Production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported MWCNTs
Deoxygenation processes that exploit milder reaction conditions under H 2 -free atmospheres appear environmentally and economically effective for the production of green diesel. Herein, green diesel was produced by catalytic deoxygenation of chicken fat oil (CFO) over oxides of binary metal pairs (N...
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| Veröffentlicht in: | RSC advances 2020-01, Vol.1 (2), p.626-642 |
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| creator | Aliana-Nasharuddin, N Asikin-Mijan, N Abdulkareem-Alsultan, G Saiman, Mohd Izham Alharthi, Fahad A Alghamdi, Abdulaziz Ali Taufiq-Yap, Y. H |
| description | Deoxygenation processes that exploit milder reaction conditions under H
2
-free atmospheres appear environmentally and economically effective for the production of green diesel. Herein, green diesel was produced by catalytic deoxygenation of chicken fat oil (CFO) over oxides of binary metal pairs (Ni-Mg, Ni-Mn, Ni-Cu, Ni-Ce) supported on multi-walled carbon nanotubes (MWCNTs). The presence of Mg and Mn with Ni afforded greater deoxygenation activity, with hydrocarbon yields of >75% and
n
-(C
15
+ C
17
) selectivity of >81%, indicating that decarboxylation/decarbonylation (deCOx) of CFO is favoured by the existence of high amount of lower strength strong acidic sites along with noticeable strongly basic sites. Based on a series of studies of different Mg and Mn dosages (5-20 wt%), the oxygen free-rich diesel-range hydrocarbons produced efficiently by Ni
10
-Mg
15
/MWCNT and Ni
10
-Mn
5
/MWCNT catalysts yielded >84% of hydrocarbons, with
n
-(C
15
+ C
17
) selectivity of >85%. The heating value of the green diesel obtained complied with the ultra-low sulphur diesel standard.
Deoxygenation processes that exploit milder reaction conditions under H
2
-free atmospheres appear environmentally and economically effective for the production of green diesel. |
| doi_str_mv | 10.1039/c9ra08409f |
| format | Article |
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2
-free atmospheres appear environmentally and economically effective for the production of green diesel. Herein, green diesel was produced by catalytic deoxygenation of chicken fat oil (CFO) over oxides of binary metal pairs (Ni-Mg, Ni-Mn, Ni-Cu, Ni-Ce) supported on multi-walled carbon nanotubes (MWCNTs). The presence of Mg and Mn with Ni afforded greater deoxygenation activity, with hydrocarbon yields of >75% and
n
-(C
15
+ C
17
) selectivity of >81%, indicating that decarboxylation/decarbonylation (deCOx) of CFO is favoured by the existence of high amount of lower strength strong acidic sites along with noticeable strongly basic sites. Based on a series of studies of different Mg and Mn dosages (5-20 wt%), the oxygen free-rich diesel-range hydrocarbons produced efficiently by Ni
10
-Mg
15
/MWCNT and Ni
10
-Mn
5
/MWCNT catalysts yielded >84% of hydrocarbons, with
n
-(C
15
+ C
17
) selectivity of >85%. The heating value of the green diesel obtained complied with the ultra-low sulphur diesel standard.
