Extraction of 2'- O -apiosyl-6'- O -crotonic acid-betanin from the ayrampo seed (Opuntia soehrensii) cuticle and its use as an emitting layer in an organic light-emitting diode
The molecule 2'- -apiosyl-6'- -crotonic acid-betanin (called Achkiy) was obtained after an ecofriendly and low-cost purification process of the extract from the ayrampo seed cuticle. Results from EDS give us an idea of the organic elements present in the ayrampo cuticle layer composed of c...
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| creator | Rivera Tito, Harry Anderson Hernández-Sosa, Gerardo Romero-Nieto, Carlos Regulska, Elzbieta Jürgensen, Nils Zimmermann, Johannes Salazar-Salinas, Karim Quintana Caceda, María Esther |
| description | The molecule 2'-
-apiosyl-6'-
-crotonic acid-betanin (called Achkiy) was obtained after an ecofriendly and low-cost purification process of the extract from the ayrampo seed cuticle. Results from EDS give us an idea of the organic elements present in the ayrampo cuticle layer composed of carbon, oxygen and nitrogen. Further characterization analysis of ayrampo extract by Fourier Transform Infrared Spectrophotometry (FTIR) corroborated the presence of characteristic functional groups corresponding to carboxyl, carbonyls, hydroxyls and secondary amines. On the other hand, we have confirmed by absortion peak the glucose, apiosyl, crotonic acid and betanin at 227 nm, 276 nm, 291 nm and 534 nm bands respectively. Mass Spectrometry (MS) characterization was used finally to identify the electroactive Achkiy molecule. This molecule was tested in an Organic Light Emitting Diode (OLED) achieving a luminance of 4.8 Cd m
when bias voltage of 16.5 V and a current of 34.1 mA was applied. In addition, the irradiance generated by the Achkiy layer reaches a value of ≈ 113.3 μW m
emitting light with a
≈ 390.10 nm. These preliminary results report an interesting molecule extracted from a natural pigment wich emits light in the blue region. |
| doi_str_mv | 10.1039/d0ra05543c |
| format | Article |
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-apiosyl-6'-
-crotonic acid-betanin (called Achkiy) was obtained after an ecofriendly and low-cost purification process of the extract from the ayrampo seed cuticle. Results from EDS give us an idea of the organic elements present in the ayrampo cuticle layer composed of carbon, oxygen and nitrogen. Further characterization analysis of ayrampo extract by Fourier Transform Infrared Spectrophotometry (FTIR) corroborated the presence of characteristic functional groups corresponding to carboxyl, carbonyls, hydroxyls and secondary amines. On the other hand, we have confirmed by absortion peak the glucose, apiosyl, crotonic acid and betanin at 227 nm, 276 nm, 291 nm and 534 nm bands respectively. Mass Spectrometry (MS) characterization was used finally to identify the electroactive Achkiy molecule. This molecule was tested in an Organic Light Emitting Diode (OLED) achieving a luminance of 4.8 Cd m
when bias voltage of 16.5 V and a current of 34.1 mA was applied. In addition, the irradiance generated by the Achkiy layer reaches a value of ≈ 113.3 μW m
emitting light with a
≈ 390.10 nm. These preliminary results report an interesting molecule extracted from a natural pigment wich emits light in the blue region.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d0ra05543c</identifier><identifier>PMID: 35517963</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Amines ; Carbonyls ; Chemistry ; Cuticles ; Fourier transforms ; Functional groups ; Infrared analysis ; Infrared spectrophotometers ; Irradiance ; Mass spectrometry ; Organic light emitting diodes ; Spectrophotometry</subject><ispartof>RSC advances, 2020-10, Vol.10 (60), p.36695-36703</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2020</rights><rights>This journal is © The Royal Society of Chemistry 2020 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c406t-117ee9ea6e33b4e4eced887f1db9ba0196944f5f108c7a45f61bb3cd10897f6c3</citedby><cites>FETCH-LOGICAL-c406t-117ee9ea6e33b4e4eced887f1db9ba0196944f5f108c7a45f61bb3cd10897f6c3</cites><orcidid>0000-0003-0054-8802 ; 0000-0002-3472-933X ; 0000-0002-4676-7114 ; 0000-0002-2871-6401 ; 0000-0002-2677-6179</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057036/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9057036/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,725,778,782,862,883,27907,27908,53774,53776</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35517963$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Rivera Tito, Harry Anderson</creatorcontrib><creatorcontrib>Hernández-Sosa, Gerardo</creatorcontrib><creatorcontrib>Romero-Nieto, Carlos</creatorcontrib><creatorcontrib>Regulska, Elzbieta</creatorcontrib><creatorcontrib>Jürgensen, Nils</creatorcontrib><creatorcontrib>Zimmermann, Johannes</creatorcontrib><creatorcontrib>Salazar-Salinas, Karim</creatorcontrib><creatorcontrib>Quintana Caceda, María Esther</creatorcontrib><title>Extraction of 2'- O -apiosyl-6'- O -crotonic acid-betanin from the ayrampo seed (Opuntia soehrensii) cuticle and its use as an emitting layer in an organic light-emitting diode</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>The molecule 2'-
-apiosyl-6'-
-crotonic acid-betanin (called Achkiy) was obtained after an ecofriendly and low-cost purification process of the extract from the ayrampo seed cuticle. Results from EDS give us an idea of the organic elements present in the ayrampo cuticle layer composed of carbon, oxygen and nitrogen. Further characterization analysis of ayrampo extract by Fourier Transform Infrared Spectrophotometry (FTIR) corroborated the presence of characteristic functional groups corresponding to carboxyl, carbonyls, hydroxyls and secondary amines. On the other hand, we have confirmed by absortion peak the glucose, apiosyl, crotonic acid and betanin at 227 nm, 276 nm, 291 nm and 534 nm bands respectively. Mass Spectrometry (MS) characterization was used finally to identify the electroactive Achkiy molecule. This molecule was tested in an Organic Light Emitting Diode (OLED) achieving a luminance of 4.8 Cd m
when bias voltage of 16.5 V and a current of 34.1 mA was applied. In addition, the irradiance generated by the Achkiy layer reaches a value of ≈ 113.3 μW m
emitting light with a
≈ 390.10 nm. These preliminary results report an interesting molecule extracted from a natural pigment wich emits light in the blue region.</description><subject>Amines</subject><subject>Carbonyls</subject><subject>Chemistry</subject><subject>Cuticles</subject><subject>Fourier transforms</subject><subject>Functional groups</subject><subject>Infrared analysis</subject><subject>Infrared spectrophotometers</subject><subject>Irradiance</subject><subject>Mass spectrometry</subject><subject>Organic light emitting diodes</subject><subject>Spectrophotometry</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNpdkl1rFDEUhgdRbKm98QdIwAurEE0mH7O5KZS1fkBhQfQ6ZJIzuykzyZhkxP1X_kRTty7V3OS8ycN7TnJO0zyn5C0lTL1zJBkiBGf2UXPaEi5xS6R6_CA-ac5zviV1SUFbSZ82J0wI2inJTptf1z9LMrb4GFAcUPsKow3CZvYx70csD9KmWGLwFhnrHe6hmOADGlKcUNkBMvtkpjmiDODQxWZeQvEG5Qi7BCF7_xrZpXg7VjI45EtGS65xrhLB5EvxYYtGs4eEqm09jGlr7tKNfrsr-Ig4Hx08a54MZsxwfr-fNd8-XH9df8I3m4-f11c32HIiC6a0A1BgJDDWc-Bgwa1W3UBdr3pDqJKK80EMlKxsZ7gYJO17Zl3VqhukZWfN5cF3XvoJnIVQ_2nUc_KTSXsdjdf_3gS_09v4QysiOsJkNbi4N0jx-wK56MlnC-NoAsQl61ZKSjoplKjoy__Q27ikUJ-nW87VinQdUZV6c6BqO3JOMByLoUTfzYJ-T75c_ZmFdYVfPCz_iP7tPPsN3USwoA</recordid><startdate>20201006</startdate><enddate>20201006</enddate><creator>Rivera Tito, Harry Anderson</creator><creator>Hernández-Sosa, Gerardo</creator><creator>Romero-Nieto, Carlos</creator><creator>Regulska, Elzbieta</creator><creator>Jürgensen, Nils</creator><creator>Zimmermann, Johannes</creator><creator>Salazar-Salinas, Karim</creator><creator>Quintana Caceda, María Esther</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0003-0054-8802</orcidid><orcidid>https://orcid.org/0000-0002-3472-933X</orcidid><orcidid>https://orcid.org/0000-0002-4676-7114</orcidid><orcidid>https://orcid.org/0000-0002-2871-6401</orcidid><orcidid>https://orcid.org/0000-0002-2677-6179</orcidid></search><sort><creationdate>20201006</creationdate><title>Extraction of 2'- O -apiosyl-6'- O -crotonic acid-betanin from the ayrampo seed (Opuntia soehrensii) cuticle and its use as an emitting layer in an organic light-emitting diode</title><author>Rivera