Metal-organic frameworks (MOFs) based nanofiber architectures for the removal of heavy metal ions
Environmental heavy metal ions (HMIs) accumulate in living organisms and cause various diseases. Metal-organic frameworks (MOFs) have proven to be promising and effective materials for removing heavy metal ions from contaminated water because of their high porosity, remarkable physical and chemical...
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Veröffentlicht in: | RSC advances 2022-01, Vol.12 (3), p.1433-145 |
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description | Environmental heavy metal ions (HMIs) accumulate in living organisms and cause various diseases. Metal-organic frameworks (MOFs) have proven to be promising and effective materials for removing heavy metal ions from contaminated water because of their high porosity, remarkable physical and chemical properties, and high specific surface area. MOFs are self-assembling metal ions or clusters with organic linkers. Metals are used as dowel pins to build two-dimensional or three-dimensional frameworks, and organic linkers serve as carriers. Modern research has mainly focused on designing MOFs-based materials with improved adsorption and separation properties. In this review, for the first time, an in-depth look at the use of MOFs nanofiber materials for HMIs removal applications is provided. This review will focus on the synthesis, properties, and recent advances and provide an understanding of the opportunities and challenges that will arise in the synthesis of future MOFs-nanofiber composites in this area. MOFs decorated on nanofibers possess rapid adsorption kinetics, a high adsorption capacity, excellent selectivity, and good reusability. In addition, the substantial adsorption capacities are mainly due to interactions between the target ions and functional binding groups on the MOFs-nanofiber composites and the highly ordered porous structure.
Metal-organic frameworks (MOFs) are promising and effective materials for removing heavy metal ions from contaminated water owing to their high porosity, remarkable physical and chemical properties, and high specific surface area. |
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Metal-organic frameworks (MOFs) are promising and effective materials for removing heavy metal ions from contaminated water owing to their high porosity, remarkable physical and chemical properties, and high specific surface area.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d1ra07034g</identifier><identifier>PMID: 35425211</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Adsorption ; Bioaccumulation ; Chemical properties ; Chemistry ; Composite materials ; Copper ; Heavy metals ; Metal ions ; Metal-organic frameworks ; Nanofibers ; Selectivity ; Self-assembly ; Synthesis</subject><ispartof>RSC advances, 2022-01, Vol.12 (3), p.1433-145</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2022</rights><rights>This journal is © The Royal Society of Chemistry 2022 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c428t-c25b6ba6a5c1a5a3ff163efc4279399ec748d312369931d798f23e2f301441613</citedby><cites>FETCH-LOGICAL-c428t-c25b6ba6a5c1a5a3ff163efc4279399ec748d312369931d798f23e2f301441613</cites><orcidid>0000-0002-7152-531X ; 0000-0002-0946-6136</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979196/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8979196/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35425211$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Adil, Heja Ibrahim</creatorcontrib><creatorcontrib>Thalji, Mohammad R</creatorcontrib><creatorcontrib>Yasin, Suhad A</creatorcontrib><creatorcontrib>Saeed, Ibtisam A</creatorcontrib><creatorcontrib>Assiri, Mohammed A</creatorcontrib><creatorcontrib>Chong, Kwok Feng</creatorcontrib><creatorcontrib>Ali, Gomaa A. M</creatorcontrib><title>Metal-organic frameworks (MOFs) based nanofiber architectures for the removal of heavy metal ions</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>Environmental heavy metal ions (HMIs) accumulate in living organisms and cause various diseases. Metal-organic frameworks (MOFs) have proven to be promising and effective materials for removing heavy metal ions from contaminated water because of their high porosity, remarkable physical and chemical properties, and high specific surface area. MOFs are self-assembling metal ions or clusters with organic linkers. Metals are used as dowel pins to build two-dimensional or three-dimensional frameworks, and organic linkers serve as carriers. Modern research has mainly focused on designing MOFs-based materials with improved adsorption and separation properties. In this review, for the first time, an in-depth look at the use of MOFs nanofiber materials for HMIs removal applications is provided. This review will focus on the synthesis, properties, and recent advances and provide an understanding of the opportunities and challenges that will arise in the synthesis of future MOFs-nanofiber composites in this area. MOFs decorated on nanofibers possess rapid adsorption kinetics, a high adsorption capacity, excellent selectivity, and good reusability. In addition, the substantial adsorption capacities are mainly due to interactions between the target ions and functional binding groups on the MOFs-nanofiber composites and the highly ordered porous structure.
Metal-organic frameworks (MOFs) are promising and effective materials for removing heavy metal ions from contaminated water owing to their high porosity, remarkable physical and chemical properties, and high specific surface area.</description><subject>Adsorption</subject><subject>Bioaccumulation</subject><subject>Chemical properties</subject><subject>Chemistry</subject><subject>Composite materials</subject><subject>Copper</subject><subject>Heavy metals</subject><subject>Metal ions</subject><subject>Metal-organic frameworks</subject><subject>Nanofibers</subject><subject>Selectivity</subject><subject>Self-assembly</subject><subject>Synthesis</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpdkdFr1TAUxoMobsy9-K4EfNmEak7Sps2LMKabwsZA9Dmcpif3drbNTNor---Xeed1el5y4Pvx8eV8jL0E8Q6EMu87iChqocrVE7YvRakLKbR5-mjfY4cpXYs8ugKp4TnbU1UpKwmwz_CSZhyKEFc49Y77iCP9CvFH4keXV2fpmLeYqOMTTsH3LUWO0a37mdy8RErch8jnNfFIY9jgwIPna8LNLR_vbXkfpvSCPfM4JDp8eA_Y97NP304_FxdX519OTy4KV8pmLpysWt2ixsoBVqi8B63IZ7E2yhhyddl0CqTSxijoatN4qUh6JaAsQYM6YB-2vjdLO1LnaJojDvYm9iPGWxuwt_8qU7-2q7CxjakNGJ0Njh4MYvi5UJrt2CdHw4AThSVZmc-nG53vmNE3_6HXYYlT_l6mwFRVnXNm6u2WcjGkFMnvwoCw9-XZj_D15Hd55xl-_Tj-Dv1TVQZebYGY3E792766A36zngU</recordid><startdate>20220105</startdate><enddate>20220105</enddate><creator>Adil, Heja Ibrahim</creator><creator>Thalji, Mohammad R</creator><creator>Yasin, Suhad A</creator><creator>Saeed, Ibtisam A</creator><creator>Assiri, Mohammed A</creator><creator>Chong, Kwok Feng</creator><creator>Ali, Gomaa A. 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Modern research has mainly focused on designing MOFs-based materials with improved adsorption and separation properties. In this review, for the first time, an in-depth look at the use of MOFs nanofiber materials for HMIs removal applications is provided. This review will focus on the synthesis, properties, and recent advances and provide an understanding of the opportunities and challenges that will arise in the synthesis of future MOFs-nanofiber composites in this area. MOFs decorated on nanofibers possess rapid adsorption kinetics, a high adsorption capacity, excellent selectivity, and good reusability. In addition, the substantial adsorption capacities are mainly due to interactions between the target ions and functional binding groups on the MOFs-nanofiber composites and the highly ordered porous structure.
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subjects | Adsorption Bioaccumulation Chemical properties Chemistry Composite materials Copper Heavy metals Metal ions Metal-organic frameworks Nanofibers Selectivity Self-assembly Synthesis |
title | Metal-organic frameworks (MOFs) based nanofiber architectures for the removal of heavy metal ions |
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