Ultrafine nanoparticles of W-doped SnO2 for durable H2S sensors with fast response and recovery
Ultrafine nanoparticles of W-doped SnO2 with an average diameter of 6 nm were fabricated via a facile hydrothermal method. The material shows a reduced particle size and enhanced response to H2S gas as compared to the pristine SnO2 nanoparticles. The detection limit can be down to 100 ppb while the...
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Veröffentlicht in: | RSC advances 2019-01, Vol.9 (20), p.11046-11053 |
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creator | Wang, Pengjian Hui, Junfeng Yuan, Tingbiao Chen, Peng Su, Yue Liang, Wenjie Chen, Fulin Zheng, Xiaoyan Zhao, Yuxin Hu, Shi |
description | Ultrafine nanoparticles of W-doped SnO2 with an average diameter of 6 nm were fabricated via a facile hydrothermal method. The material shows a reduced particle size and enhanced response to H2S gas as compared to the pristine SnO2 nanoparticles. The detection limit can be down to 100 ppb while the response time and recovery time of the 5%-doped one are reduced to 17 s and 7 s respectively. In addition, the material shows impressive long-term stability of the response through 40 cycles of injection with 10 ppm H2S, which is attractive for designing a durable hydrogen sulfide sensor. The doping of W results in the reduction of size and modification of the electronic band structure of SnO2, which reduces the response time and recovery time and further improves the sensing durability of the materials. |
doi_str_mv | 10.1039/c9ra00944b |
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The material shows a reduced particle size and enhanced response to H2S gas as compared to the pristine SnO2 nanoparticles. The detection limit can be down to 100 ppb while the response time and recovery time of the 5%-doped one are reduced to 17 s and 7 s respectively. In addition, the material shows impressive long-term stability of the response through 40 cycles of injection with 10 ppm H2S, which is attractive for designing a durable hydrogen sulfide sensor. The doping of W results in the reduction of size and modification of the electronic band structure of SnO2, which reduces the response time and recovery time and further improves the sensing durability of the materials.</description><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c9ra00944b</identifier><identifier>PMID: 35520261</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Chemistry ; Durability ; Hydrogen sulfide ; Nanoparticles ; Recovery time ; Response time ; Tin dioxide ; Ultrafines</subject><ispartof>RSC advances, 2019-01, Vol.9 (20), p.11046-11053</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><rights>This journal is © The Royal Society of Chemistry 2019 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9063019/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9063019/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27901,27902,53766,53768</link.rule.ids></links><search><creatorcontrib>Wang, Pengjian</creatorcontrib><creatorcontrib>Hui, Junfeng</creatorcontrib><creatorcontrib>Yuan, Tingbiao</creatorcontrib><creatorcontrib>Chen, Peng</creatorcontrib><creatorcontrib>Su, Yue</creatorcontrib><creatorcontrib>Liang, Wenjie</creatorcontrib><creatorcontrib>Chen, Fulin</creatorcontrib><creatorcontrib>Zheng, Xiaoyan</creatorcontrib><creatorcontrib>Zhao, Yuxin</creatorcontrib><creatorcontrib>Hu, Shi</creatorcontrib><title>Ultrafine nanoparticles of W-doped SnO2 for durable H2S sensors with fast response and recovery</title><title>RSC advances</title><description>Ultrafine nanoparticles of W-doped SnO2 with an average diameter of 6 nm were fabricated via a facile hydrothermal method. The material shows a reduced particle size and enhanced response to H2S gas as compared to the pristine SnO2 nanoparticles. The detection limit can be down to 100 ppb while the response time and recovery time of the 5%-doped one are reduced to 17 s and 7 s respectively. In addition, the material shows impressive long-term stability of the response through 40 cycles of injection with 10 ppm H2S, which is attractive for designing a durable hydrogen sulfide sensor. The doping of W results in the reduction of size and modification of the electronic band structure of SnO2, which reduces the response time and recovery time and further improves the sensing durability of the materials.