Deoxygenation processes that exploit milder reaction conditions under H
2
-free atmospheres appear environmentally and economically effective for the production of green diesel.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c9ra08409f</identifier><identifier>PMID: 35494444</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Animal fat ; Calorific value ; Chemistry ; Chickens ; Copper ; Decarboxylation ; Deoxygenation ; Hydrocarbons ; Magnesium ; Manganese ; Metal oxides ; Multi wall carbon nanotubes ; Nickel ; Selectivity</subject><ispartof>RSC advances, 2020-01, Vol.1 (2), p.626-642</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2020</rights><rights>This journal is © The Royal Society of Chemistry 2020 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c520t-d22bc68aa8e232fa798955f40494214f1e358e9b5939f519a632226ceb073f423</citedby><cites>FETCH-LOGICAL-c520t-d22bc68aa8e232fa798955f40494214f1e358e9b5939f519a632226ceb073f423</cites><orcidid>0000-0001-7513-9777 ; 0000-0002-3574-7206</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9047115/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9047115/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35494444$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Aliana-Nasharuddin, N</creatorcontrib><creatorcontrib>Asikin-Mijan, N</creatorcontrib><creatorcontrib>Abdulkareem-Alsultan, G</creatorcontrib><creatorcontrib>Saiman, Mohd Izham</creatorcontrib><creatorcontrib>Alharthi, Fahad A</creatorcontrib><creatorcontrib>Alghamdi, Abdulaziz Ali</creatorcontrib><creatorcontrib>Taufiq-Yap, Y. H</creatorcontrib><title>Production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported MWCNTs</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>Deoxygenation processes that exploit milder reaction conditions under H
2
-free atmospheres appear environmentally and economically effective for the production of green diesel. Herein, green diesel was produced by catalytic deoxygenation of chicken fat oil (CFO) over oxides of binary metal pairs (Ni-Mg, Ni-Mn, Ni-Cu, Ni-Ce) supported on multi-walled carbon nanotubes (MWCNTs). The presence of Mg and Mn with Ni afforded greater deoxygenation activity, with hydrocarbon yields of >75% and
n
-(C
15
+ C
17
) selectivity of >81%, indicating that decarboxylation/decarbonylation (deCOx) of CFO is favoured by the existence of high amount of lower strength strong acidic sites along with noticeable strongly basic sites. Based on a series of studies of different Mg and Mn dosages (5-20 wt%), the oxygen free-rich diesel-range hydrocarbons produced efficiently by Ni
10
-Mg
15
/MWCNT and Ni
10
-Mn
5
/MWCNT catalysts yielded >84% of hydrocarbons, with
n
-(C
15
+ C
17
) selectivity of >85%. The heating value of the green diesel obtained complied with the ultra-low sulphur diesel standard.
Deoxygenation processes that exploit milder reaction conditions under H
2
-free atmospheres appear environmentally and economically effective for the production of green diesel.</description><subject>Animal fat</subject><subject>Calorific value</subject><subject>Chemistry</subject><subject>Chickens</subject><subject>Copper</subject><subject>Decarboxylation</subject><subject>Deoxygenation</subject><subject>Hydrocarbons</subject><subject>Magnesium</subject><subject>Manganese</subject><subject>Metal oxides</subject><subject>Multi wall carbon nanotubes</subject><subject>Nickel</subject><subject>Selectivity</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9ks1rFTEUxQex2NJ2416JdCPCaL5fshHKo9VC_UAqLkMmc_OaOjMZk5nSB_7xxr72WV14Nwnc3z2cy7lV9ZTg1wQz_cbpZLHiWPtH1R7FXNYUS_34wX-3Osz5CpeSglBJnlS7THDNS-1VPz-n2M5uCnFA0aNVAhhQGyBDh3yKPXJ2st16Cg61EG_WKxjsPewug_tecG8nFEOH4jUkZFGGVOZREwab1qiHMo_iTWihzvM4xjRBiz58W368yAfVjrddhsO7d7_6enpysXxfn396d7Y8Pq-doHiqW0obJ5W1Ciij3i600kJ4jssSlHBPgAkFuhGaaS-ItpJRSqWDBi-Y55TtV283uuPc9NA6GKZkOzOm0BeLJtpg_u4M4dKs4rXRmC8IEUXg5Z1Aij9myJPpQ3bQdXaAOGdDpVCSSy5IQY_-Qa_inIaynqGMcaGVUrpQrzaUSzHnBH5rhmDzO1ez1F-Ob3M9LfDzh_a36H2KBXixAVJ22-6fwzBj6wvz7H8M-wWt6LQE</recordid><startdate>20200102</startdate><enddate>20200102</enddate><creator>Aliana-Nasharuddin, N</creator><creator>Asikin-Mijan, N</creator><creator>Abdulkareem-Alsultan, G</creator><creator>Saiman, Mohd