Tito, Harry Anderson ; Hernández-Sosa, Gerardo ; Romero-Nieto, Carlos ; Regulska, Elzbieta ; Jürgensen, Nils ; Zimmermann, Johannes ; Salazar-Salinas, Karim ; Quintana Caceda, María Esther</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c406t-117ee9ea6e33b4e4eced887f1db9ba0196944f5f108c7a45f61bb3cd10897f6c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Amines</topic><topic>Carbonyls</topic><topic>Chemistry</topic><topic>Cuticles</topic><topic>Fourier transforms</topic><topic>Functional groups</topic><topic>Infrared analysis</topic><topic>Infrared spectrophotometers</topic><topic>Irradiance</topic><topic>Mass spectrometry</topic><topic>Organic light emitting diodes</topic><topic>Spectrophotometry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rivera Tito, Harry Anderson</creatorcontrib><creatorcontrib>Hernández-Sosa, Gerardo</creatorcontrib><creatorcontrib>Romero-Nieto, Carlos</creatorcontrib><creatorcontrib>Regulska, Elzbieta</creatorcontrib><creatorcontrib>Jürgensen, Nils</creatorcontrib><creatorcontrib>Zimmermann, Johannes</creatorcontrib><creatorcontrib>Salazar-Salinas, Karim</creatorcontrib><creatorcontrib>Quintana Caceda, María Esther</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rivera Tito, Harry Anderson</au><au>Hernández-Sosa, Gerardo</au><au>Romero-Nieto, Carlos</au><au>Regulska, Elzbieta</au><au>Jürgensen, Nils</au><au>Zimmermann, Johannes</au><au>Salazar-Salinas, Karim</au><au>Quintana Caceda, María Esther</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Extraction of 2'- O -apiosyl-6'- O -crotonic acid-betanin from the ayrampo seed (Opuntia soehrensii) cuticle and its use as an emitting layer in an organic light-emitting diode</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2020-10-06</date><risdate>2020</risdate><volume>10</volume><issue>60</issue><spage>36695</spage><epage>36703</epage><pages>36695-36703</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>The molecule 2'-
-apiosyl-6'-
-crotonic acid-betanin (called Achkiy) was obtained after an ecofriendly and low-cost purification process of the extract from the ayrampo seed cuticle. Results from EDS give us an idea of the organic elements present in the ayrampo cuticle layer composed of carbon, oxygen and nitrogen. Further characterization analysis of ayrampo extract by Fourier Transform Infrared Spectrophotometry (FTIR) corroborated the presence of characteristic functional groups corresponding to carboxyl, carbonyls, hydroxyls and secondary amines. On the other hand, we have confirmed by absortion peak the glucose, apiosyl, crotonic acid and betanin at 227 nm, 276 nm, 291 nm and 534 nm bands respectively. Mass Spectrometry (MS) characterization was used finally to identify the electroactive Achkiy molecule. This molecule was tested in an Organic Light Emitting Diode (OLED) achieving a luminance of 4.8 Cd m
when bias voltage of 16.5 V and a current of 34.1 mA was applied. In addition, the irradiance generated by the Achkiy layer reaches a value of ≈ 113.3 μW m
emitting light with a
≈ 390.10 nm. These preliminary results report an interesting molecule extracted from a natural pigment wich emits light in the blue region.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35517963</pmid><doi>10.1039/d0ra05543c</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0003-0054-8802</orcidid><orcidid>https://orcid.org/0000-0002-3472-933X</orcidid><orcidid>https://orcid.org/0000-0002-4676-7114</orcidid><orcidid>https://orcid.org/0000-0002-2871-6401</orcidid><orcidid>https://orcid.org/0000-0002-2677-6179</orcidid><oa>free_for_read</oa></addata></record> |
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| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; PubMed Central |
| subjects | Amines Carbonyls Chemistry Cuticles Fourier transforms Functional groups Infrared analysis Infrared spectrophotometers Irradiance Mass spectrometry Organic light emitting diodes Spectrophotometry |
| title | Extraction of 2'- O -apiosyl-6'- O -crotonic acid-betanin from the ayrampo seed (Opuntia soehrensii) cuticle and its use as an emitting layer in an organic light-emitting diode |
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