</description><subject>Chemistry</subject><subject>Durability</subject><subject>Hydrogen sulfide</subject><subject>Nanoparticles</subject><subject>Recovery time</subject><subject>Response time</subject><subject>Tin dioxide</subject><subject>Ultrafines</subject><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpdj8FLwzAYxYMgbsxd_AsCXrxUk3xN2lwEGeqEwQ5zeAxpk7iOLqlJO9l_b8Fd9F2-9_geP3gI3VByTwnIh1pGTYjM8-oCTRnJRcaIkBM0T2lPRglOmaBXaAKcMzLaKVLbto_aNd5ir33odOyburUJB4c_MhM6a_DGrxl2IWIzRF21Fi_ZBifrU4gJfzf9Djudehxt6oJPFmtvxlCHo42na3TpdJvs_HxnaPvy_L5YZqv169viaZV1rKB9Ziw4wqpcQlkCNYyZsgJXUy2MFJw7KRmANrxwgoMpoLIF0DHIGmriOIcZevzldkN1sKa2fpzVqi42Bx1PKuhG_f34Zqc-w1FJIoBQOQLuzoAYvgabenVoUm3bVnsbhqSYEJSUrAAxVm__VfdhiH6cpxgjRSkKAAo_ggp6tA</recordid><startdate>20190101</startdate><enddate>20190101</enddate><creator>Wang, Pengjian</creator><creator>Hui, Junfeng</creator><creator>Yuan, Tingbiao</creator><creator>Chen, Peng</creator><creator>Su, Yue</creator><creator>Liang, Wenjie</creator><creator>Chen, Fulin</creator><creator>Zheng, Xiaoyan</creator><creator>Zhao, Yuxin</creator><creator>Hu, Shi</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20190101</creationdate><title>Ultrafine nanoparticles of W-doped SnO2 for durable H2S sensors with fast response and recovery</title><author>Wang, Pengjian ; Hui, Junfeng ; Yuan, Tingbiao ; Chen, Peng ; Su, Yue ; Liang, Wenjie ; Chen, Fulin ; Zheng, Xiaoyan ; Zhao, Yuxin ; Hu, Shi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p271t-de3f02b4938831d22d8b3fc1a6d9655f99233ad57f653d73be7317f69c3c0f553</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Chemistry</topic><topic>Durability</topic><topic>Hydrogen sulfide</topic><topic>Nanoparticles</topic><topic>Recovery time</topic><topic>Response time</topic><topic>Tin dioxide</topic><topic>Ultrafines</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Pengjian</creatorcontrib><creatorcontrib>Hui, Junfeng</creatorcontrib><creatorcontrib>Yuan, Tingbiao</creatorcontrib><creatorcontrib>Chen, Peng</creatorcontrib><creatorcontrib>Su, Yue</creatorcontrib><creatorcontrib>Liang, Wenjie</creatorcontrib><creatorcontrib>Chen, Fulin</creatorcontrib><creatorcontrib>Zheng, Xiaoyan</creatorcontrib><creatorcontrib>Zhao, Yuxin</creatorcontrib><creatorcontrib>Hu, Shi</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Pengjian</au><au>Hui, Junfeng</au><au>Yuan, Tingbiao</au><au>Chen, Peng</au><au>Su, Yue</au><au>Liang, Wenjie</au><au>Chen, Fulin</au><au>Zheng, Xiaoyan</au><au>Zhao, Yuxin</au><au>Hu, Shi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ultrafine nanoparticles of W-doped SnO2 for durable H2S sensors with fast response and recovery</atitle><jtitle>RSC advances</jtitle><date>2019-01-01</date><risdate>2019</risdate><volume>9</volume><issue>20</issue><spage>11046</spage><epage>11053</epage><pages>11046-11053</pages><eissn>2046-2069</eissn><abstract>Ultrafine nanoparticles of W-doped SnO2 with an average diameter of 6 nm were fabricated via a facile hydrothermal method. The material shows a reduced particle size and enhanced response to H2S gas as compared to the pristine SnO2 nanoparticles. The detection limit can be down to 100 ppb while the response time and recovery time of the 5%-doped one are reduced to 17 s and 7 s respectively. In addition, the material shows impressive long-term stability of the response through 40 cycles of injection with 10 ppm H2S, which is attractive for designing a durable hydrogen sulfide sensor. The doping of W results in the reduction of size and modification of the electronic band structure of SnO2, which reduces the response time and recovery time and further improves the sensing durability of the materials.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><pmid>35520261</pmid><doi>10.1039/c9ra00944b</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Chemistry Durability Hydrogen sulfide Nanoparticles Recovery time Response time Tin dioxide Ultrafines |
title | Ultrafine nanoparticles of W-doped SnO2 for durable H2S sensors with fast response and recovery |
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