Izham</creator><creator>Alharthi, Fahad A</creator><creator>Alghamdi, Abdulaziz Ali</creator><creator>Taufiq-Yap, Y. H</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-7513-9777</orcidid><orcidid>https://orcid.org/0000-0002-3574-7206</orcidid></search><sort><creationdate>20200102</creationdate><title>Production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported MWCNTs</title><author>Aliana-Nasharuddin, N ; Asikin-Mijan, N ; Abdulkareem-Alsultan, G ; Saiman, Mohd Izham ; Alharthi, Fahad A ; Alghamdi, Abdulaziz Ali ; Taufiq-Yap, Y. H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c520t-d22bc68aa8e232fa798955f40494214f1e358e9b5939f519a632226ceb073f423</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Animal fat</topic><topic>Calorific value</topic><topic>Chemistry</topic><topic>Chickens</topic><topic>Copper</topic><topic>Decarboxylation</topic><topic>Deoxygenation</topic><topic>Hydrocarbons</topic><topic>Magnesium</topic><topic>Manganese</topic><topic>Metal oxides</topic><topic>Multi wall carbon nanotubes</topic><topic>Nickel</topic><topic>Selectivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aliana-Nasharuddin, N</creatorcontrib><creatorcontrib>Asikin-Mijan, N</creatorcontrib><creatorcontrib>Abdulkareem-Alsultan, G</creatorcontrib><creatorcontrib>Saiman, Mohd Izham</creatorcontrib><creatorcontrib>Alharthi, Fahad A</creatorcontrib><creatorcontrib>Alghamdi, Abdulaziz Ali</creatorcontrib><creatorcontrib>Taufiq-Yap, Y. H</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aliana-Nasharuddin, N</au><au>Asikin-Mijan, N</au><au>Abdulkareem-Alsultan, G</au><au>Saiman, Mohd Izham</au><au>Alharthi, Fahad A</au><au>Alghamdi, Abdulaziz Ali</au><au>Taufiq-Yap, Y. H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported MWCNTs</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2020-01-02</date><risdate>2020</risdate><volume>1</volume><issue>2</issue><spage>626</spage><epage>642</epage><pages>626-642</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Deoxygenation processes that exploit milder reaction conditions under H
2
-free atmospheres appear environmentally and economically effective for the production of green diesel. Herein, green diesel was produced by catalytic deoxygenation of chicken fat oil (CFO) over oxides of binary metal pairs (Ni-Mg, Ni-Mn, Ni-Cu, Ni-Ce) supported on multi-walled carbon nanotubes (MWCNTs). The presence of Mg and Mn with Ni afforded greater deoxygenation activity, with hydrocarbon yields of >75% and
n
-(C
15
+ C
17
) selectivity of >81%, indicating that decarboxylation/decarbonylation (deCOx) of CFO is favoured by the existence of high amount of lower strength strong acidic sites along with noticeable strongly basic sites. Based on a series of studies of different Mg and Mn dosages (5-20 wt%), the oxygen free-rich diesel-range hydrocarbons produced efficiently by Ni
10
-Mg
15
/MWCNT and Ni
10
-Mn
5
/MWCNT catalysts yielded >84% of hydrocarbons, with
n
-(C
15
+ C
17
) selectivity of >85%. The heating value of the green diesel obtained complied with the ultra-low sulphur diesel standard.
Deoxygenation processes that exploit milder reaction conditions under H
2
-free atmospheres appear environmentally and economically effective for the production of green diesel.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35494444</pmid><doi>10.1039/c9ra08409f</doi><tpages>17</tpages><orcidid>https://orcid.org/0000-0001-7513-9777</orcidid><orcidid>https://orcid.org/0000-0002-3574-7206</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2046-2069 |
| ispartof | RSC advances, 2020-01, Vol.1 (2), p.626-642 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9047115 |
| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; PubMed Central Open Access |
| subjects | Animal fat Calorific value Chemistry Chickens Copper Decarboxylation Deoxygenation Hydrocarbons Magnesium Manganese Metal oxides Multi wall carbon nanotubes Nickel Selectivity |
| title | Production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported MWCNTs |
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