PO(CH 2 CH 2 CF 3 ) 3 : an organic ultraviolet nonlinear optical material without any anionic group
Researchers have focused on inorganic compounds to design deep ultraviolet (UV) nonlinear optical (NLO) materials according to anionic group theory, such as CO , NO , SO and PO anions. Here we provide a new route to design an UV NLO material using a pure organic compound without any anions. Compound...
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| Veröffentlicht in: | RSC advances 2022-02, Vol.12 (8), p.4955-4960 |
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| container_title | RSC advances |
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| creator | Lin, Liting Li, Xiaoqian Qian, Kun Cheng, Lin Zhong, Youquan Xu, Hua |
| description | Researchers have focused on inorganic compounds to design deep ultraviolet (UV) nonlinear optical (NLO) materials according to anionic group theory, such as CO
, NO
, SO
and PO
anions. Here we provide a new route to design an UV NLO material using a pure organic compound without any anions. Compound PO(CH
CH
CF
)
1, an UV NLO material, has light transmittance up to 83% in the UV spectral region which is larger than most inorganic UV NLO materials. It also displays a wide transparent band, a SHG response of 0.30 × KH
PO
, and a cut-off edge below 200 nm. It displays ladder-like nonlinear optical properties weakened by 1.4 times at around
, making compound 1 a potential temperature-controlled UV NLO material. Theoretical analyses reveal that the nonlinear optical properties are primarily due to O-2p, P-2p and F-2p. |
| doi_str_mv | 10.1039/d1ra08768a |
| format | Article |
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, NO
, SO
and PO
anions. Here we provide a new route to design an UV NLO material using a pure organic compound without any anions. Compound PO(CH
CH
CF
)
1, an UV NLO material, has light transmittance up to 83% in the UV spectral region which is larger than most inorganic UV NLO materials. It also displays a wide transparent band, a SHG response of 0.30 × KH
PO
, and a cut-off edge below 200 nm. It displays ladder-like nonlinear optical properties weakened by 1.4 times at around
, making compound 1 a potential temperature-controlled UV NLO material. Theoretical analyses reveal that the nonlinear optical properties are primarily due to O-2p, P-2p and F-2p.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d1ra08768a</identifier><identifier>PMID: 35425516</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Anions ; Chemistry ; Displays ; Group theory ; Inorganic compounds ; Light transmittance ; Nonlinear optics ; Optical materials ; Optical properties ; Organic compounds ; Potassium phosphates</subject><ispartof>RSC advances, 2022-02, Vol.12 (8), p.4955-4960</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2022</rights><rights>This journal is © The Royal Society of Chemistry 2022 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c321a-c7b4ffde2bd59101c504e14db314db0f45fec151dae1daab120a4838cbed49f63</citedby><cites>FETCH-LOGICAL-c321a-c7b4ffde2bd59101c504e14db314db0f45fec151dae1daab120a4838cbed49f63</cites><orcidid>0000-0002-4915-6466</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981396/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981396/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35425516$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Lin, Liting</creatorcontrib><creatorcontrib>Li, Xiaoqian</creatorcontrib><creatorcontrib>Qian, Kun</creatorcontrib><creatorcontrib>Cheng, Lin</creatorcontrib><creatorcontrib>Zhong, Youquan</creatorcontrib><creatorcontrib>Xu, Hua</creatorcontrib><title>PO(CH 2 CH 2 CF 3 ) 3 : an organic ultraviolet nonlinear optical material without any anionic group</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>Researchers have focused on inorganic compounds to design deep ultraviolet (UV) nonlinear optical (NLO) materials according to anionic group theory, such as CO
, NO
, SO
and PO
anions. Here we provide a new route to design an UV NLO material using a pure organic compound without any anions. Compound PO(CH
CH
CF
)
1, an UV NLO material, has light transmittance up to 83% in the UV spectral region which is larger than most inorganic UV NLO materials. It also displays a wide transparent band, a SHG response of 0.30 × KH
PO
, and a cut-off edge below 200 nm. It displays ladder-like nonlinear optical properties weakened by 1.4 times at around
