employed to produce thermo-responsive olive/silicone-based Janus emulsions stabilized by poly(
N
,
N
-diethylacrylamide) carrying 0.7 mol% oleoyl side chains.</description><subject>Breakdown</subject><subject>Chemistry</subject><subject>Droplets</subject><subject>Emulsion polymerization</subject><subject>Photomicrographs</subject><subject>Time dependence</subject><subject>Transition temperature</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kc1r3DAQxUVpaUKaS-8pDr2UglN9WbYugbD0k0CgpGchy-OtEtlyRvaW9K-v2k03SQ-dy8zwfjxmeIS8ZPSEUaHfOY2WCqmEe0L2OZWq5FTppw_mPXKY0hXNpSrGFXtO9kRVMS0U3SfuEoYJ0M4LQjmjX68BoSsQNoDJtwGKFsFed_HHWMS-mGK4HQDLNNvWB_8zozH4DZQpby6OUEQfii92XFIBwxKSj2N6QZ71NiQ4vOsH5NuH95erT-X5xcfPq7Pz0slKziXrO1lx2UjdSKCy0YIK1zBpmWit5FUnqatky6xoHO1qLpRmTlslWM2gE0ockNOt77S0A3QOxhltMBP6weKtidabx8rov5t13BhNldSyzgZv7gww3iyQZjP45CAEO0JckuFKMdoIzmlGX_-DXsUFx_ye4VzWVc01Y5l6u6UcxpQQ-t0xjJrf8ZmV_nr2J75Vhl89PH-H_g0rA0dbAJPbqff5Z_34f7qZul78Am5lq20</recordid><startdate>20190619</startdate><enddate>20190619</enddate><creator>Raju, Rajarshi Roy</creator><creator>Liebig, Ferenc</creator><creator>Hess, Andreas</creator><creator>Schlaad, Helmut</creator><creator>Koetz, Joachim</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-9113-1337</orcidid><orcidid>https://orcid.org/0000-0002-5824-7204</orcidid></search><sort><creationdate>20190619</creationdate><title>Temperature-triggered reversible breakdown of polymer-stabilized olive-silicone oil Janus emulsions</title><author>Raju, Rajarshi Roy ; Liebig, Ferenc ; Hess, Andreas ; Schlaad, Helmut ; Koetz, Joachim</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c454t-1fd452484984e0489303c814a13ba425d40c54b1a38c0d723691c9a63171ed363</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Breakdown</topic><topic>Chemistry</topic><topic>Droplets</topic><topic>Emulsion polymerization</topic><topic>Photomicrographs</topic><topic>Time dependence</topic><topic>Transition temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Raju, Rajarshi Roy</creatorcontrib><creatorcontrib>Liebig, Ferenc</creatorcontrib><creatorcontrib>Hess, Andreas</creatorcontrib><creatorcontrib>Schlaad, Helmut</creatorcontrib><creatorcontrib>Koetz, Joachim</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Raju, Rajarshi Roy</au><au>Liebig, Ferenc</au><au>Hess, Andreas</au><au>Schlaad, Helmut</au><au>Koetz, Joachim</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Temperature-triggered reversible breakdown of polymer-stabilized olive-silicone oil Janus emulsions</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2019-06-19</date><risdate>2019</risdate><volume>9</volume><issue>34</issue><spage>19271</spage><epage>19277</epage><pages>19271-19277</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>A one-step moderate energy vibrational emulsification method was successfully employed to produce thermo-responsive olive/silicone-based Janus emulsions stabilized by poly(
N
,
N
-diethylacrylamide) carrying 0.7 mol% oleoyl side chains. Completely engulfed emulsion droplets remained stable at room temperature and could be destabilized on demand upon heating to the transition temperature of the polymeric stabilizer. Time-dependent light micrographs demonstrate the temperature-induced breakdown of the Janus droplets, which opens new aspects of application, for instance in biocatalysis.
A one-step moderate energy vibrational emulsification method was successfully employed to produce thermo-responsive olive/silicone-based Janus emulsions stabilized by poly(
N
,
N
-diethylacrylamide) carrying 0.7 mol% oleoyl side chains.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35519360</pmid><doi>10.1039/c9ra03463c</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-9113-1337</orcidid><orcidid>https://orcid.org/0000-0002-5824-7204</orcidid><oa>free_for_read</oa></addata></record> |
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| ispartof | RSC advances, 2019-06, Vol.9 (34), p.19271-19277 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9064947 |
| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; PubMed Central |
| subjects | Breakdown Chemistry Droplets Emulsion polymerization Photomicrographs Time dependence Transition temperature |
| title | Temperature-triggered reversible breakdown of polymer-stabilized olive-silicone oil Janus emulsions |
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