Air-processed active-layer of organic solar cells investigated by conducting AFM for precise defect detection

Atmospheric processing of organic solar cells (OSCs) has already emerged and will be a challenge to emulate with the existing market leaders in terms of overall cost reduction and large scale production. However, the presence of defects in the active layer of OSC needs to be identified effectively to minimize the performance degradation involved. In this work, conventional bulk-heterojunction (BHJ) OSCs are fabricated entirely in air having an efficiency ( η ) up to 4.0% using P3HT and PC 61 BM as the donor and acceptor, respectively. The devices have exhibited reasonable degradation of performance parameters with aging time and uninterrupted illumination during characterization in ambient air. This visible degradation was as expected because of environmental oxygen and moisture penetration into the photoactive layer through the defects, which can be prevented by immediate encapsulation. Conducting AFM is utilized here to visualize these defects more prominently, which are impossible to see in typical AFM topography. Overall, significant development of atmospheric processing of BHJ OSCs is made, and performance stability is also studied to bring down the fabrication costs in the near future. Current imaging by C-AFM is demonstrated as a very effective tool to probe the defects in the organic solar cell active layer.