From Serendipity to Rational Design: Heteroleptic Dirhodium Amidate Complexes for Diastereodivergent Asymmetric Cyclopropanation

A heteroleptic dirhodium paddlewheel complex comprising three chiral carboxylate ligands and one achiral acetamidate ligand has recently been found to be uniquely effective in catalyzing the asymmetric cyclopropanation of olefins with α-stannylated (silylated and germylated) α-diazoacetate derivativ...

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Veröffentlicht in:	Journal of the American Chemical Society 2022-04, Vol.144 (16), p.7465-7478
Hauptverfasser:	Caló, Fabio Pasquale, Zimmer, Anne, Bistoni, Giovanni, Fürstner, Alois
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Catalysis Cyclopropanes - chemistry Humans Ligands Lithium Rhodium - chemistry
Online-Zugang:	Volltext
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