, making compound 1 a potential temperature-controlled UV NLO material. Theoretical analyses reveal that the nonlinear optical properties are primarily due to O-2p, P-2p and F-2p.</description><subject>Anions</subject><subject>Chemistry</subject><subject>Displays</subject><subject>Group theory</subject><subject>Inorganic compounds</subject><subject>Light transmittance</subject><subject>Nonlinear optics</subject><subject>Optical materials</subject><subject>Optical properties</subject><subject>Organic compounds</subject><subject>Potassium phosphates</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpdkdtKAzEQhoMoVrQ3PoAEvFGhmslhu-uFUOoRChXR65DNZmtkm9TsbsW3N2trUQP_zEC-GSb5EToEcg6EZRcFBEXSYZKqLbRHCU8GlCTZ9q-6h_p1_UbiSQTQBHZRjwlOhYBkD-nH6cn4HlO8CreY4dOoS6wc9mGmnNW4rZqgltZXpsHOu8o6owL2i8ZqVeG5akywsfiwzatvm9j5GWV91zoLvl0coJ1SVbXpr_M-erm9eR7fDybTu4fxaDLQjIIa6GHOy7IwNC9EBgS0INwAL3LWBVJyURoNAgplolQOlCieslTnpuBZmbB9dLWau2jzuSm0cXHvSi6CnavwKb2y8u-Ns69y5pcyzVJgWTfgZD0g-PfW1I2c21qbqlLO-LaWNH5gkgrGO_T4H_rm2-Di8yJFh5QPBaSROltROvi6DqbcLANEdvbJa3gafds3ivDR7_U36I9Z7AulNpQM</recordid><startdate>20220203</startdate><enddate>20220203</enddate><creator>Lin, Liting</creator><creator>Li, Xiaoqian</creator><creator>Qian, Kun</creator><creator>Cheng, Lin</creator><creator>Zhong, Youquan</creator><creator>Xu, Hua</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-4915-6466</orcidid></search><sort><creationdate>20220203</creationdate><title>PO(CH 2 CH 2 CF 3 ) 3 : an organic ultraviolet nonlinear optical material without any anionic group</title><author>Lin, Liting ; Li, Xiaoqian ; Qian, Kun ; Cheng, Lin ; Zhong, Youquan ; Xu, Hua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c321a-c7b4ffde2bd59101c504e14db314db0f45fec151dae1daab120a4838cbed49f63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Anions</topic><topic>Chemistry</topic><topic>Displays</topic><topic>Group theory</topic><topic>Inorganic compounds</topic><topic>Light transmittance</topic><topic>Nonlinear optics</topic><topic>Optical materials</topic><topic>Optical properties</topic><topic>Organic compounds</topic><topic>Potassium phosphates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lin, Liting</creatorcontrib><creatorcontrib>Li, Xiaoqian</creatorcontrib><creatorcontrib>Qian, Kun</creatorcontrib><creatorcontrib>Cheng, Lin</creatorcontrib><creatorcontrib>Zhong, Youquan</creatorcontrib><creatorcontrib>Xu, Hua</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lin, Liting</au><au>Li, Xiaoqian</au><au>Qian, Kun</au><au>Cheng, Lin</au><au>Zhong, Youquan</au><au>Xu, Hua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>PO(CH 2 CH 2 CF 3 ) 3 : an organic ultraviolet nonlinear optical material without any anionic group</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2022-02-03</date><risdate>2022</risdate><volume>12</volume><issue>8</issue><spage>4955</spage><epage>4960</epage><pages>4955-4960</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Researchers have focused on inorganic compounds to design deep ultraviolet (UV) nonlinear optical (NLO) materials according to anionic group theory, such as CO
, NO
, SO
and PO
anions. Here we provide a new route to design an UV NLO material using a pure organic compound without any anions. Compound PO(CH
CH
CF
)
1, an UV NLO material, has light transmittance up to 83% in the UV spectral region which is larger than most inorganic UV NLO materials. It also displays a wide transparent band, a SHG response of 0.30 × KH
PO
, and a cut-off edge below 200 nm. It displays ladder-like nonlinear optical properties weakened by 1.4 times at around
, making compound 1 a potential temperature-controlled UV NLO material. Theoretical analyses reveal that the nonlinear optical properties are primarily due to O-2p, P-2p and F-2p.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35425516</pmid><doi>10.1039/d1ra08768a</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-4915-6466</orcidid><oa>free_for_read</oa></addata></record> |
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| source | PubMed Central Free; DOAJ Directory of Open Access Journals; EZB-FREE-00999 freely available EZB journals; PubMed Central Open Access |
| subjects | Anions Chemistry Displays Group theory Inorganic compounds Light transmittance Nonlinear optics Optical materials Optical properties Organic compounds Potassium phosphates |
| title | PO(CH 2 CH 2 CF 3 ) 3 : an organic ultraviolet nonlinear optical material without any anionic group |
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